LEADER 05207nam 2200625Ia 450 001 9910144280003321 005 20170814190141.0 010 $a1-281-75871-X 010 $a9786611758714 010 $a3-527-61559-8 010 $a3-527-61558-X 035 $a(CKB)1000000000376625 035 $a(EBL)481639 035 $a(OCoLC)262833456 035 $a(SSID)ssj0000154289 035 $a(PQKBManifestationID)11162739 035 $a(PQKBTitleCode)TC0000154289 035 $a(PQKBWorkID)10417503 035 $a(PQKB)10647605 035 $a(MiAaPQ)EBC481639 035 $a(EXLCZ)991000000000376625 100 $a19941020d1995 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aFerrocenes$b[electronic resource] $ehomogeneous catalysis, organic synthesis, materials science /$fedited by Antonio Togni and Tamio Hayashi 210 $aWeinheim ;$aNew York $cVCH Publishers$dc1995 215 $a1 online resource (562 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29048-6 320 $aIncludes bibliographical references and index. 327 $aFerrocenes; Preface; Contents; List of Contributors; List of Abbreviations; Part 1. Homogeneous Catalysis; 1 1,1'-Bis (dipheny1phosphino)ferrocene - Coordination Chemistry, Organic Syntheses, and Catalysis; 1.1 Introduction; 1.2 Preparation and Complexation; 1.3 Structural Properties; 1.3.1 Modes of Coordination; 1.3.2 Geometrical Distortions; 1.4 Spectroscopic Characteristics; 1.4.1 Techniques; 1.4.1.1 31P NMR Spectroscopy; 1.4.1.2 1H NMR Spectroscopy; 1.4.1.3 Mo?ssbauer Spectroscopy; 1.4.2 NMR Fluxionality; 1.5 Catalysis; 1.5.1 Cross Coupling 327 $a1.5.1.1 Organic Electrophile and Organometallic Coupling1.5.1.2 Arylation and Vinylation of Alkenes; 1.5.1.3 Carbonylation and Carbonylative Coupling; 1.5.1.4 Nucleophilic Substitution; 1.5.1.5 Polycondensation and Polymerization; 1.5.2 Olefin Functionalization; 1.5.2.1 Hydroformylation; 1.5.2.2 Hydrogenation and Reduction; 1.5.2.3 Hydroboration and Hydrosilylation; 1.5.2.4 Isomerization; 1.6 Cluster Complexes; 1.7 Electrochemistry; 1.8 Biomedical Applications; 1.9 Summary; References; 2 Asymmetric Catalysis with Chiral Ferrocenylphosphine Ligands; 2.1 Introduction 327 $a2.2 Preparation of Chiral Ferrocenylphosphines2.3 Structure of Chiral Ferrocenylphosphines and their Transition-Metal Complexes; 2.4 Catalytic Asymmetric Reactions with Chiral Ferrocenylphosphine Ligands; 2.4.1 Cross-Coupling of Organometallics with Halides; 2.4.2 Allylic Substitution Reactions via ?-Ally1 Complexes; 2.4.3 Hydrogenation of Olefins and Ketones; 2.4.4 Hydrosilylation of Olefins and Ketones; 2.4.5 Aldol Reaction of ?-Isocyanocarboxylates; 2.4.6 Others; References; 3 Enantioselective Addition of Dialkylzinc to Aldehydes Catalyzed by Chiral Ferrocenyl Aminoalcohols 327 $a3.1 Introduction3.2 Chiral Ferrocenylzincs Bearing an Aminoethanol Auxiliary [12]; 3.2.1 Synthesis of the Catalysts; 3.2.2 Addition of Diethylzinc to Benzaldehyde; 3.3 N- (1-Ferrocenylalky1)-N-alk ylnorephedrines [13]; 3.3.1 Synthesis of the Catalysts; 3.3.2 Addition of Diethylzinc to Aldehydes; 3.4 Chiral Polymers Bearing N-Ferrocenylmethylephedrine [14]; 3.4.1 Synthesis of the Catalysts; 3.4.2 Addition of Diethylzinc to Benzaldehyde; 3.5 Chiral 1,2-Disubstituted Ferrocenyl Aminoalcohols [15]; 3.5.1 Synthesis of the Catalysts; 3.5.2 Addition of Dialkylzinc to Aldehydes 327 $a3.5.3 Addition of Dialkylzincs to o-Phthalaldehyde: A Facile Synthesis of Optically Active 3-Alkylphthalides [16]3.5.4 Enantio- and Diastereoselective Addition of Diethylzinc to Racemic ?-Thio- and ?-Selenoaldehydes [17]; 3.6 Summary; References; Part 2. Organic Synthesis - Selected Aspects; 4 Chiral Ferrocene Derivatives. An Introduction; 4.1 Central and Planar Chirality in Metallocenes; 4.2 a-Ferrocenylalkyl Carbocations; 4.2.1 Structure and Stability; 4.2.2 Stereochemistry; 4.3 Central Chiral Ferrocene Derivatives; 4.3.1 Syntheses; 4.3.1.1 By Resolution; 4.3.1.2 By Asymmetric Synthesis 327 $a4.3.1.3 From the Chiral Pool 330 $aWith applications ranging from asymmetric catalysis to magnetic materials, ferrocene is one of the most versatile building blocks in synthesis. This book captures the multidisciplinary nature of ferrocene research, including topics such as ferrocene-containing polymers, ferrocene-containing thermotropic liquid crystals, chiral ferrocene derivatives, and ferrocene-containing charge-transfer materials.In addition, the reader will find* valuable information for planning syntheses* over 70 tables, making relevant data available at a glance * carefully selected references, provi 606 $aFerrocene 606 $aOrganoiron compounds 608 $aElectronic books. 615 0$aFerrocene. 615 0$aOrganoiron compounds. 676 $a547.05621 701 $aTogni$b Antonio$0863256 701 $aHayashi$b Tamio$092745 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144280003321 996 $aFerrocenes$91926978 997 $aUNINA