LEADER 04656nam 2200625 a 450 001 9910144120303321 005 20170810183248.0 010 $a1-281-84262-1 010 $a9786611842628 010 $a3-527-61475-3 010 $a3-527-61474-5 035 $a(CKB)1000000000549277 035 $a(EBL)481586 035 $a(OCoLC)289310566 035 $a(SSID)ssj0000117553 035 $a(PQKBManifestationID)11136273 035 $a(PQKBTitleCode)TC0000117553 035 $a(PQKBWorkID)10049532 035 $a(PQKB)10248724 035 $a(MiAaPQ)EBC481586 035 $a(EXLCZ)991000000000549277 100 $a19970429d1996 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aCapillary gas adsorption chromatography$b[electronic resource] /$fby V.G. Berezkin and J. de Zeeuw 210 $aHeidelberg $cHu?thig Verlag$dc1996 215 $a1 online resource (334 p.) 225 1 $aChromatographic methods 300 $aDescription based upon print version of record. 311 $a3-527-29675-1 320 $aIncludes bibliographical references and index. 327 $aCapillary Gas Adsorption Chromatography; Contents; 1. Introduction; 1.1 Advantages and Limitations of Gas-Solid Chromatography; 1.2 Discovery of Gas-Solid Open Tubular Capillary Columns; 1.3 Classification of Capillary Columns in Gas Chromatography; References; 2. Capillary Gas-Solid Chromatography (Advantages and Limitations); 2.1 On the Role of Gas-Solid Chromatography; 2.2 Comparison of Open Tubular and Packed Gas Adsorption Columns; 2.3 Some Peculiarities of Capillary Adsorption Columns; 2.4 Uncoated Capillaries as Capillary Adsorption Columns; References 327 $a3. Fundamentals of Gas-Solid Chromatography3.1 Retention in Gas-Solid Chromatography; 3.2 Chromatographic Zone Broadening in ALOT Columns; 3.3 Dependence of Column Efficiency on Sample Size; 3.4 Resolution of Analyzed Compounds; References; 4. Chromatographic Adsorbents; 4.1 Carbon Adsorbents; 4.2 Molybdenite (MoS2); 4.3 Porous Polymer Adsorbents; 4.4 Silica Gels; 4.5 Alumina; 4.6 Molecular Sieves; 4.7 Ionic Adsorbents; References; 5. Modified Gas-Solid Chromatography; 5.1 Solid Adsorbents Modified by Non-volatile Organic Compounds; 5.2 Adsorbents Modified by Inorganic Salts 327 $a5.3 Chemically Modified Adsorbents (Bonded-Phase Silica as Adsorbent in Gas Chromatography)5.4 Adsorbents Modified by Volatile Compounds; 5.4.1 The Role of Volatile Modifier in Gas Chromatography; 5.4.2 Water Vapor as Carrier Gas and Modifying Agent; 5.4.3 Water Vapor (Carrier Gas) and Inorganic Salts (Stationary Phase) in Gas Chromatography; 5.4.4 Carbon Dioxide as Carrier Gas and Modifying Agent; 5.4.5 Use of Volatile Modifier (""Transparent"" to the Flame Ionization Detector); 5.4.6 Using Volatile Modifier with Super-selective Detector 327 $a5.5 Adsorption Open Tubular Columns with Modified AdsorbentsReferences; 6. Preparation of Adsorbent Layer Open Tubular Columns; 6.1 Suspension Method; 6.1.1 ALOT Columns with Graphitized Carbon Black; 6.1.2 ALOT Columns with Alumina; 6.1.3 ALOT Columns with other Oxide Adsorbents; 6.1.4 ALOT Columns with Molecular Sieves; 6.1.5 SCOT Columns; 6.2 Preparation of Adsorbent Layer by Synthesis from Materials of the Inner Capillary Walls; 6.3 Preparation of ALOT Columns by Sorbent Synthesis inside the Capillary Column; 6.4 Formation of Adsorption Layer during Glass Capillary Drawing; 6.5 Conclusion 327 $aReferences7. Applications of ALOT Columns; 7.1 The Carrier Gas; 7.1.1 Use of Hydrogen; 7.1.2 Optimum Carrier Gas Velocity; 7.2 Release of Particles from the Column Wall upon Application; 7.2.1 Use of Pre-columns; 7.2.2 Use of Particle Traps; 7.3 Separation of Gases; 7.3.1 Inert Gases; 7.3.2 Carbon Monoxide; 7.3.3 Carbon Dioxide; 7.3.4 Carbon Monoxide, Carbon Dioxide and Air; 7.3.5 Carbon Dioxide, C1-C4 Hydrocarbons and Inert Gases; 7.3.6 Sulfur Gases; 7.4 Separation of C1-C5 Hydrocarbons; 7.4.1 C1-C2 Hydrocarbons; 7.4.2 C1-C4 Hydrocarbons 327 $a7.4.3 Hydrocarbon Impurity Analysis in Main Hydrocarbon Streams 410 0$aChromatographic methods. 606 $aGas chromatography 608 $aElectronic books. 615 0$aGas chromatography. 676 $a543.0896 676 $a622 700 $aBerezkin$b V. G$g(Viktor Grigor?evich),$f1931-$015238 701 $aZeeuw$b J. de$g(Jaap)$0978675 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144120303321 996 $aCapillary gas adsorption chromatography$92230620 997 $aUNINA