LEADER 05225nam 2200625 450 001 9910144120103321 005 20170816112115.0 010 $a1-281-94719-9 010 $a9786611947194 010 $a3-527-62327-2 010 $a3-527-62328-0 035 $a(CKB)1000000000549282 035 $a(EBL)482232 035 $a(OCoLC)264703279 035 $a(SSID)ssj0000183810 035 $a(PQKBManifestationID)11156654 035 $a(PQKBTitleCode)TC0000183810 035 $a(PQKBWorkID)10195386 035 $a(PQKB)11704004 035 $a(MiAaPQ)EBC482232 035 $a(PPN)243298285 035 $a(EXLCZ)991000000000549282 100 $a20160820h20082008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aIron catalysis in organic chemistry $ereactions and applications /$fedited by Bernd Plietker 210 1$aWeinheim, [Germany] :$cWiley-VCH Verlag GmbH & Co. KGaA,$d2008. 210 4$dİ2008 215 $a1 online resource (297 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31927-1 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aIron Catalysis in Organic Chemistry; Contents; Preface; List of Contributors; 1 Iron Complexes in Organic Chemistry; 1.1 Introduction; 1.2 General Aspects of Iron Complex Chemistry; 1.2.1 Electronic Configuration, Oxidation States, Structures; 1.2.2 Fundamental Reactions; 1.3 Organoiron Complexes and Their Applications; 1.3.1 Binary Carbonyl-Iron Complexes; 1.3.2 Alkene-Iron Complexes; 1.3.3 Allyl- and Trimethylenemethane-Iron Complexes; 1.3.4 Acyl- and Carbene-Iron Complexes; 1.3.5 Diene-Iron Complexes; 1.3.6 Ferrocenes; 1.3.7 Arene-Iron Complexes; 1.4 Catalysis Using Iron Complexes 327 $a1.4.1 Iron Complexes as Substrates and/or Products in Catalytic Reactions1.4.2 Iron Complexes as Ligands for Other Transition Metal Catalysts; 1.4.3 Iron Complexes as Catalytically Active Species; References; 2 Iron Catalysis in Biological and Biomimetic Reactions; 2.1 Non-heme Iron Catalysts in Biological and Biomimetic Transformations; 2.1.1 Introduction: Iron in Biological Processes; 2.1.2 Non-heme Iron Proteins; 2.1.2.1 Mononuclear Iron Sites; 2.1.2.2 Dinuclear Iron Sites; 2.1.3 Summary; References; 2.2 Organic Reactions Catalyzed by Heme Proteins 327 $a2.2.1 Classification and General Reactivity Schemes of Heme Proteins Used in Organic Synthesis2.2.2 Organic Reactions Catalyzed by Cytochromes P450; 2.2.3 Organic Reactions Catalyzed by Heme Peroxidases; 2.2.3.1 Dehydrogenations (""Peroxidase Reactivity""); 2.2.3.2 Sulfoxidations (""Peroxygenase Reactivity""); 2.2.3.3 Peroxide Disproportionation (""Catalase Reactivity""); 2.2.3.4 Halogenation (""Haloperoxidase Reactivity""); 2.2.3.5 Epoxidations (""Monoxygenase Activity""); References; 3 Iron-catalyzed Oxidation Reactions; 3.1 Oxidations of C-H and C=C Bonds; 3.1.1 Gif Chemistry 327 $a3.1.2 Alkene Epoxidation3.1.3 Alkene Dihydroxylation; 3.1.4 The Kharasch Reaction and Related Reactions; 3.1.5 Aziridination and Diamination; References; 3.2 Oxidative Allylic Oxygenation and Amination; 3.2.1 Introduction; 3.2.2 Iron-catalyzed Allylic Oxidations; 3.2.2.1 Simple Iron Salts; 3.2.2.2 Fe(III) Complexes with Bidentate Ligands; 3.2.2.3 Fe(3+)/Fe(2+) Porphyrin and Phthalocyanine Complexes; 3.2.2.4 Iron(III) Salen Complexes; 3.2.2.5 Non-heme Iron Complexes with Tetra- and Pentadentate Ligands; 3.2.3 Oxidative Allylic Aminations; 3.2.4 Conclusion; References 327 $a3.3 Oxidation of Heteroatoms (N and S)3.3.1 Oxidation of Nitrogen Compounds; 3.3.1.1 Oxidation of Hydroxylamines to Nitroso Compounds; 3.3.1.2 Oxidation of Arylamines; 3.3.1.3 Other N-Oxidations; 3.3.2 Oxidation of Sulfur Compounds; 3.3.2.1 Oxidation of Thiols to Disulfides; 3.3.2.2 Oxidation of Sulfides; 3.3.2.3 Oxidative Imination of Sulfur Compounds; References; 4 Reduction of Unsaturated Compounds with Homogeneous Iron Catalysts; 4.1 Introduction; 4.2 Hydrogenation of Carbonyl Compounds; 4.3 Hydrogenation of Carbon-Carbon Double Bonds; 4.4 Hydrogenation of Imines and Similar Compounds 327 $a4.5 Catalytic Hydrosilylations 330 $aThis first comprehensive book to cover this exciting field also deals with the biological aspects, such as enzymes with iron.Following an introduction, this handy reference and handbook goes on to deal with reductions, oxidations of C, H- and C=C bonds, oxidative allylic oxygenation and amination, the oxidation of heteroatoms, cross coupling reactions, aromatic and nucleophilic substitutions, addition to carbonyl compounds, and cyclisations as well as ring opening reactions.The chapters are clearly classified according to the reaction type, allowing readers to quickly locate the desire 606 $aIron catalysts 606 $aCatalysis 615 0$aIron catalysts. 615 0$aCatalysis. 676 $a547.05621 702 $aPlietker$b Bernd 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144120103321 996 $aIron catalysis in organic chemistry$92273856 997 $aUNINA