LEADER 05269nam 2200661 450 001 9910144115003321 005 20170815111134.0 010 $a1-281-94021-6 010 $a9786611940218 010 $a0-470-99828-8 010 $a0-470-99829-6 035 $a(CKB)1000000000555964 035 $a(EBL)366781 035 $a(OCoLC)298943873 035 $a(SSID)ssj0000225573 035 $a(PQKBManifestationID)11208790 035 $a(PQKBTitleCode)TC0000225573 035 $a(PQKBWorkID)10233212 035 $a(PQKB)10176239 035 $a(MiAaPQ)EBC366781 035 $a(EXLCZ)991000000000555964 100 $a20160818h20082008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 12$aA practical approach to quantitative metal analysis of organic matrices /$fMartin C. Brennan 210 1$aWest Sussex, England :$cWiley,$d2008. 210 4$dİ2008 215 $a1 online resource (278 p.) 300 $aDescription based upon print version of record. 311 $a0-470-03197-2 320 $aIncludes bibliographical references and index. 327 $aA Practical Approach to Quantitative Metal Analysis of Organic Matrices; Contents; Preface; Biography; Acknowledgements; 1 A Practical Approach to Quantitative Metal Analysis of Organic Matrices Using ICP-OES; 1.1 Introduction and Basic Overview; 1.2 Schematic Representation of the Energies Generated by Atomic Spectroscopic Methods; 1.3 Excitation Energy (Quantum Theory and Atomic Spectra); 1.4 Ionisation Energy and Number of Excited Atoms; 1.5 Width of Atomic Lines; 1.5.1 Natural Broadening; 1.5.2 Doppler Broadening; 1.5.3 Lorentzian Broadening or Pressure Broadening 327 $a1.5.4 Holtsmark Broadening or Resonance Broadening1.5.5 Field Broadening or Stark Broadening; 1.5.6 Self-Absorption and Self-Reversal Broadening; 1.6 Brief Summary of Atomic Spectroscopic Techniques Used for Elemental Analysis; 1.6.1 The Atomic Absorption Spectrophotometer; 1.6.2 Atomic Fluorescence Spectroscopy; 1.6.3 Direct Current Plasma Optical Emission Spectrometry (DCP-OES); 1.6.4 Microwave Induced Plasma (MIP); 1.6.5 Glow Discharge Optical Emission Spectrometry (GD-OES); 1.6.6 Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) 327 $a1.7 Summary: Applications of Atomic SpectroscopyReferences; 2 Instrumentations Associated with Atomic Spectroscopy; 2.1 Instrumentation; 2.2 Types of Plasma Sources; 2.2.1 Direct Current Plasma Atomic Emission Spectrograph; 2.2.2 Microwave Induced Plasma; 2.2.3 Optical Emission Spectroscopy; 2.3 Sample Introduction Systems; 2.3.1 Mechanical Transfer of Sample/Standards Using Peristaltic Pump, Pressure Valves, Motorised Syringes, etc.; 2.3.2 Nebulisers; 2.3.3 Brief Outline of Atomic Spectroscopy Hyphenated Systems; 2.4 Spray Chambers; 2.5 ICP-OES Torches; 2.6 Optics; 2.6.1 Grating Orders 327 $a2.7 Signal Detectors2.7.1 Photomultiplier Tubes; 2.7.2 Charge Coupled Devices; References; 3 Methodologies of Metal Analysis of Organic Matrices Using ICP-OES; 3.1 Sample Preparation Techniques and Methods of Analysis; 3.2 Defining Goals; 3.3 Steps in Chemical Analytical Protocol; 3.4 Sampling and its Importance; 3.5 Sample Preparation Methods; 3.5.1 Direct Analysis of Organic Solutions; 3.5.2 Sample Dissolution; 3.5.3 Chemical Extraction of Metals from Organic Matrices; 3.5.4 Dry Ashing without Retaining Aids; 3.5.5 Dry Ashing with Retaining Aids; 3.5.6 Acid Digestion Using Microwave Oven 327 $a3.5.7 Oxygen Bomb Flask Combustion (Low Pressure)3.5.8 High Pressure Oxygen Combustion; 3.5.9 Sample Preparation Using Fusion Methods; 3.5.10 Analysis Using Slurry Solution Method; 3.5.11 Sample Preparation Using Leaching Method; 3.5.12 Sample Preparation Using a UV Digester; 3.6 Non-Spectral Corrections Using ICP-OES; 3.6.1 Effect of Solvents on ICP-OES; 3.6.2 Effect of Viscosity on Signal Response; 3.6.3 Comparison of Nebulisation Efficiency of Solvents Using ICP-OES; 3.6.4 Choice of Carrier Liquid; 3.7 Methodology of Measurement; 3.7.1 Choice of Standard Materials 327 $a3.7.2 Quantitative Analysis Using Calibration Graph Method 330 $aThere has been significant expansion in the application of atomic spectrographic techniques in recent years, which has brought with it the need to provide more flexible methods to a wider range of samples, particularly non-aqueous samples. This book compares the traditional and improved methods in the analysis of non-aqueous samples for elemental analyses by atomic emission spectroscopic methods whilst describing procedures that will attempt to improve sample preparation methods. 606 $aAtomic emission spectroscopy 606 $aMetals$xAnalysis 606 $aChemistry, Organic 608 $aElectronic books. 615 0$aAtomic emission spectroscopy. 615 0$aMetals$xAnalysis. 615 0$aChemistry, Organic. 676 $a543.52 676 $a543.6 700 $aBrennan$b Martin$f1943-$0984316 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144115003321 996 $aA practical approach to quantitative metal analysis of organic matrices$92248134 997 $aUNINA