LEADER 05064nam 2200661 450 001 9910144113803321 005 20170918200635.0 010 $a1-281-94716-4 010 $a9786611947163 010 $a3-527-62321-3 010 $a3-527-62322-1 035 $a(CKB)1000000000556068 035 $a(EBL)481754 035 $a(OCoLC)283799096 035 $a(SSID)ssj0000217652 035 $a(PQKBManifestationID)11186862 035 $a(PQKBTitleCode)TC0000217652 035 $a(PQKBWorkID)10202531 035 $a(PQKB)11413835 035 $a(MiAaPQ)EBC481754 035 $a(EXLCZ)991000000000556068 100 $a20160818h20082008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aPalladacycles $esynthesis, characterization and applications /$fedited by Jairton Dupont and Michel Pfeffer 210 1$aWeinheim, [Germany] :$cWiley-VCH Verlag GmbH & Co. KGaA,$d2008. 210 4$dİ2008 215 $a1 online resource (433 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31781-3 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aPalladacycles; Contents; List of Contributors; 1 Introduction; 1.1 Introduction; 1.2 Definition; 1.3 Historical Overview; 1.4 Classification of Palladacycles (Types); 1.5 Final Remarks; References; 2 C-H Bond Activation; 2.1 General Remarks; 2.2 Activation of Aryl C-H Bonds; 2.2.1 Donor Group Coordination; 2.2.2 Metal Precursor; 2.2.3 Electron Density at the Arene C-H Bond; 2.3 Pincer Complexes: A Special Case; 2.4 Transcyclometallation; 2.5 Activation of Heterocyclic C-H Bonds, Formation of Pd-Carbene Bonds; 2.6 Activation of sp(3) C-H Bonds; 2.6.1 Activation of Benzylic C-H Bonds 327 $a2.6.2 Activation of Aliphatic C-H Bonds2.7 Conclusions and Perspectives; References; 3 Oxidative Addition and Transmetallation; 3.1 Introduction; 3.2 Oxidative Addition; 3.3 Transmetallation; References; 4 Synthesis via Other Synthetic Solutions; 4.1 Introduction; 4.2 Synthesis of Palladacycles via Nucleophile-Palladation Reaction of Olefins or Alkynes Bearing Electron-Donor Heteroatoms; 4.2.1 Alkoxypalladation Reaction; 4.2.2 Carbopalladation; 4.2.3 Chloropalladation; 4.3 Carbopalladation Reaction via Insertion of Olefins or Alkynes into the Pd-C ?-Bond of Nonpalladacyclic Species 327 $a4.3.1 Insertion of Olefins or Alkynes Bearing Electron-Donor Atoms4.3.2 Insertion of Olefins, Allenes or Alkynes into a Pd-C ?-Bond of a Fragment Containing Electron-Donor Atoms; 4.4 Nucleophile Palladation of Olefins or Alkynes Not Bearing Heteroatoms; 4.4.1 Aminopalladation and Aminoformylpalladation; 4.5 Conclusion; References; 5 The Pd-C Building Block of Palladacycles: A Cornerstone for Stoichiometric C-C and C-X Bond Assemblage; 5.1 Introduction; 5.2 Reactions with Carbon Monoxide; 5.3 Reactions with Alkenes; 5.4 Reaction with Alkynes; 5.5 Reaction with Isocyanides 327 $a5.6 Reaction with Allenes5.7 Reactions with Acyl Halides; 5.8 Reaction with Halogens; 5.9 Conclusions; References; 6 C-H Activations via Palladacycles; 6.1 Introduction: C-C Bond Formation via Cyclopalladation Reactions; 6.2 Stoichiometric C-H Activation Chemistry; 6.3 Catalytic Chemistry; 6.3.1 Vinylations; 6.4 Arylations; 6.5 Direct C-H C-H Coupling Reactions; 6.6 Alkylations; 6.7 Other Reactions; 6.7.1 Carbonylations; 6.7.2 C-N Bond Formation; 6.8 Conclusion; References; 7 Cyclopalladated Compounds as Resolving Agents for Racemic Mixtures of Ligands; 7.1 Introduction 327 $a7.2 Resolution Methods7.3 Chiral Palladacyclic Auxiliaries; 7.4 Monodentate Ligands; 7.4.1 Resolution of Phosphines and Arsines; 7.4.2 Resolution of Air-Sensitive Ligands; 7.4.3 Resolution of Atropoisomeric Phosphines; 7.4.4 Resolution of Halogenophosphines; 7.4.5 Resolution of Stibines; 7.4.6 Resolution of Cluttered Chiral Bidentate Ligands; 7.5 Bidentate Ligands; 7.5.1 Neutral Ligands; 7.5.2 Anionic Ligands; 7.6 Conclusion; References; 8 Application of Cyclopalladated Compounds as Catalysts for Heck and Sonogashira Reactions; 8.1 Heck Reaction; 8.1.1 Introduction; 8.1.2 Mechanism 327 $a8.1.3 Catalysts 330 $aFrom synthesis to applications in catalysis, material science and biology this much-needed book is the first to comprehensively present everything you need to know about palladacycles. Renowned international authors guarantee high-quality content, making this a must-have for everyone working in the field. 606 $aOrganometallic compounds 606 $aPolycyclic compounds 606 $aCatalysis 608 $aElectronic books. 615 0$aOrganometallic compounds. 615 0$aPolycyclic compounds. 615 0$aCatalysis. 676 $a547.5 702 $aDupont$b Jairton 702 $aPfeffer$b Michel 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144113803321 996 $aPalladacycles$92170854 997 $aUNINA LEADER 03304nam 2200577 450 001 9910809080103321 005 20230803033108.0 010 $a0-674-72693-6 010 $a0-674-72604-9 024 7 $a10.4159/harvard.9780674726048 035 $a(CKB)3710000000054662 035 $a(EBL)3301341 035 $a(SSID)ssj0000941173 035 $a(PQKBManifestationID)11473291 035 $a(PQKBTitleCode)TC0000941173 035 $a(PQKBWorkID)10963555 035 $a(PQKB)10344073 035 $a(MiAaPQ)EBC3301341 035 $a(DE-B1597)209584 035 $a(OCoLC)862745956 035 $a(OCoLC)979579384 035 $a(DE-B1597)9780674726048 035 $a(Au-PeEL)EBL3301341 035 $a(CaPaEBR)ebr10782446 035 $a(EXLCZ)993710000000054662 100 $a20130418d2013 uy| 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aCivil examinations and meritocracy in late Imperial China /$fBenjamin A. Elman 210 1$aCambridge, Massachusetts ;$aLondon, England :$cHarvard University Press,$d2013. 215 $a1 online resource (416 p.) 300 $aDescription based upon print version of record. 311 $a0-674-72495-X 320 $aIncludes bibliographical references and index. 327 $apart I. Becoming mainstream : "way learning" during the late empire -- part II. Unintended consequences of civil examinations -- part III. Retooling civil examinations to suit changing times. 330 $aDuring China's late imperial period (roughly 1400-1900 CE), men gathered by the millions every two or three years outside official examination compounds sprinkled across China. Only one percent of candidates would complete the academic regimen that would earn them a post in the administrative bureaucracy. Civil Examinations assesses the role of education, examination, and China's civil service in fostering the world's first professional class based on demonstrated knowledge and skill. Civil examinations were instituted in China in the seventh century CE, but in the Ming and Qing eras they were at the center of a complex social web that held together the intellectual, political, and economic life of imperial China. Local elites and the court sought to influence how the government regulated the classical curriculum and selected civil officials. As a guarantor of educational merit, examinations tied the dynasty to the privileged gentry and literati classes--both ideologically and institutionally. China eliminated its classical examination system in 1905. But this carefully balanced, constantly contested piece of social engineering, worked out over centuries, was an early harbinger of the meritocratic regime of college boards and other entrance exams that undergirds higher education in much of the world today. 606 $aCivil service$zChina$xExaminations$xHistory 615 0$aCivil service$xExaminations$xHistory. 676 $a352.6/3076 700 $aElman$b Benjamin A.$f1946-$0934862 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910809080103321 996 $aCivil examinations and meritocracy in late Imperial China$94115445 997 $aUNINA 999 $p$23.75$u11/21/2019$5Poli