LEADER 01209cam2-22004091i-450- 001 990003337360403321 005 20130415095337.0 035 $a000333736 035 $aFED01000333736 035 $a(Aleph)000333736FED01 035 $a000333736 100 $a20030910d1972----km-y0itay50------ba 101 0 $aeng 102 $aGB 105 $ay-------001yy 200 1 $aEssays in biography$fJohn Maynard Keynes 210 $aLondon$cMacmillan$aNew York$cSt. Martin's Press$d1972 215 $aXX, 460 p.$d22 cm 461 0$1001000300297$12001$a<> collected writings of John Maynard Keynes$v10 610 0 $aEconomisti$aGran Bretagna$aBiografie 676 $a330.15 676 $aD/0.2 700 1$aKeynes,$bJohn Maynard$f<1883-1946>$034099 801 0$aIT$bUNINA$gRICA$2UNIMARC 901 $aBK 912 $a990003337360403321 952 $a330.15 KEY /1$bLINGUE 722$fDECLI 952 $aCOLLEZ. 771 (10)$b20226$fFSPBC 952 $aA/70 KEY$b5646/I$fSES 952 $aA/70 KEY$b8603/I$fSES 952 $aA/70 KEY/DEP$b5646/I$fSES 952 $aXV C 45$bs.i.$fDTE 959 $aDECLI 959 $aFSPBC 959 $aSES 996 $aEssays in biography$921631 997 $aUNINA LEADER 05370nam 2200673 a 450 001 9910144100303321 005 20170815111120.0 010 $a1-281-94011-9 010 $a9786611940119 010 $a0-470-72342-4 010 $a0-470-72341-6 035 $a(CKB)1000000000551018 035 $a(EBL)366783 035 $a(OCoLC)298944860 035 $a(SSID)ssj0000155884 035 $a(PQKBManifestationID)11149564 035 $a(PQKBTitleCode)TC0000155884 035 $a(PQKBWorkID)10122161 035 $a(PQKB)11010998 035 $a(MiAaPQ)EBC366783 035 $a(EXLCZ)991000000000551018 100 $a20080623d2008 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aFlash chemistry$b[electronic resource] $efast organic synthesis in microsystems /$fJun-ichi Yoshida 210 $aHoboken, N.J. $cWiley$d2008 215 $a1 online resource (248 p.) 300 $aDescription based upon print version of record. 311 $a0-470-03586-2 320 $aIncludes bibliographical references and index. 327 $aFlash Chemistry Fast Organic Synthesis in Microsystems; Contents; Preface; 1 Introduction; 1.1 Flask Chemistry; 1.2 Flash Chemistry; 1.3 Flask Chemistry or Flash Chemistry; References; 2 The Background to Flash Chemistry; 2.1 How do Chemical Reactions Take Place?; 2.1.1 Macroscopic View of Chemical Reactions; 2.1.2 Thermodynamic Equilibrium and Kinetics; 2.1.3 Kinetics; 2.1.4 Transition State Theory; 2.1.5 Femtosecond Chemistry and Reaction Dynamics; 2.1.6 Reactions for Dynamics and Reactions for Synthesis; 2.1.7 Bimolecular Reactions in the Gas Phase 327 $a2.1.8 Bimolecular Reactions in the Solution Phase2.1.9 Fast Chemical Synthesis Inspired by Reaction Dynamics; References; 3 What is Flash Chemistry?; 4 Why is Flash Chemistry Needed?; 4.1 Chemical Reaction, an Extremely Fast Process at Molecular Level; 4.2 Rapid Construction of Chemical Libraries; 4.3 Rapid Synthesis of Radioactive Positron Emission Tomography Probes; 4.4 On-demand Rapid Synthesis i n Industry 304.5 Conclusions; References; 5 Methods of Activating Molecules; 5.1 Thermal Activation of Organic Molecules; 5.1.1 High Temperature Reactions; 5.1.2 Flash Vacuum Pyrolysis 327 $a5.1.3 Microwave Reactions5.2 Photochemical Activation; 5.3 Electrochemical Activation; 5.4 Chemical Activation; 5.5 Accumulation of Reactive Species; 5.5.1 The Cation-pool Method; 5.6 Continuous Generation of Reactive Species in a Flow System; 5.7 Interconversion Between Reactive Species; 5.8 Conclusions; References; 6 Control of Extremely Fast Reactions; 6.1 Mixing; 6.1.1 How Does Mixing Take Place?; 6.1.2 Molecular Diffusion and Brownian Motion; 6.1.3 Disguised Chemical Selectivity; 6.1.4 Lowering the Reaction Temperature; 6.1.5 The High Dilution Method; 6.1.6 Micromixing 327 $a6.1.7 Friedel-Crafts Alkylation Using anN-acyliminium Ion Pool6.1.8 Micromixing as a Powerful Tool for Flash Chemistry; 6.1.9 Disguised Chemical Selectivity in Competitive Parallel Reactions; 6.2 Temperature Control; 6.2.1 Exothermicity of Fast Reactions; 6.2.2 Hammond's Postulate; 6.2.3 The Friedel-Crafts Reaction; 6.2.4 Solvent; 6.2.5 Heat Transfer; 6.2.6 Precise Temperature Control in Microflow Systems; 6.3 Residence Time Control; 6.3.1 The Discovery of Benzyne. The Concept of Reactive Intermediates; 6.3.2 o -Bromophenyllithi um; 6.4 Conclusions; References 327 $a7 Microfluidic Devices and Microflow Systems7.1 Brief History; 7.1.1 Microflow Systems for Chemical Analysis; 7.1.2 Microflow Systems for Chemical Synthesis; 7.2 Characteristic Features of Microflow Systems; 7.3 Microstructured Fluidic Devices; 7.3.1 Microchip Reactors; 7.3.2 Microtube Reactors; 7.3.3 Micromixer; 7.3.4 Passive Micromixers; 7.3.5 Microheat Exchanger; 7.3.6 Photochemical Microflow Reactor; 7.3.7 Electrochemical Microflow Reactor; 7.3.8 Catalyst-containing Microflow Reactor; 7.3.9 Microflow Reactors for High-pressure and High-temperature Conditions; 7.4 Conclusions; References 327 $a8 Applications of Flash Chemistry in Organic Synthesis 330 $aHave you ever wished you could speed up your organic syntheses without losing control of the reaction? Flash Chemistry is a new concept which offers an integrated scheme for fast, controlled organic synthesis. It brings together the generation of highly reactive species and their reactions in Microsystems to enable highly controlled organic syntheses on a preparative scale in timescales of a few seconds or less. Flash Chemistry: Fast Organic Synthesis in microsystems is the first book to describe this exciting new technique, with chapters covering:an introduction to f 606 $aOrganic compounds$xSynthesis 606 $aIntermediates (Chemistry) 606 $aMicroreactors 606 $aOrganic reaction mechanisms 608 $aElectronic books. 615 0$aOrganic compounds$xSynthesis. 615 0$aIntermediates (Chemistry) 615 0$aMicroreactors. 615 0$aOrganic reaction mechanisms. 676 $a547.2 676 $a547/.2 700 $aYoshida$b Jun?ichi$f1952-$0855535 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144100303321 996 $aFlash chemistry$91909972 997 $aUNINA LEADER 01365nam a22002651i 4500 001 991001464399707536 005 20031113154715.0 008 040407s1957 it a||||||||||||||||ita 035 $ab12774297-39ule_inst 035 $aARCHE-075392$9ExL 040 $aDip.to Scienze Storiche$bita$cA.t.i. Arché s.c.r.l. 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