LEADER 05417nam 2200649Ia 450 001 9910144005503321 005 20170816121719.0 010 $a1-280-85413-8 010 $a9786610854134 010 $a3-527-60672-6 010 $a3-527-60705-6 035 $a(CKB)1000000000376052 035 $a(EBL)481716 035 $a(OCoLC)70114281 035 $a(SSID)ssj0000253731 035 $a(PQKBManifestationID)11216065 035 $a(PQKBTitleCode)TC0000253731 035 $a(PQKBWorkID)10207710 035 $a(PQKB)11635924 035 $a(MiAaPQ)EBC481716 035 $a(EXLCZ)991000000000376052 100 $a20060620d2005 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aSupercritical carbon dioxide in polymer reaction engineering$b[electronic resource] /$fedited by Maartje F. Kemmere and Thierry Meyer 210 $aWeinheim $cWiley-VCH$dc2005 215 $a1 online resource (361 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31092-4 320 $aIncludes bibliographical references and index. 327 $aSupercritical Carbon Dioxide; Foreword; Preface; Contents; List of Contributors; 1 Supercritical Carbon Dioxide for Sustainable Polymer Processes; 1.1 Introduction; 1.2 Strategic Organic Solvent Replacement; 1.3 Physical and Chemical Properties of Supercritical CO(2); 1.4 Interactions of Carbon Dioxide with Polymers and Monomers; 1.5 Concluding Remarks and Outlook; Notation; References; 2 Phase Behavior of Polymer Systems in High-Pressure Carbon Dioxide; 2.1 Introduction; 2.2 General Phase Behavior in Polymer/Solvent Systems; 2.3 Polymer Solubility in CO(2); 2.4 Thermodynamic Modeling 327 $a2.5 ConclusionsNotation; References; 3 Transport Properties of Supercritical Carbon Dioxide; 3.1 Introduction; 3.2 Hydrodynamics and Mixing; 3.2.1 Laser-Doppler Velocimetry and Computational Fluid Dynamics; 3.2.2 Flow Characteristics; 3.3 Heat Transfer; 3.3.1 Specific for Near-Critical Fluids: the Piston Effect; 3.3.2 Reaction Calorimetry; 3.3.3 Heat Transfer in Stirred Vessel with SCFs; 3.4 Conclusions; Notation; References; 4 Kinetics of Free-Radical Polymerization in Homogeneous Phase of Supercritical Carbon Dioxide; 4.1 Introduction; 4.2 Experimental; 4.3 Initiation; 4.4 Propagation 327 $a4.4.1 Propagation Rate Coefficients4.4.2 Reactivity Ratios; 4.5 Termination; 4.6 Chain Transfer; 4.7 Conclusions; Notation; References; 5 Monitoring Reactions in Supercritical Media; 5.1 Introduction; 5.2 On-line Analytical Methods Used in SCF; 5.2.1 Spectroscopic Methods; 5.2.1.1 FTIR; 5.2.1.2 Raman Spectroscopy; 5.2.1.3 UV/Vis; 5.2.1.4 NMR; 5.2.2 Reflectometry; 5.2.3 Acoustic Methods; 5.3 Calorimetric Methods; 5.3.1 Power Compensation Calorimetry; 5.3.2 Heat Flow Calorimetry; 5.3.2.1 Heat Balance Equations [27]; 5.3.2.2 Determination of Physico-Chemical Parameters 327 $a5.3.2.3 Calorimeter Validation by Heat Generation Simulation5.4 MMA Polymerization as an Example; 5.4.1 Calorimetric Results; 5.4.2 The Coupling of Calorimetry and On-Line Analysis; 5.5 Conclusions; Notation; References; 6 Heterogeneous Polymerization in Supercritical Carbon Dioxide; 6.1 Introduction; 6.2 Literature Review; 6.3 Modeling of the Process; 6.4 Case Study I: MMA Dispersion Polymerization; 6.5 Case Study II: VDF Precipitation Polymerization; 6.6 Concluding Remarks and Outlook; Notation; References; 7 Inverse Emulsion Polymerization in Carbon Dioxide; 7.1 Introduction 327 $a7.2 Inverse Emulsion Polymerization in CO(2): Design Constraints7.3 Surfactant Design for Inverse Emulsion Polymerization; 7.3.1 Designing CO(2)-philic Compounds: What Can We Learn from Fluoropolymer Behavior?; 7.3.2 Non-Fluorous CO(2)-Philes: the Role of Oxygen; 7.4 Inverse Emulsion Polymerization in CO(2): Results; 7.5 Future Challenges; References; 8 Catalytic Polymerization of Olefins in Supercritical Carbon Dioxide; 8.1 Introduction; 8.2 Phase Behavior of Polyolefin-Monomer-CO(2) Systems; 8.2.1 Cloud-Point Measurements on the PEP-Ethylene-CO(2) System 327 $a8.2.2 SAFT Modeling of the PEP-Ethylene-CO(2) System 330 $aRecently, supercritical fluids have emerged as more sustainable alternatives for the organic solvents often used in polymer processes. This is the first book emphasizing the potential of supercritical carbon dioxide for polymer processes from an engineering point of view. It develops a state-of-the-art overview on polymer fundamentals, polymerization reactions and polymer processing in supercritical carbon dioxide. The book covers topics in a multidisciplinary approach starting from polymer chemistry and thermodynamics, going through monitoring, polymerization processes and ending with polymer 606 $aLiquid carbon dioxide 606 $aPolymerization 606 $aSupercritical fluid extraction 608 $aElectronic books. 615 0$aLiquid carbon dioxide. 615 0$aPolymerization. 615 0$aSupercritical fluid extraction. 676 $a660.284248 701 $aKemmere$b Maartje F$0916461 701 $aMeyer$b Thierry$f1961-$0916462 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144005503321 996 $aSupercritical carbon dioxide in polymer reaction engineering$92054449 997 $aUNINA