LEADER 05497nam 2200673Ia 450 001 9910143963603321 005 20170810192812.0 010 $a1-281-08788-2 010 $a9786611087883 010 $a3-527-60674-2 010 $a3-527-60691-2 035 $a(CKB)1000000000375906 035 $a(EBL)481583 035 $a(OCoLC)180273297 035 $a(SSID)ssj0000106160 035 $a(PQKBManifestationID)11130814 035 $a(PQKBTitleCode)TC0000106160 035 $a(PQKBWorkID)10108921 035 $a(PQKB)10167817 035 $a(MiAaPQ)EBC481583 035 $a(iGPub)WILEYB0018591 035 $a(EXLCZ)991000000000375906 100 $a20050207d2005 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aArtificial photosynthesis$b[electronic resource] $efrom basic biology to industrial application /$fedited by Anthony F. Collings and Christa Critchley 205 $a1st ed. 210 $aWeinheim $cWiley-VCH ;$a[Chichester $cJohn Wiley, distributor]$dc2005 215 $a1 online resource (341 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31090-8 320 $aIncludes bibliographical references and index. 327 $aArtificial Photosynthesis; Foreword; Preface; Contents; List of Contributors; Part I The Context; 1 Artificial Photosynthesis: Social and Political Issues; 1.1 Introduction; 1.2 The Need for a Transition to Artificial Photosynthesis; 1.3 Some Associated Social and Political Issues; 1.4 Using the Available Photons: Towards Sustainability Science; 1.5 Conclusions; References; 2 An Integrated Artificial Photosynthesis Model; 2.1 Introduction; 2.2 Natural Photosynthesis; 2.3 Artificial Photosynthesis: An Integrated Strategy; 2.4 A Technological Approach to Photosynthesis 327 $a2.5 Program 1: Biomimetic Photoelectric Generation2.5.1 Milestones; 2.6 Program 2: Electrolytic Hydrogen; 2.6.1 Milestones; 2.7 Programs 3 and 4: Waterless Agriculture; 2.7.1 Program 3: Bioenergetic Converters; 2.7.1.1 Milestones; 2.7.2 Program 4: The CO(2)-fixing Enzyme Reactor; 2.7.2.1 Milestones; 2.8 Conclusions; References; Part II Capturing Sunlight; 3 Broadband Photon-harvesting Biomolecules for Photovoltaics; 3.1 Introduction; 3.2 The Photoelectrochemical Gra?tzel Cell (Dye-sensitized Solar Cell); 3.3 Typical Components and Performance of a DSSC; 3.3.1 Construction and Mode of Operation 327 $a3.3.2 Typical DSSC Performance3.3.3 Device Limitations; 3.4 Melanins as Broadband Sensitizers for DSSCs; 3.4.1 Melanin Basics; 3.4.2 Melanin Chemical, Structural, and Spectroscopic Properties; 3.4.3 Melanin Electrical and Photoconductive Properties; 3.4.4 Melanins as Broadband Photon-harvesting Systems; 3.4.5 A DSSC Based Upon Synthetic Eumelanin; 3.5 Conclusions; References; 4 The Design of Natural Photosynthetic Antenna Systems; 4.1 Introduction; 4.2 Confined Geometries: From Weak to Strong Coupling and Everything in Between 327 $a4.2.1 Conventional Fo?rster Theory: B800 to B800 Intra-band Energy Transfer4.2.2 Generalized Fo?rster Theory: B800 to B850 Inter-band Energy Transfer; 4.2.3 Generalized Fo?rster Theory with the Transition Density Cube Method: Car to Bchl Inter-pigment Energy Transfer; 4.2.4 Modified Redfield Theory: Intra-band B850 Exciton Dynamics; 4.3 Energetic Disorder Within Light-harvesting Complexes; 4.3.1 From Isolated Complexes to Membranes: Disorder in LH2; 4.3.2 Photosystem I; 4.4 Photochemistry and Photoprotection in the Bacterial Reaction Center; 4.5 The Regulation of Photosynthetic Light Harvesting 327 $a4.6 Concluding RemarksReferences; 5 Identifying Redox-active Chromophores in Photosystem II by Low-temperature Optical Spectroscopies; 5.1 Introduction; 5.2 Experimental Methods; 5.2.1 Sample Preparation; 5.2.2 Illumination; 5.2.3 Spectra; 5.3 Results and Discussion; 5.3.1 Absorption and CD Signatures: Plant PSII Cores and BBYs; 5.3.2 Absorption and CD Signatures: Plant and Cyanobacterial PSII Cores; 5.3.3 Absorption Signatures: The Native and Solubilized Reaction Center; 5.3.4 MCD Signatures: P680 and Chl(Z); 5.3.5 Electrochromic Signature: Pheo(D1) in Active PSII; 5.4 Conclusions 327 $a5.4.1 Low-temperature Precision Polarization Spectroscopies 330 $aSince the events crucial to plant photosynthesis are now known in molecular detail, this process is no longer nature's secret, but can for the first time be mimicked by technology. Broad in its scope, this book spans the basics of biological photosynthesis right up to the current approaches for its technical exploitation, making it the most complete resource on artificial photosynthesis ever published. The contents draw on the expertise of the Australian Artificial Photosynthesis Network, currently the world's largest coordinated research effort to develop effective photosynthesis technolo 606 $aBiotechnology 606 $aPhotosynthesis$xIndustrial applications 606 $aPhotosynthesis 608 $aElectronic books. 615 0$aBiotechnology. 615 0$aPhotosynthesis$xIndustrial applications. 615 0$aPhotosynthesis. 676 $a660.6 701 $aCollings$b Anthony F$0978670 701 $aCritchley$b Christa$0978671 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910143963603321 996 $aArtificial photosynthesis$92230615 997 $aUNINA