LEADER 05385nam 22006854a 450 001 9910143567903321 005 20170810185100.0 010 $a1-280-28813-2 010 $a9786610288137 010 $a0-470-30216-X 010 $a0-471-74931-1 010 $a0-471-74930-3 035 $a(CKB)1000000000355885 035 $a(EBL)243676 035 $a(OCoLC)70821410 035 $a(SSID)ssj0000187499 035 $a(PQKBManifestationID)11939165 035 $a(PQKBTitleCode)TC0000187499 035 $a(PQKBWorkID)10134626 035 $a(PQKB)10537206 035 $a(MiAaPQ)EBC243676 035 $a(PPN)143436740 035 $a(EXLCZ)991000000000355885 100 $a20050419d2005 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aKinetics of materials$b[electronic resource] /$fRobert W. Balluffi, Samuel M. Allen, W. Craig Carter ; with editorial assistance from Rachel A. Kemper 210 $aHoboken, N.J. $cJ. Wiley & Sons$d2005 215 $a1 online resource (673 p.) 300 $a"Wiley-Interscience." 311 $a0-471-24689-1 320 $aIncludes bibliographical references and index. 327 $aCONTENTS; Preface; Acknowledgments; Notation; S ymbols-Roman; Symbols-Greek; 1 Introduction; 1.1 Thermodynamics and Kinetics; 1.1.1 Classical Thermodynamics and Constructions of Kinetic Theories; 1.1.2 Averaging; 1.2 Irreversible Thermodynamics and Kinetics; 1.3 Mathematical Background; 1.3.1 Fields; 1.3.2 Variations; 1.3.3 Continuum Limits and Coarse Graining; 1.3.4 Fluxes; 1.3.5 Accumulation; 1.3.6 Conserved and Nonconserved Quantities; 1.3.7 Matrices, Tensors, and the Eigensystem; Bibliography; Exercises; PART I MOTION OF ATOMS AND MOLECULES BY DIFFUSION 327 $a2 Irreversible Thermodynamics: Coupled Forces and Fluxes2.1 Entropy and Entropy Production; 2.1.1 Entropy Production; 2.1.2 Conjugate Forces and Fluxes; 2.1.3 Basic Postulate of Irreversible Thermodynamics; 2.2 Linear Irreversible Thermodynamics; 2.2.1 General Coupling between Forces and Fluxes; 2.2.2 Force-Flux Relations when Extensive Quantities are Constrained; 2.2.3 Introduction of the Diffusion Potential; 2.2.4 Onsager's Symmetry Principle; Bibliography; Exercises; 3 Driving Forces and Fluxes for Diffusion; 3.1 Concentration Gradients and Diffusion 327 $a3.1.1 Self-Diffusion: Diffusion in the Absence of Chemical Effects3.1.2 Self-Diffusion of Component i in a Chemically Homogeneous Binary Solution; 3.1.3 Diffusion of Substitutional Particles in a Chemical Concentration Gradient; 3.1.4 Diffusion of Interstitial Particles in a Chemical Concentration Gradient; 3.1.5 On the Algebraic Signs of Diffusivities; 3.1.6 Summary of Diffusivities; 3.2 Electrical Potential Gradients and Diffusion; 3.2.1 Charged Ions in Ionic Conductors; 3.2.2 Electromigration in Metals; 3.3 Thermal Gradients and Diffusion; 3.4 Capillarity and Diffusion 327 $a3.4.1 The Flux Equation and Diffusion Equation3.4.2 Boundary Conditions; 3.5 Stress and Diffusion; 3.5.1 Effect of Stress on Mobilities; 3.5.2 Stress as a Driving Force for Diffusion: Formation of Solute-Atom Atmosphere around Dislocations; 3.5.3 Influence of Stress on the Boundary Conditions for Diffusion: Diffusional Creep; 3.5.4 Summary of Diffusion Potentials; Bibliography; Exercises; 4 The Diffusion Equation; 4.1 Fick's Second Law; 4.1.1 Linearization of the Diffusion Equation; 4.1.2 Relation of Fick's Second Law to the Heat Equation 327 $a4.1.3 Variational Interpretation of the Diffusion Equation4.2 Constant Diffusivity; 4.2.1 Geometrical Interpretation of the Diffusion Equation when Diffusivity is Constant; 4.2.2 Scaling of the Diffusion Equation; 4.2.3 Superposition; 4.3 Diffusivity as a Function of Concentration; 4.4 Diffusivity as a Function of Time; 4.5 Diffusivity as a Function of Direction; Bibliography; Exercises; 5 Solutions to the Diffusion Equation; 5.1 Steady-State Solutions; 5.1.1 One Dimension; 5.1.2 Cylindrical Shell; 5.1.3 Spherical Shell; 5.1.4 Variable Diffusivity; 5.2 Non-Steady-State Diffusion 327 $a5.2.1 Instantaneous Localized Sources in Infinite Media 330 $aA classroom-tested textbook providing a fundamental understanding of basic kinetic processes in materialsThis textbook, reflecting the hands-on teaching experience of its three authors, evolved from Massachusetts Institute of Technology's first-year graduate curriculum in the Department of Materials Science and Engineering. It discusses key topics collectively representing the basic kinetic processes that cause changes in the size, shape, composition, and atomistic structure of materials. Readers gain a deeper understanding of these kinetic processes and of the properties and applicati 606 $aMaterials$xMechanical properties 606 $aMaterials science 615 0$aMaterials$xMechanical properties. 615 0$aMaterials science. 676 $a541.394 676 $a620.1/1292 676 $a620.11292 700 $aBalluffi$b R. W$0855558 701 $aAllen$b Samuel M$0855559 701 $aCarter$b W. Craig$0855560 701 $aKemper$b Rachel A$0855561 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910143567903321 996 $aKinetics of materials$91910002 997 $aUNINA