LEADER 05492nam 2200697 a 450 001 9910143564203321 005 20200520144314.0 010 $a1-280-28689-X 010 $a9786610286898 010 $a0-470-32429-5 010 $a0-471-74199-X 010 $a0-471-74198-1 035 $a(CKB)1000000000355309 035 $a(EBL)242872 035 $a(SSID)ssj0000159878 035 $a(PQKBManifestationID)11946963 035 $a(PQKBTitleCode)TC0000159878 035 $a(PQKBWorkID)10181781 035 $a(PQKB)10856754 035 $a(Au-PeEL)EBL242872 035 $a(CaPaEBR)ebr10305159 035 $a(CaONFJC)MIL28689 035 $z(PPN)124012345 035 $a(PPN)170224279 035 $a(FR-PaCSA)41000273 035 $a(MiAaPQ)EBC242872 035 $a(OCoLC)85784681 035 $a(EXLCZ)991000000000355309 100 $a20050202d2006 uy 0 101 0 $aeng 135 $aurcn||||||||| 181 $ctxt 182 $cc 183 $acr 200 10$aFundamentals of electrochemistry /$fV.S. Bagotsky 205 $a2nd ed. 210 $aHoboken, N.J. $cWiley-Interscience$dc2006 215 $a1 online resource (752 p.) 225 1 $aThe Electrochemical Society series 300 $aSome chapters translated from Russian by Klaus Muller. 311 $a0-471-70058-4 320 $aIncludes bibliographical references (p. 709-710) and indexes. 327 $aFUNDAMENTALS OF ELECTROCHEMISTRY; CONTENTS; Contributors; Preface to the Second Edition; Preface to the First Edition; List of Photographs; Abbreviations; Symbols; PART I BASIC CONCEPTS; 1. Electric Currents in Ionic Conductors; 1.1 Various Types of Conductors; 1.2 Ions in Electrolyte Solutions; 1.3 Conductivity of Electrolyte Solutions; 1.4 Circuits Involving Ionic Conductors. Electrodes; 1.5 Passage of Current Through Electrodes. Electrode Reactions; 1.6 Classification of Electrodes and Electrode Reactions; 1.7 Faraday's Laws; 1.8 Equations for Mass Balance 327 $a1.9 Sign Convention for Currents and Fluxes 2. Electrode Potentials; 2.1 Interfacial Potential Differences (Galvani Potentials); 2.2 Exchange Currents; 2.3 Open-Circuit Voltages; 2.4 Electrode Potentials; 2.5 Cell Voltage at Nonzero Current; 3. Thermodynamics of Electrochemical Systems; 3.1 Conventional and Undefined Parameters; 3.2 Thermodynamic Functions in Electrochemistry; 3.3 Thermodynamic Activity; 3.4 Equations for the EMF of Galvanic Cells; 3.5 Concentration Dependence of Electrode Potentials; 3.6 Special Thermodynamic Features of Electrode Potentials; 4. Mass Transfer in Electrolytes 327 $a4.1 Basic Laws of Ionic Diffusion in Solutions 4.2 Limiting Diffusion Currents in Electrolytes; 4.3 Ionic Transport by Migration and Diffusion; 4.4 Convective Transport; 5. Phase Boundaries (Interfaces) Between Miscible Electrolytes; 5.1 Types of Interfaces Between Electrolytes; 5.2 Potentials Between Similar Electrolytes (Diffusion Potentials); 5.3 Distribution of the Ions Between Dissimilar but Miscible Electrolytes; 5.4 Distribution of Ions in Cells with Membrane; 5.5 Galvanic Cells with Transference; 6. Polarization of Electrodes; 6.1 Basic Concepts; 6.2 Laws of Activation Polarization 327 $a6.3 Diffusional Concentration Polarization 6.4 Superposition of Concentration and Activation Polarization; 7. Aqueous Electrolyte Solutions; 7.1 Electrolytic Dissociation; 7.2 Ionic Solvation (Hydration) in Solutions; 7.3 Activity of Real Electrolyte Solutions; 7.4 Physical Theories of Ion-Ion Interactions; 8. Nonaqueous Electrolytes; 8.1 Different Types of Electrolytes and Their Practical Utilization; 8.2 Nonaqueous Electrolyte Solutions; 8.3 Ionically Conducting Melts; 8.4 Inorganic Solid Electrolytes; 9. Electron Work Functions and Volta Potentials; 9.1 Surface Potential of a Phase 327 $a9.2 Work Functions 9.3 Volta Potentials; 9.4 Two Problems in Electrochemistry; 10. Structure and Properties of Surface Layers; 10.1 Electrical Structure of Interphases; 10.2 Adsorption Phenomena; 10.3 Thermodynamics of Surface Phenomena; 10.4 Mercury Electrode Surface; 10.5 Platinum Electrode Surface; 10.6 Surfaces of Other Electrodes; 11. Transient Processes; 11.1 Evidence for Transient Conditions; 11.2 Transient Diffusion to Electrodes of Large Size; 11.3 Transient Diffusion to Electrodes of Finite Size; 12. Electrochemical Research Techniques; 12.1 Reference Electrodes 327 $a12.2 Voltage and Electrode Potential Measurements (Potentiometry) 330 $aFundamentals of Electrochemistry provides the basic outline of most topics of theoretical and applied electrochemistry for students not yet familiar with this field, as well as an outline of recent and advanced developments in electrochemistry for people who are already dealing with electrochemical problems.The content of this edition is arranged so that all basic information is contained in the first part of the book, which is now rewritten and simplified in order to make it more accessible and used as a textbook for undergraduate students. More advanced topics, of interest for postgr 410 0$aElectrochemical Society series. 606 $aElectrochemistry 615 0$aElectrochemistry. 676 $a541/.37 700 $aBagotskii$b V. S$g(Vladimir Sergeevich)$0505559 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910143564203321 996 $aFundamentals of electrochemistry$9804568 997 $aUNINA