LEADER 05242nam 2200709Ia 450 001 9910143555903321 005 20170815111539.0 010 $a1-280-23565-9 010 $a9786610235650 010 $a0-470-29481-7 010 $a0-471-74731-9 010 $a0-471-74730-0 035 $a(CKB)1000000000355376 035 $a(EBL)239978 035 $a(OCoLC)70850432 035 $a(SSID)ssj0000261533 035 $a(PQKBManifestationID)11238130 035 $a(PQKBTitleCode)TC0000261533 035 $a(PQKBWorkID)10257207 035 $a(PQKB)10858989 035 $a(MiAaPQ)EBC239978 035 $a(EXLCZ)991000000000355376 100 $a20050802d2006 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aTransition metal-containing polymers$b[electronic resource] /$fedited by Alaa S. Abd-El-Aziz ... [et al.] 210 $aHoboken, NJ $cWiley$dc2006 215 $a1 online resource (235 p.) 225 1 $aMacromolecules containing metal and metal-like elements ;$vv. 6 300 $aDescription based upon print version of record. 311 $a0-471-68445-7 320 $aIncludes bibliographical references and index. 327 $aMacromolecules Containing Metal and Metal-Like Elements Volume 6; Contributors; Contents; Preface; Series Preface; 1. Introduction; I. Coverage; II. General Concepts; III. Historical; IV. Polymers Containing Bis(Cyclopentadienyl) Metal Complexes; A. Polymerization of Olefin-Functionalized Metallocenes; B. Alkyne Metathesis Polymerization of Substituted Metallocenes; C. Polycondensation of Metallocenes; D. Ring-Opening Polymerization; E. Coordination of Metals to Cyclopentadienyl Rings; F. Introduction of Metallocenes into Preformed Polymers; V. Arene-Transition Metal Polymers 327 $aA. Polymerization of Olefin-Containing ArenesB. Ring-Opening Metathesis Polymerization of Substituted Norbornenes; C. Nucleophilic Aromatic Substitution Polymerization of Chloroarene Complexes; D. Polycondensation of Arene Complexes; E. Coordination of Organometallic Moieties to Arenes; F. Supramolecular Assembly of Polymers; VI. Polymers with Metal-Coordinated Cyclobutadienes; VII. Polymers Containing Metal Carbonyl Complexes; VIII. Polymers with Metal-Carbon s-Bonds; A. Transition Metal Polyynes; B. Metal-Aryl and Metal-Alkyl Systems; IX. Metal-Metal Bonded Systems; X. Conclusion 327 $aXI. References2. Lithographic Applications of Highly Metallized Polyferrocenylsilanes; I. Introduction; II. Polyferrocenylsilanes as Electron Beam Lithography Resists; III. Polyferrocenylsilanes as Reactive Ion Etch Resists; IV. Polyferrocenylsilanes as UV Photoresists; V. Conclusions; VI. Acknowledgments; VII. References; 3. Polymers Possessing Reactive Metallacycles in the Mainchain; I. Introduction; II. Synthesis and Reactions of Organometallic Polymers Possessing Metallacycles in the Mainchain; A. Cobaltacyclopentadiene-Containing Polymers 327 $aB. Conversion of Cobaltacyclopentadiene-Containing Polymers into Polymers Possessing Various Mainchain Structuresi. Conversion into Other Organometallic Polymers; ii. Conversion into Organic Polymers with Various Functional Groups in the Mainchain; C. Synthesis and Reactions of Titanacycle-Containing Polymers; i. Polymers Containing Titanacyclopentadiene Unit in the Mainchain; ii. Polymers Possessing Other Titanacycle Units; III. Summary; IV. References; 4. Mechanistic Aspects of the Photodegradation of Polymers Containing Metal-Metal Bonds Along Their Backbones; I. Introduction 327 $aII. General Overview of Polymer PhotodegradationA. The Auto-Oxidation Mechanism; B. Reactions of Hydroperoxide Species That Lead to Backbone Degradation; C. Other Photochemical Degradation Mechanisms; D. Methods for Intentionally Making Polymers Photodegradable; III. Metal-Metal Bond-Containing Polymers; A. Synthesis and Characterization; B. Synthesis of the Difunctional Dimers; C. Synthesis of the Polymers; D. Characterization of the Polymers; E. Photochemical Reactions in Solution; F. Photochemistry in the Solid State; IV. Factors Controlling the Rate of Photochemical Degradation 327 $aA. Cage Effects 330 $aThis series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. The sixth volume in this series provides useful descriptions of the transition metals and their applications, edited by high-quality team of macromolecular experts from around the world. 410 0$aMacromolecules containing metal and metal-like elements ;$vv. 6. 606 $aTransition metal compounds 606 $aMetal complexes 606 $aOrganometallic polymers 606 $aMacromolecules 608 $aElectronic books. 615 0$aTransition metal compounds. 615 0$aMetal complexes. 615 0$aOrganometallic polymers. 615 0$aMacromolecules. 676 $a546.6 676 $a547.7 701 $aAbd-El-Aziz$b Alaa S$0869596 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910143555903321 996 $aTransition metal-containing polymers$91996058 997 $aUNINA