LEADER 05341nam 2200661 a 450 001 9910143508303321 005 20170815113616.0 010 $a1-280-27198-1 010 $a9786610271986 010 $a0-470-32566-6 010 $a0-470-86488-5 010 $a0-470-86786-8 035 $a(CKB)111087027146358 035 $a(EBL)163120 035 $a(OCoLC)52849126 035 $a(SSID)ssj0000216321 035 $a(PQKBManifestationID)11178926 035 $a(PQKBTitleCode)TC0000216321 035 $a(PQKBWorkID)10214808 035 $a(PQKB)10869817 035 $a(MiAaPQ)EBC163120 035 $a(EXLCZ)99111087027146358 100 $a20021024d2003 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aOrganometallic compounds in the environment$b[electronic resource] /$fedited by P.J. Craig 205 $a2nd ed. 210 $a[West Sussex, England] ;$aHoboken, NJ $cJ. Wiley$d2003 215 $a1 online resource (435 p.) 300 $aDescription based upon print version of record. 311 $a0-471-89993-3 320 $aIncludes bibliographical references and index. 327 $aOrganometallic Compounds in the Environment; CONTENTS; List of Contributors; Preface; 1 Occurrence and Pathways of Organometallic Compounds in the Environment-General Considerations; 1.1 Scope of this Work; 1.2 General Approach: Speciation, Concentration and Terminology; 1.3 Types of Organometallic Compound; 1.4 Thermodynamic Stability of Organometallic Compounds; 1.5 Kinetic Stability of Organometallic Compounds; 1.6 Stability of Organometallic Compounds to Atmospheric Oxidation; 1.7 Stability of Organometallics to Water; 1.8 Stability of Organometallics to Light and Atmospheric Reagents 327 $a1.9 Coordination Preferences of Organometallic Species in the Environment1.10 Stability of Organometallic Compounds in Biological Systems; 1.11 General Comments on the Toxicities of Organometallic Compounds; 1.12 General Considerations on Environmental Reactivity of Organometallic Compounds; 1.13 Microbial Biotransformation of Metals and Metalloids; 1.13.1 Introduction; 1.13.2 Reduction and Oxidation; 1.13.3 Methylation and Alkylation; 1.13.4 Mechanisms of Biomethylation; 1.14 Correlation of Quantitative Structure-Activity Relationships with Organotin Molecular Topology and Bioactivity 327 $a1.15 Practical Considerations1.16 References; 2 Organomercury Compounds in the Environment; 2.1 Introduction; 2.2 Human Health Concerns Related to Methylmercury (MMHg); 2.3 Toxicity and Wildlife; 2.4 Analytical Methods; 2.5 Methylmercury Cycling at the Earth's Surface; 2.5.1 Methylmercury in Water; 2.5.2 Methylated Mercury in the Atmosphere; 2.6 Methylmercury Production, Decomposition, and Bioaccumulation; 2.6.1 Pathways of Mercury Methylation; 2.6.2 Pathways of MMHg Demethylation; 2.6.3 Environmental Factors that Affect MMHg Production; 2.6.4 Factors that Affect the Bioaccumulation of MMHg 327 $a2.7 References3 Organotin Compounds in the Environment; 3.1 Introduction; 3.2 Use of TBT in Antifouling Preparations; 3.3 Legislation on TBT; 3.4 Distribution in the Environment; 3.5 Biomethylation; 3.6 Overview of Decay Rates of TBT and other Organotins in Water and Sediments; 3.7 Methods for the Analysis of Organotin Speciation in the Environment; 3.7.1 Sample Preparation Methods; 3.7.2 Analytical Methods Based on Gas Chromatography; 3.7.3 Analytical Methods Based on Liquid Chromatography; 3.7.4 Analytical Methods Based on Other Techniques; 3.7.5 Calibration Techniques 327 $a3.7.6 Certified Reference Methods3.8 General Toxicology of Organotin Compounds; 3.8.1 Human Toxicology; 3.8.2 Bioaccumulation; 3.8.3 Neurotoxicity; 3.8.4 Hepatotoxicity; 3.8.5 Haemolysis; 3.8.6 Immunotoxicity; 3.8.7 Mutagenicity/Genotoxicity; 3.8.8 Carcinogenicity; 3.8.9 Sterility; 3.8.10 Embryotoxicity; 3.8.11 Mechanisms of toxicity; 3.9 References; 4 Organolead Compounds in the Environment; 4.1 Introduction; 4.2 Tetraalkyllead in Gasoline; 4.3 Leaded Gasoline Phaseout; 4.4 Analytical Methods for Organolead Compounds; 4.4.1 Atmospheric Samples; 4.4.2 Water Samples 327 $a4.4.3 Sediment and Soil Samples 330 $aA knowledge of the chemical structure and concentration of organometal compounds throughout the ecosystem is important in working out the pathways and mechanisms by which metals distribute themselves throughout the environment. Treating the topic as an integrated subject area, the Second Edition of Organometallic Compounds in the Environment covers all the recent developments in analytical techniques and reports all the new work that has been achieved since the first book.Covers the general importance and characteristics of organometallic species.Includes gener 606 $aOrganometallic compounds 606 $aEnvironmental chemistry 608 $aElectronic books. 615 0$aOrganometallic compounds. 615 0$aEnvironmental chemistry. 676 $a363.7384 676 $a547.05 676 $a574.5222 701 $aCraig$b P. J.$f1944-$0856088 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910143508303321 996 $aOrganometallic compounds in the environment$91911298 997 $aUNINA