LEADER 05880nam 22008533u 450 001 9910143508003321 005 20221021181528.0 010 $a1-280-27032-2 010 $a9786610270323 010 $a0-470-36296-0 010 $a0-470-85579-7 010 $a0-470-85580-0 035 $a(CKB)111087027148366 035 $a(EBL)153812 035 $a(OCoLC)807996068 035 $a(SSID)ssj0000291044 035 $a(PQKBManifestationID)11217254 035 $a(PQKBTitleCode)TC0000291044 035 $a(PQKBWorkID)10249037 035 $a(PQKB)10569495 035 $a(MiAaPQ)EBC153812 035 $a(EXLCZ)99111087027148366 100 $a20131014d2003|||| u|| | 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aCatalysts for fine chemical synthesis$b[electronic resource] $ehydrolysis, oxidation and reduction 210 $aHoboken $cWiley$d2003 215 $a1 online resource (245 p.) 225 1 $aCatalysts For Fine Chemicals Synthesis ;$vv.7 300 $aDescription based upon print version of record. 311 $a0-471-98123-0 327 $aCatalysts for Fine Chemical Synthesis Volume 1; Contents; Series Preface; Preface to Volume 1; Abbreviations; PART I: REVIEW; 1 The Integration of Biotransformations into the Catalyst Portfolio; 1.1 Hydrolysis of esters, amides, nitriles and oxiranes; 1.2 Reduction reactions; 1.2.1 Reduction of carbonyl compounds; 1.2.2 Reduction of alkenes; 1.3 Oxidative transformations; 1.4 Carbon-carbon bond-forming reactions; 1.5 Conclusions; References; PART II: PROCEDURES; 2 General Information; 3 Asymmetric Epoxidation; 3.1 Introduction; References; 4 Epoxidation of a, b-Unsaturated Carbonyl Compounds 327 $a4.1 Non-asymmetric epoxidation4.2 Asymmetric epoxidation using poly-D-leucine; 4.2.1 Synthesis of leucine N-carboxyanhydride; 4.2.2 Synthesis of immobilized poly-D-leucine; 4.2.3 Asymmetric epoxidation of (E)-benzylideneacetophenone; 4.2.4 Conclusion; 4.3 Asymmetric epoxidation using chiral modified diethylzinc; 4.3.1 Epoxidation of 2-isobutylidene-1-tetralone; 4.3.2 Conclusion; 4.4 Asymmetric epoxidation of (E)-benzylideneacetophenone using the La-(R)-BINOL-Ph(3)PO/cumene hydroperoxide system; 4.4.1 Merits of the system; References; 5 Epoxidation of Allylic Alcohols 327 $a5.1 Non-asymmetric epoxidation5.2 Asymmetric epoxidation using a chiral titanium complex; 5.2.1 Epoxidation of cinnamyl alcohol; 5.2.2 Epoxidation of (E)-2-methyl-3-phenyl-2-propenol; 5.2.3 Epoxidation of (E)-2-hexen-1-ol; 5.2.4 Conclusion; 5.3 Asymmetric epoxidation of (E)-undec-2-en-1-ol using poly(octamethylene tartrate); 5.3.1 Synthesis of branched poly (octamethylene-L-(+)-tartrate); 5.3.2 Asymmetric epoxidation of (E)-undec-2-en-1-ol; References; 6 Epoxidation of Unfunctionalized Alkenes and a, b-Unsaturated Esters 327 $a6.1 Asymmetric epoxidation of disubstituted Z-alkenes using a chiral salen-manganese complex6.1.1 Epoxidation of (Z)-methyl styrene; 6.1.2 Epoxidation of (Z)-ethyl cinnamate; 6.1.3 Conclusion; 6.2 Asymmetric epoxidation of disubstituted E-alkanes using a D-fructose based catalyst; 6.2.1 Epoxidation of (E)-stilbene; 6.2.2 Conclusion; 6.3 Enantioselective epoxidation of (E)-b-methylstyrene by D(2)-symmetric chiral trans-dioxoruthenium (VI) porphyrins; 6.3.1 Preparation of the trans-dioxoruthenium(VI) complexes with D(2)-symmetric porphyrins (H(2)L(1-3)) 327 $a6.3.2 Enantioselective epoxidation of (E)-b-methylstyrene6.3.3 Conclusion; References; 7 Asymmetric Hydroxylation and Aminohydroxylation; 7.1 Asymmetric aminohydroxylation of 4-methoxystyrene; 7.1.1 Conclusion; 7.2 Asymmetric dihydroxylation of (1-cyclohexenyl)acetonitrile; 7.2.1 (R,R)-(1,2-Dihydroxycyclohexyl)acetonitrile acetonide; 7.2.2 Conclusion; References; 8 Asymmetric Sulfoxidation; 8.1 Asymmetric oxidation of sulfides and kinetic resolution of sulfoxides; 8.1.1 Asymmetric oxidation of 4-bromothioanisole; 8.1.2 Kinetic resolution of racemic 4-bromophenyl methyl sulfoxide; References 327 $a9 Asymmetric Reduction of Ketones Using Organometallic Catalysts 330 $aCatalysts are increasingly used by chemists engaged in fine chemical synthesis within both industry and academia. Today, there exists a huge choice of high-tech catalysts, which add enormously to the repertoire of synthetic possibilities. However, catalysts are occasionally capricious, sometimes difficult to use and almost always require both skill and experience in order to achieve optimal results. This series aims to be a practical help for advanced undergraduate, graduate and postgraduate students, as well as experienced chemists in industry and academia working in organic and organometalli 410 0$aCatalysts For Fine Chemicals Synthesis 606 $aCatalysts 606 $aChemistry, Organic 606 $aChemistry, Organic 606 $aEnzymes 606 $aHydrolysis 606 $aOrganic compounds 606 $aOxidation-reduction reaction 606 $aSynthesis 606 $aBiomedical Engineering$2HILCC 606 $aHealth & Biological Sciences$2HILCC 608 $aElectronic books. 615 4$aCatalysts. 615 4$aChemistry, Organic. 615 4$aChemistry, Organic. 615 4$aEnzymes. 615 4$aHydrolysis. 615 4$aOrganic compounds. 615 4$aOxidation-reduction reaction. 615 4$aSynthesis. 615 7$aBiomedical Engineering 615 7$aHealth & Biological Sciences 676 $a660.634 676 $a660/.28443 700 $aRoberts$b Stanley M$0754844 701 $aPoignant$b Geraldine$043932 801 0$bAU-PeEL 801 1$bAU-PeEL 801 2$bAU-PeEL 906 $aBOOK 912 $a9910143508003321 996 $aCatalysts for Fine Chemical Synthesis$92041353 997 $aUNINA