LEADER 05266nam 2200661 a 450 001 9910141639403321 005 20200520144314.0 010 $a1-118-55825-1 010 $a1-118-55840-5 010 $a1-118-55821-9 035 $a(CKB)2670000000340131 035 $a(EBL)1153526 035 $a(OCoLC)831118417 035 $a(SSID)ssj0000835871 035 $a(PQKBManifestationID)11461956 035 $a(PQKBTitleCode)TC0000835871 035 $a(PQKBWorkID)11006485 035 $a(PQKB)10731475 035 $a(OCoLC)847729060 035 $a(MiAaPQ)EBC1153526 035 $a(Au-PeEL)EBL1153526 035 $a(CaPaEBR)ebr10674797 035 $a(CaONFJC)MIL497772 035 $a(PPN)198734980 035 $a(EXLCZ)992670000000340131 100 $a20150303d2013 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aOrbital interactions in chemistry$b[electronic resource] /$fby Thomas A. Albright, Jeremy K. Burdett, Myung-Hwan Whangbo 205 $a2nd ed. 210 $aHoboken, N.J. $cJohn Wiley & Sons$dc2013 215 $a1 online resource (835 p.) 300 $aIncludes index. 311 $a0-471-08039-X 327 $aOrbital Interactions In Chemistry; Contents; Preface; About the Authors; Chapter 1: Atomic and Molecular Orbitals; 1.1 Introduction; 1.2 Atomic Orbitals; 1.3 Molecular Orbitals; Problems; References; Chapter 2: Concepts of Bonding and Orbital Interaction; 2.1 Orbital Interaction Energy; 2.1.1 Degenerate Interaction; 2.1.2 Nondegenerate Interaction; 2.2 Molecular Orbital Coefficients; 2.2.1 Degenerate Interaction; 2.2.2 Nondegenerate Interaction; 2.3 The Two-Orbital Problem-Summary; 2.4 Electron Density Distribution; Problems; References; Chapter 3: Perturbational Molecular Orbital Theory 327 $a3.1 Introduction3.2 Intermolecular Perturbation; 3.3 Linear H3, HF, and the Three-Orbital Problem; 3.4 Degenerate Perturbation; Problems; References; Chapter 4: Symmetry; 4.1 Introduction; 4.2 Symmetry of Molecules; 4.3 Representations of Groups; 4.4 Symmetry Properties of Orbitals; 4.5 Symmetry-Adapted Wavefunctions; 4.6 Direct Products; 4.7 Symmetry Properties, Integrals, and the Noncrossing Rule; 4.8 Principles of Orbital Construction Using Symmetry Principles; 4.9 Symmetry Properties of Molecular Vibrations; Problems; References 327 $aChapter 5: Molecular Orbital Construction from Fragment Orbitals5.1 Introduction; 5.2 Triangular H3; 5.3 Rectangular and Square Planar H4; 5.4 Tetrahedral H4; 5.5 Linear H4; 5.6 Pentagonal H5 and Hexagonal H6; 5.7 Orbitals of Cyclic Systems; Problems; References; Chapter 6: Molecular Orbitals of Diatomic Molecules and Electronegativity Perturbation; 6.1 Introduction; 6.2 Orbital Hybridization; 6.3 Molecular Orbitals of Diatomic Molecules; 6.4 Electronegativity Perturbation; 6.5 Photoelectron Spectroscopy and Through-Bond Conjugation; Problems; References 327 $aChapter 7: Molecular Orbitals and Geometrical Perturbation7.1 Molecular Orbitals of AH2; 7.2 Geometrical Perturbation; 7.3 Walsh Diagrams; 7.4 Jahn-Teller Distortions; 7.4.1 First-Order Jahn-Teller Distortion; 7.4.2 Second-Order Jahn-Teller Distortion; 7.4.3 Three-Center Bonding; 7.5 Bond Orbitals and Photoelectron Spectra Of AH2 Molecules; Problems; References; Chapter 8: State Wavefunctions and State Energies; 8.1 Introduction; 8.2 The Molecular Hamiltonian and State Wavefunctions; 8.3 Fock Operator; 8.4 State Energy; 8.5 Excitation Energy; 8.6 Ionization Potential and Electron Affinity 327 $a8.7 Electron Density Distribution and Magnitudes of Coulomb and Exchange Repulsions8.8 Low versus High Spin States; 8.9 Electron-Electron Repulsion and Charged Species; 8.10 Configuration Interaction; 8.11 Toward More Quantitative Treatments; 8.12 The Density Functional Method; Problems; References; Chapter 9: Molecular Orbitals of Small Building Blocks; 9.1 Introduction; 9.2 The AH System; 9.3 Shapes of AH3 Systems; 9.4 ?-Bonding Effects of Ligands; 9.5 The AH4 System; 9.6 The AHn Series-Some Generalizations; Problems; References; Chapter 10: Molecules with Two Heavy Atoms; 10.1 Introduction 327 $a10.2 A2H6 Systems 330 $a Explains the underlying structure that unites all disciplines in chemistry Now in its second edition, this book explores organic, organometallic, inorganic, solid state, and materials chemistry, demonstrating how common molecular orbital situations arise throughout the whole chemical spectrum. The authors explore the relationships that enable readers to grasp the theory that underlies and connects traditional fields of study within chemistry, thereby providing a conceptual framework with which to think about chemical structure and reactivity problems. Orbital Interactions 606 $aMolecular orbitals 615 0$aMolecular orbitals. 676 $a541/.28 686 $aSCI013050$2bisacsh 700 $aAlbright$b Thomas A$066295 701 $aBurdett$b Jeremy K$066296 701 $aWhangbo$b Myung-Hwan$066297 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910141639403321 996 $aOrbital interactions in chemistry$9377799 997 $aUNINA