LEADER 05787nam 2200769 a 450 001 9910141612203321 005 20200520144314.0 010 $a1-118-35675-6 010 $a1-118-35676-4 010 $a1-118-35674-8 035 $a(CKB)2670000000350741 035 $a(EBL)1173431 035 $a(OCoLC)850147373 035 $a(SSID)ssj0000871798 035 $a(PQKBManifestationID)11478049 035 $a(PQKBTitleCode)TC0000871798 035 $a(PQKBWorkID)10824040 035 $a(PQKB)11508052 035 $a(SSID)ssj0000916944 035 $a(PQKBManifestationID)11485387 035 $a(PQKBTitleCode)TC0000916944 035 $a(PQKBWorkID)10878082 035 $a(PQKB)11722216 035 $a(MiAaPQ)EBC1173431 035 $a(DLC) 2013007823 035 $a(Au-PeEL)EBL1173431 035 $a(CaPaEBR)ebr10691475 035 $a(CaONFJC)MIL484656 035 $a(PPN)199180105 035 $a(EXLCZ)992670000000350741 100 $a20130222d2013 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aLiquid phase oxidation via heterogeneous catalysis$b[electronic resource] $eorganic synthesis and industrial applications /$fedited by Mario G. Clerici, Oxana A. Kholdeeva 210 $aHoboken, N.J. $cWiley$d2013 215 $a1 online resource (548 p.) 300 $aIncludes index. 311 $a0-470-91552-8 320 $aIncludes bibliographical references and index. 327 $aLiquid Phase Oxidation via Heterogeneous Catalysis: Organic Synthesis And Industrial Applications; Contents; Preface; Contributors; Abbreviations; 1 Environmentally Benign Oxidants; 1.1 Introduction; 1.2 Oxygen (Air); 1.3 Alkylhydroperoxides; 1.4 Hydrogen Peroxide; 1.5 Conclusions; References; 2 Oxidation Reactions Catalyzed by Transition-Metal-Substituted Zeolites; 2.1 Introduction; 2.2 Synthesis and Characterization of Zeolites; 2.2.1 Isomorphous Metal Substitution; 2.2.2 Synthesis of Titanium Silicalite-1 (TS-1); 2.2.3 Characterization of Titanium Silicalite-1 (TS-1) 327 $a2.2.4 Ti-Beta, Synthesis and Characterization2.2.5 Other Ti Zeolites; 2.2.6 Other Metal Zeolites; 2.3 Catalytic Properties; 2.3.1 Hydroxylation of Alkanes; 2.3.2 Hydroxylation of Aromatic Compounds; 2.3.3 Oxidation of Olefinic Compounds; 2.3.4 Oxidation of Alcohol and Ether Compounds; 2.3.5 Reactions of Carbonyl Compounds; 2.3.6 Oxidation of N-Compounds; 2.3.7 Oxidation of S-Compounds; 2.4 Mechanistic Aspects; 2.4.1 The Nature of Active Species; 2.4.2 Hydroxylation; 2.4.3 Epoxidation; 2.4.4 Oxidation of Alcohols; 2.4.5 Ammoximation; 2.4.6 Decomposition of Hydrogen Peroxide 327 $a2.4.7 Active Species, Adsorption and Catalytic Activity2.5 Stability of Metal-Substituted Zeolites to Reaction Conditions; 2.6 Conclusions; References; 3 Selective Catalytic Oxidation over Ordered Nanoporous Metallo-Aluminophosphates; 3.1 Introduction; 3.2 Synthesis; 3.2.1 Microporous Aluminophosphates; 3.2.2 Mesoporous Aluminophosphates; 3.3 Characterization; 3.4 Catalytic Properties; 3.4.1 Oxidation of Hydrocarbons; 3.4.2 Oxidation of Olefins; 3.4.3 Oxidation of Alcohols; 3.4.4 Oxidation of Phenols; 3.4.5 Ammoximation and Ammoxidation; 3.4.6 Baeyer-Villiger Oxidation 327 $a3.4.7 Oxidation of Heterocycles3.5 Mechanistic Aspects; 3.6 Catalysts Stability; 3.7 Conclusion; References; 4 Selective Oxidations Catalyzed by Mesoporous Metal Silicates; 4.1 Introduction; 4.2 Synthesis and Characterization; 4.2.1 General Synthetic Approaches; 4.2.2 Characterization Techniques; 4.2.3 Sol-Gel Synthesis of Amorphous Mixed Oxides; 4.2.4 Thermolytic Molecular Precursor Method; 4.2.5 Templated Synthesis of Ordered Metal Silicates; 4.2.6 Postsynthesis Modifications; 4.2.7 Organic-Inorganic Hybrid Materials; 4.3 Catalytic Properties; 4.3.1 Oxidation of Alkanes 327 $a4.3.2 Oxidation of Aromatic Compounds4.3.3 Oxidation of Olefins; 4.3.4 Oxidation of Alcohols; 4.3.5 Oxidation of Ketones and Aldehydes; 4.3.6 Oxidation of S-compounds; 4.3.7 Oxidation of Amines; 4.4 Mechanistic Aspects; 4.5 Stability; 4.5.1 Mechanisms of Deactivation; 4.5.2 Solving Problem of Hydrothermal Stability; 4.5.3 Hydrothermally Stable Catalysts: Scope and Limitations; 4.6 Conclusions and Outlook; References; 5 Liquid Phase Oxidation of Organic Compounds by Supported Metal-Based Catalysts with a Focus on Gold; 5.1 Introduction; 5.2 Catalyst Preparation and Characterization 327 $a5.3 Catalytic Properties 330 $a Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions 606 $aOxidation 606 $aOxidation$xIndustrial applications 606 $aHeterogeneous catalysis 606 $aHeterogeneous catalysis$xIndustrial applications 615 0$aOxidation. 615 0$aOxidation$xIndustrial applications. 615 0$aHeterogeneous catalysis. 615 0$aHeterogeneous catalysis$xIndustrial applications. 676 $a541/.393 701 $aClerici$b Mario G$0963940 701 $aKholdeeva$b Oxana A$0963941 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910141612203321 996 $aLiquid phase oxidation via heterogeneous catalysis$92185983 997 $aUNINA