LEADER 05607nam 2200697Ia 450 001 9910141316503321 005 20230801221954.0 010 $a1-119-94092-3 010 $a1-280-59152-8 010 $a9786613621351 010 $a1-119-94588-7 010 $a1-119-94589-5 035 $a(CKB)2670000000161888 035 $a(EBL)879006 035 $a(OCoLC)784124287 035 $a(SSID)ssj0000622990 035 $a(PQKBManifestationID)11389590 035 $a(PQKBTitleCode)TC0000622990 035 $a(PQKBWorkID)10647936 035 $a(PQKB)10365257 035 $a(MiAaPQ)EBC879006 035 $a(Au-PeEL)EBL879006 035 $a(CaPaEBR)ebr10546537 035 $a(CaONFJC)MIL362135 035 $a(EXLCZ)992670000000161888 100 $a20111227d2012 uy 0 101 0 $aeng 135 $aurcn||||||||| 181 $ctxt 182 $cc 183 $acr 200 04$aThe importance of Pi-interactions in crystal engineering$b[electronic resource] $efrontiers in crystal engineering /$fedited by Edward R.T. Tiekink, Ju?lio Zukerman-Schpector 205 $a2nd ed. 210 $aHoboken, NJ $cWiley$d2012 215 $a1 online resource (402 p.) 300 $aDescription based upon print version of record. 311 $a0-470-68827-0 320 $aIncludes bibliographical references and index. 327 $aThe Importance of Pi-Interactions in Crystal Engineering; Contents; Preface; List of Contributors; 1 The CH/p Hydrogen Bond: Implication in Crystal Engineering; 1.1 Introduction; 1.1.1 Evidence and the Nature of the CH/p Hydrogen Bond; 1.1.2 Directionality of the CH/p Hydrogen Bond; 1.2 Cooperative Effect of the CH/p Hydrogen Bond; 1.2.1 Cooperative Effect as Evidenced by High-Level Ab Initio MO Calculations; 1.2.2 Cooperative Effect as Evidenced by Periodic Ab Initio MO Calculations; 1.2.3 Cooperative Effect as Evidenced by Stabilisation of Materials in Aromatic Nanochannels 327 $a1.2.4 Optical Resolution 1.3 CH/p Hydrogen Bonds in Supramolecular Chemistry; 1.3.1 Crystal Packing; 1.3.2 Lattice Inclusion Type Clathrates; 1.3.3 Cavity Inclusion Type Clathrates; 1.4 Crystallographic Database Analyses; 1.4.1 CH/p Hydrogen Bonds as Evidenced by CSD Analyses; 1.4.2 Systematic CSD Analyses; 1.5 Systematic CSD Analyses of the CH/p Hydrogen Bond; 1.5.1 Method and General Survey of Organic Molecules; 1.5.2 Organometallic Compounds; 1.6 Summary and Outlook; Acknowledgments; References; 2 New Aspects of Aromatic p. . . p and C-H . . . p Interactions in Crystal Engineering 327 $a2.1 Introduction 2.1.1 Planar Aromatic Molecules; 2.1.2 Edge-Face (EF) and Offset Face-Face (OFF) Interactions; 2.1.3 Competition between EF and OFF Interactions; 2.1.4 Edge-Edge (EE) Interactions; 2.2 Three-Dimensional Aromatic Structures; 2.2.1 Aryl . . . Aryl Embrace Interactions; 2.2.2 Design of Heteroaromatic Inclusion Hosts; 2.3 Endo,Endo-Facial Dimers; 2.3.1 The Basic P4AE Interaction Motif; 2.3.2 Discrete Endo,Endo-Facial Dimers; 2.3.3 Aggregated Endo,Endo-Facial Dimers; 2.4 Multiply Halogenated Heteroaromatic Molecules; 2.4.1 The p-Halogen Dimer (PHD) Interaction 327 $a2.4.2 The PHD Unit in Staircase Inclusion Structures 2.4.3 The PHD Unit in Layer Structures; 2.4.4 Switch from Endo,Endo-Facial Dimer to PHD Unit; 2.5 Expansion of the Endo,Endo-Facial Dimer; 2.5.1 Penannular Guest Enclosure; 2.5.2 Types of Molecular Pens; 2.6 (EF)6 Brick-Like Building Blocks; 2.6.1 Phenylated Heteroaromatic Molecules; 2.6.2 Packing of the Bricks; 2.6.3 Different Inclusion Families and Their Convergence; 2.7 Other Novel Multiple Edge-Face Assemblies; 2.7.1 The (EF)2 Handclasp Interaction; 2.7.2 Formation of Hexameric Inclusion Capsules 327 $a2.7.3 Formation of Hexameric Hydrate Clusters 2.8 Other Types of Aryl-Aryl Contacts; 2.8.1 Different OFF Packing Geometries; 2.8.2 Exo,Endo-Facial OFF Interactions; 2.8.3 Exo,Exo-Facial OFF Interactions; 2.8.4 Swivel Interactions; 2.9 Conclusions; Acknowledgments; References; 3 CH-p and p-p Interactions as Contributors to the Guest Binding in Reversible Inclusion and Encapsulation Complexes; 3.1 Introduction; 3.1.1 Theoretical Considerations of Aromatic-Aromatic (p-p) Interactions and CH-p Interactions 327 $a3.2 Probing Aromatic-Aromatic (p-p) Interactions and CH-p Interactions with Solid-State Structures of Reversible Inclusion and Encapsulation Complexes 330 $aCrystal engineers aim to control the way molecules aggregate in the crystalline phase and are therefore concerned with crystal structure prediction, polymorphism, and discovering the relative importance of different types of intermolecular forces and their influence on molecular structure. In order to design crystal structures, knowledge of the types, strengths, and nature of possible intermolecular interactions is essential. Non-covalent interactions involving p-systems is a theme that is under extensive investigation as these interactions can be inductors for the assembly of a vast array of 606 $aMolecular crystals 606 $aSupramolecular organometallic chemistry 606 $aCrystal growth 615 0$aMolecular crystals. 615 0$aSupramolecular organometallic chemistry. 615 0$aCrystal growth. 676 $a548/.3 701 $aTiekink$b Edward R. T$0867117 701 $aZukerman-Schpector$b Ju?lio$0896985 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910141316503321 996 $aThe importance of Pi-interactions in crystal engineering$92004221 997 $aUNINA LEADER 03481nam 2200577 450 001 9910812672003321 005 20230814235207.0 010 $a3-11-056043-7 010 $a3-11-056316-9 024 7 $a10.1515/9783110563160 035 $a(CKB)4340000000210800 035 $a(MiAaPQ)EBC5116193 035 $a(DE-B1597)487461 035 $a(OCoLC)1009212562 035 $a(DE-B1597)9783110563160 035 $a(Au-PeEL)EBL5116193 035 $a(CaPaEBR)ebr11462282 035 $a(EXLCZ)994340000000210800 100 $a20171125h20182018 uy 0 101 0 $ager 135 $aurcnu|||||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 10$aGeschlechtsspezifische ko?rper- und Rollenbilder $eeine korpuslinguistische untersuchung /$fSina Lautenschla?ger 210 1$aBerlin, [Germany] ;$aBoston, [Massachusetts] :$cDe Gruyter,$d2018. 210 4$d©2018 215 $a1 online resource (402 pages) $cillustrations, tables 225 1 $aSprache und Wissen,$x1964-2284 ;$vBand 31 311 $a3-11-056017-8 320 $aIncludes bibliographical references. 327 $tFrontmatter -- $tDanksagung -- $tInhalt -- $tAbbildungs- und Tabellenverzeichnis -- $tEinleitung -- $t1. Konstruktivistische Prämisse und Framesemantik -- $t2. Das Verhältnis von Geschlecht (gender) und Sprache -- $t3. Korpuslinguistik -- $t4. Korpus und Methode -- $t5. Korpuslinguistische Untersuchung: Geschlechtsspezifische Körperund Rollenbilder -- $t6. Zusammenfassung -- $tLiteratur- und Quellenverzeichnis 330 $aAussagen darüber, was männlich oder weiblich ist, was für Männer und Frauen normal oder typisch ist (oder eben nicht ist), finden sich in den Massenmedien in großer Dichte, sowohl explizit als auch implizit. Diese Studie unterzieht bundesdeutsche Pressetexte erstmals einer großangelegten genderlinguistischen Analyse, um der Frage nachzugehen, wie geschlechtsspezifische Körper- und Rollenbilder in diesen Pressetexten mittels und in Sprache (re)produziert und propagiert werden. Zwei sich ergänzende Methoden werden dazu angewendet: die quantitativ verfahrende Korpuslinguistik und die qualitativ angelegte Framesemantik. Auf diese Weise werden typische Sprachgebrauchsmuster mit ihren charakteristischen (Be)Deutungen erkennbar. Da neben einer synchronen auch eine diachrone Analyse durchgeführt wird, lassen sich sowohl Konstanten als auch Veränderungen im Sprachgebrauch erforschen, was Rückschlüsse auf das (jeweils zeitspezifische) gesellschaftliche Wissen erlaubt. 330 $aPress articles convey, propagate, and (re)produce explicit and subliminal gender-specific images of body and role. This corpus linguistic analysis looks at patterns of such explicit and implicit statements about gender, both synchronically and diachronically. The social meanings and interpretations found in the texts are examined using a frame-semantic approach. 410 0$aSprache und Wissen ;$vBand 31. 606 $aGerman philology 610 $acorpus linguistics. 610 $adiscourse. 610 $aframe semantics. 610 $agender role. 615 0$aGerman philology. 676 $a430 686 $aMS 2850$2rvk 700 $aLautenschla?ger$b Sina$01720559 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910812672003321 996 $aGeschlechtsspezifische ko?rper- und Rollenbilder$94119323 997 $aUNINA