LEADER 05364nam 2200697Ia 450 001 9910140705103321 005 20200520144314.0 010 $a9786613140500 010 $a9781283140508 010 $a1283140500 010 $a9783527630554 010 $a3527630554 010 $a9783527630561 010 $a3527630562 035 $a(CKB)2670000000019029 035 $a(EBL)530467 035 $a(OCoLC)741453977 035 $a(SSID)ssj0000420207 035 $a(PQKBManifestationID)11295548 035 $a(PQKBTitleCode)TC0000420207 035 $a(PQKBWorkID)10385607 035 $a(PQKB)10083839 035 $a(MiAaPQ)EBC530467 035 $a(Perlego)2769555 035 $a(EXLCZ)992670000000019029 100 $a20091126d2010 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aIdeas in chemistry and molecular sciences$iAdvances in synthetic chemistry /$fedited by Bruno Pignataro 210 $aWeinheim $cWiley-VCH$d2010 215 $a1 online resource (333 p.) 300 $aDescription based upon print version of record. 311 08$a9783527325399 311 08$a3527325395 320 $aIncludes bibliographical references and index. 327 $aIdeas in Chemistry and Molecular Sciences; Contents; Preface; List of Contributors; Part I Innovative Processes in Organic Chemistry; 1 N-Hydroxy Derivatives: Key Organocatalysts for the Selective Free Radical Aerobic Oxidation of Organic Compounds; 1.1 Introduction; 1.2 General Reactivity of N-Hydroxy Derivatives; 1.3 Aerobic Oxidation Catalyzed by N-Hydroxy Amines; 1.3.1 Aerobic Oxidation of Alcohols to Aldehydes and Ketones; 1.4 Aerobic Oxidation Catalyzed by N-Hydroxy Amides; 1.4.1 Peroxidation of Polyunsaturated Fatty Acids; 1.5 Aerobic Oxidation Catalyzed by N-Hydroxy Imides 327 $a1.5.1 Oxidation of Benzylalcohols to Aldehydes1.5.2 Oxidation of Silanes; 1.5.3 Oxidation of N-Alkylamides; 1.5.4 Oxidation of Tertiary Benzylamines to Aldehydes; 1.5.5 Oxidative Functionalization of Alkylaromatics; 1.5.6 Oxidative Acylation of N-Heteroaromatic Bases; 1.5.7 Aerobic Synthesis of p-Hydroxybenzoic Acids and Diphenols; 1.5.8 Selective Halogenation of Alkanes; 1.5.9 Aerobic Oxidation of Cycloalkanes to Diacids; 1.5.10 Epoxidation of Olefins; 1.5.11 Oxidation of Alkylaromatics; 1.6 Conclusions; Acknowledgments; References 327 $a2 Gold-Catalyzed Intra- and Intermolecular Cycloadditions of Push-Pull Dienynes2.1 Introduction; 2.2 Gold-Catalyzed Enyne Cycloisomerizations; 2.2.1 General Remarks; 2.2.2 Influence of the Electronic Nature of the Alkyne Substituent; 2.2.3 Gold-Catalyzed Cycloaromatization of Push-Pull Dienyne Acids: Synthesis of 2,3-Disubstituted Phenols; 2.3 Gold-Catalyzed Intermolecular Cycloadditions; 2.3.1 Cycloadditions of Enynes, Propargyl Acetylenes, and Alkynyl Cyclopropanes 327 $a2.3.2 Gold-Catalyzed Intermolecular Hetero-Dehydro-Diels-Alder Cycloaddition of Push-Pull Dienynes with Nonactivated Nitriles: Regioselective Synthesis of Pyridines2.4 Conclusions and Future Perspectives; Acknowledgments; References; 3 N-Heterocyclic Carbenes in Copper-Catalyzed Reactions; 3.1 Introduction; 3.2 Preparation of NHC-Containing Copper Complexes; 3.3 Main Applications of [(NHC)Cu] Complexes in Catalysis; 3.4 Copper Hydride-Mediated Reactions; 3.4.1 Hydrosilylation of Carbonyl Compounds; 3.4.2 Mechanistic Considerations; 3.4.3 Related Transformations 327 $a3.5 [3 + 2] Cycloaddition of Azides and Alkynes3.5.1 Click Chemistry; 3.5.2 Use of Internal Alkynes: Mechanistic Implications; 3.6 Concluding Remarks; Acknowledgments; References; 4 Supported Organocatalysts as a Powerful Tool in Organic Synthesis; 4.1 Introduction; 4.2 l-Proline and its Derivatives on Ionic Liquid-Modified Silica Gels; 4.3 Polystyrene-Supported Proline as a Versatile and Recyclable Organocatalyst; 4.3.1 Nonasymmetric Reactions; 4.3.1.1 ?-Selenenylation of Aldehydes; 4.3.1.2 Baylis-Hillman Reaction; 4.3.2 Asymmetric Reactions; 4.3.2.1 Aldol Reaction 327 $a4.4 Prolinamide-Supported Polystyrenes as Highly Stereoselective and Recyclable Organocatalysts for the Aldol Reaction 330 $aWritten by some of the most talented young chemists in Europe, this text covers most of the groundbreaking issues in chemistry. It provides an account of the latest research results in European chemistry based on a selection of leading young scientists participating in the 2008 European Young Chemists Award competition. The contributions range from self-organization to new catalytic synthetic methodologies to organocatalysis. In addition, the authors provide a current overview of their field of research and a preview of future directions.For organic, catalytic, natural products and biochem 517 3 $aAdvances in synthetic chemistry 606 $aChemistry 606 $aOrganic compounds$xSynthesis 606 $aInorganic compounds$xSynthesis 615 0$aChemistry. 615 0$aOrganic compounds$xSynthesis. 615 0$aInorganic compounds$xSynthesis. 676 $a540 701 $aPignataro$b Bruno$0931664 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910140705103321 996 $aIdeas in chemistry and molecular sciences$92111217 997 $aUNINA