LEADER 05174nam 2200625Ia 450 001 9910140558803321 005 20170815170944.0 010 $a1-282-68579-1 010 $a9786612685798 010 $a0-470-66076-7 010 $a0-470-66075-9 035 $a(CKB)2670000000018938 035 $a(EBL)530060 035 $a(OCoLC)630541322 035 $a(SSID)ssj0000418275 035 $a(PQKBManifestationID)11259708 035 $a(PQKBTitleCode)TC0000418275 035 $a(PQKBWorkID)10377353 035 $a(PQKB)11015052 035 $a(MiAaPQ)EBC530060 035 $a(EXLCZ)992670000000018938 100 $a20100106d2010 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aFunctionalized inorganic fluorides$b[electronic resource] $esynthesis, characterization & properties of nanostructured solids /$fedited by Alain Tressaud 210 $aHoboken, NJ $cWiley$d2010 215 $a1 online resource (617 p.) 300 $aDescription based upon print version of record. 311 $a0-470-74050-7 320 $aIncludes bibliographical references and index. 327 $aFunctionalized Inorganic Fluorides; Contents; Preface; List of Contributors; 1 Sol-Gel Synthesis of Nano-Scaled Metal Fluorides - Mechanism and Properties; 1.1 Introduction; 1.1.1 Sol-Gel Syntheses of Oxides - An Intensively Studied and Widely Used Process; 1.1.2 Sol-Gel Syntheses of Metal Fluorides - Overview of Methods; 1.2 Fluorolytic Sol-Gel Synthesis; 1.2.1 Mechanism and Properties; 1.2.2 Insight into Mechanism by Analytical Methods; 1.2.3 Exploring Properties; 1.2.4 Possible Fields of Application; References; 2 Microwave-Assisted Route Towards Fluorinated Nanomaterials; 2.1 Introduction 327 $a2.2 Introduction to Microwave Synthesis2.2.1 A Brief History; 2.2.2 Mechanisms to Generate Heat; 2.2.3 Advantages of Microwave Synthesis; 2.2.4 Examples of Microwave Experiments; 2.3 Preparation of Nanosized Metal Fluorides; 2.3.1 Aluminium-based Fluoride Materials; 2.3.2 Microwave-assisted Synthesis of Transition Metal Oxy-Hydroxy-Fluorides; 2.4 Concluding Remarks; Acknowledgements; References; 3 High Surface Area Metal Fluorides as Catalysts; 3.1 Introduction; 3.2 High Surface Area Aluminium Fluoride as Catalyst; 3.3 Host-Guest Metal Fluoride Systems 327 $a3.4 Hydroxy(oxo)fluorides as Bi-acidic Catalysts3.5 Oxidation Catalysis; 3.6 Metal Fluoride Supported Noble Metal Catalysts; 3.6.1 Hydrodechlorination of Monochlorodifluoromethane; 3.6.2 Hydrodechlorination of Dichloroacetic Acid (DCA); 3.6.3 Suzuki Coupling; References; 4 Investigation of Surface Acidity using a Range of Probe Molecules; 4.1 Introduction; 4.1.1 Setting the Scene: Metal Fluorides versus Metal Oxides; 4.1.2 Some Examples of the Application of FTIR Spectroscopy to the Study of Surface Acidity in Metal Oxides; 4.1.3 A Preview 327 $a4.2 Characterization of Acidity on a Surface: Contrasts with Molecular Fluorides4.2.1 Molecular Brnsted and Molecular Lewis Acids; 4.2.2 A Possible Benchmark for Solid Metal Fluoride, Lewis Acids: Aluminium Chlorofluoride; 4.3 Experimental Methodology; 4.3.1 FTIR Spectroscopy; 4.3.2 Characteristic Reactions and the Detection of Adsorbed Species by a Radiotracer Method; 4.4 Experimental Studies of Surface Acidity; 4.4.1 Using FTIR Spectroscopy; 4.4.2 Using HCl as a Probe with Detection via [36Cl]-Labelling 327 $a4.4.3 Metal Fluoride Surfaces that Contain Surface Hydroxyl Groups: Aluminium Hydroxy Fluorides with the Hexagonal Tungsten Bronze Structure4.4.4 Possible Geometries for HCl Adsorbed at Metal Fluoride Surfaces: Relation to Oxide and Oxyfluoride Surfaces; 4.5 Conclusions; References; 5 Probing Short and Medium Range Order in Al-based Fluorides using High Resolution Solid State Nuclear Magnetic Resonance and Parameter Modelling; 5.1 Introduction; 5.2 High Resolution NMR Techniques; 5.2.1 Fast MAS and High Magnetic Field; 5.2.2 27Al NMR; 5.2.3 High Resolution Correlation NMR Techniques 327 $a5.3 Application to Functionalized Al-Based Fluorides with Catalytic Properties 330 $aFunctionalized Inorganic Fluorides: Synthesis, Characterization & Properties of Nanostructured Solids covers several classes of nanostructured and functionalized inorganic fluorides, oxide-fluorides, and fluorinated oxides such as silica and alumina. Ranging from powders or glass-ceramics to thin layers and coatings, they have applications as more efficient and less aggressive catalysts, UV absorbers, planar optical waveguides, integrated lasers and optical amplifiers, luminescent materials, anti-reflective coatings and high Tc superconductors. With a focus on new types 606 $aFluorides 606 $aFluorine compounds 608 $aElectronic books. 615 0$aFluorides. 615 0$aFluorine compounds. 676 $a546.731 676 $a546/.731 701 $aTressaud$b Alain$0898078 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910140558803321 996 $aFunctionalized inorganic fluorides$92006599 997 $aUNINA