LEADER 05335nam 2200673 450 001 9910140266403321 005 20200520144314.0 010 $a1-118-74484-5 010 $a1-118-74499-3 010 $a1-118-74496-9 035 $a(CKB)2670000000547214 035 $a(EBL)1656363 035 $a(SSID)ssj0001212116 035 $a(PQKBManifestationID)11687651 035 $a(PQKBTitleCode)TC0001212116 035 $a(PQKBWorkID)11206386 035 $a(PQKB)11195922 035 $a(OCoLC)878149535 035 $a(MiAaPQ)EBC1656363 035 $a(Au-PeEL)EBL1656363 035 $a(CaPaEBR)ebr10851641 035 $a(CaONFJC)MIL584594 035 $a(OCoLC)874966748 035 $a(PPN)198219881 035 $a(EXLCZ)992670000000547214 100 $a20140406h20142014 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aInorganic syntheses$hVolume 36 /$f[edited by] Gregory S. Girolami, Alfred P. Satterberger 210 1$aHoboken, New Jersey :$cJohn Wiley & Sons,$d2014. 210 4$dİ2014 215 $a1 online resource (333 p.) 225 1 $aInorganic Syntheses 300 $aDescription based upon print version of record. 311 $a1-118-74487-X 320 $aIncludes bibliographical references and indexes. 327 $aInorganic Syntheses; Preface; Dedication; Notice to Contributors and Checkers; Toxic Substances and Laboratory Hazards; Contents; Chapter One: Transition Metal Halide Compounds; 1. Octahedral Hexatantalum Halide Clusters; A. Tetradecachlorohexatantalum Octahydrate; B. Tetradecabromohexatantalum Octahydrate; C. Tetrakis(benzyltributylammonium) Octadecachlorohexatantalate; 2. Octahedral Hexamolybdenum Halide Clusters; A. Tetradecachlorohexamolybdate Hexahydrate (Chloromolybdic Acid); B. Hexamolybdenum Dodecachloride; 3. Ether Complexes of Molybdenum(III) and Molybdenum(IV) Chlorides 327 $aA. Tetrachlorobis(diethyl ether)molybdenum(IV)B. Trichlorotris(tetrahydrofuran)molybdenum(III); 4. Octahedral Hexatungsten Halide Clusters; A. Bis(hydroxonium) Tetradecachlorohexatungstate Heptahydrate (Chlorotungstic Acid); B. Hexatungsten Dodecachloride; 5. Trinuclear Tungsten Halide Clusters; A. Tritungsten Decachloride; B. Trisodium Tridecachlorotritungstate; C. Tris(benzyltributylammonium) Tridecachlorotritungstate; 6. Crystalline and Amorphous Forms of Tungsten Tetrachloride; A. Crystalline Tungsten Tetrachloride by Solid-State Reduction 327 $aB. Amorphous Tungsten Tetrachloride by Solution-Phase ReductionChapter Two: Cyclopentadienyl Compounds; 7. Sodium and Potassium Cyclopentadienide; A. Sodium Cyclopentadienide; B. Potassium Cyclopentadienide; 8. (Pentafluorophenyl)cyclopentadiene and its Sodium Salt; A. (Pentafluorophenyl)cyclopentadiene; B. Sodium (Pentafluorophenyl)cyclopentadienide; 9. Bis(?5-pentamethylcyclopentadienyl) Complexes of Scandium; A. Bis(?5-pentamethylcyclopentadienyl)chloroscandium; B. Bis(?5-pentamethylcyclopentadienyl)methylscandium; C. Bis(?5-pentamethylcyclopentadienyl)phenylscandium 327 $aD. Bis(?5-pentamethylcyclopentadienyl)(o-tolyl)scandium10. Bis(?5-pentamethylcyclopentadienyl) Complexes of Titanium,Zirconium, and Hafnium; A. Bis(?5-pentamethylcyclopentadienyl)dichlorotitanium(IV); B. Bis(?5-pentamethylcyclopentadienyl)dichlorozirconium(IV); C. Bis(?5-pentamethylcyclopentadienyl)dichlorohafnium(IV); 11. Bis(?5-pentamethylcyclopentadienyl) Complexes of Niobiumand Tantalum; A. Bis(?5-pentamethylcyclopentadienyl)dichlorotantalum(IV); B. Bis(?5-pentamethylcyclopentadienyl)dichloroniobium(IV); 12. Bis(?5-pentamethylcyclopentadienyl) Complexes of Molybdenum 327 $aA. Bis(pentamethylcyclopentadienyl)dichloromolybdenum(IV)B. Bis(pentamethylcyclopentadienyl)dihydridomolybdenum(IV); 13. (?5-Cyclopentadienyl)tricarbonylmanganese(I) Complexes; A. (?5-Cyclopentadienyl)tricarbonylmanganese(I); B. (?5-Pentamethylcyclopentadienyl)tricarbonylmanganese(I); 14. 1,1'-Diaminoferrocene; A. 1,1'-Dilithioferrocene N,N,N',N'-Tetramethylethylenediamine; B. 1,1'-Dibromoferrocene; C. One-Pot Preparation of 1,1'-Dibromoferrocene from Ferrocene; D. 1,1'-Diaminoferrocene; E. 1,1'-Diaminoferrocenium Hexafluorophosphate; F. 1,1'-Diaminoferrocenium Triflate 327 $a15. Mono(?5-pentamethylcyclopentadienyl) Complexes of Osmium 330 $aThis volume of Inorganic Syntheses spans the preparations of wide range of important inorganic, organometallic and solid-state compounds. The volume is divided into 6 chapters. The first chapter contains the syntheses ofsome key early transition metal halide clusters and the very useful mononuclear molybdenum(III) synthon, MoCl3(THF)3. Chapter 2 covers the synthesis of a number of cyclopentadienyl compounds, including a novel route to sodium and potassium cyclopentadienide, MC5H5. Chapter 3 details synthetic procedures for a range of m 410 0$aInorganic Syntheses 606 $aInorganic compounds$xSynthesis 615 0$aInorganic compounds$xSynthesis. 676 $a541.39 702 $aGirolami$b Gregory S. 702 $aSatterberger$b Alfred P. 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910140266403321 996 $aInorganic syntheses$9793039 997 $aUNINA