LEADER 05268nam 2200637Ia 450 001 9910139971003321 005 20230725041237.0 010 $a1-282-38015-X 010 $a9786612380150 010 $a0-470-55700-1 010 $a0-470-55699-4 035 $a(CKB)1000000000822155 035 $a(EBL)469879 035 $a(OCoLC)476311766 035 $a(SSID)ssj0000343454 035 $a(PQKBManifestationID)11947795 035 $a(PQKBTitleCode)TC0000343454 035 $a(PQKBWorkID)10291463 035 $a(PQKB)10059492 035 $a(MiAaPQ)EBC469879 035 $a(Au-PeEL)EBL469879 035 $a(CaPaEBR)ebr10350165 035 $a(CaONFJC)MIL238015 035 $a(EXLCZ)991000000000822155 100 $a20090526d2010 uy 0 101 0 $aeng 135 $aurcn||||||||| 181 $ctxt 182 $cc 183 $acr 200 10$aSyndiotactic polystyrene$b[electronic resource] $esynthesis, characterization, processing, and applications /$fJu?rgen Schellenberg 210 $aHoboken, N.J. $cWiley$dc2010 215 $a1 online resource (486 p.) 300 $aIncludes index. 311 $a0-470-28688-1 327 $aSYNDIOTACTIC POLYSTYRENE; CONTENTS; PREFACE; CONTRIBUTORS; ABOUT THE EDITOR; PART I INTRODUCTION; 1. Historical Overview and Commercialization of Syndiotactic Polystyrene; 1.1 Discovery of Syndiotactic Polystyrene (SPS); 1.2 Early Years of Development (1985-1989); 1.3 Intense Development Years (1989-1996); 1.4 Initial Commercial Launch Stage (1996-2001); 1.5 Years 2001-2007; PART II PREPARATION OF SYNDIOTACTIC POLYSTYRENE; 2. Transition Metal Catalysts for Syndiotactic Polystyrene; 2.1 Introduction; 2.2 Transition Metal Compounds; 2.2.1 Metals; 2.2.2 Titanium Complexes 327 $a2.2.3 Molecular Weight Control 2.2.4 Supported and Heterogeneous Catalysts; 2.3 Summary; References; 3. Cocatalysts for the Syndiospecific Styrene Polymerization; 3.1 Introduction; 3.2 MAO; 3.3 Boron Compounds; 3.4 Other Chemicals; 3.5 Summary; References; 4. Mechanisms for Stereochemical Control in the Syndiotactic Polymerization of Styrene; 4.1 Introduction; 4.2 Insertion of the Growing Polymer Chain into the Double Bond of Styrene; 4.3 Stereochemistry of the Styrene Insertion; 4.4 Effects of Hydrogenation of the Catalyst; 4.5 Active Site Species; 4.5.1 Valence of Active Sites 327 $a4.5.2 Number of Active Sites 4.5.3 Structure of Active Sites; 4.6 Theoretical Analysis of the Catalyst; 4.7 Kinetic Analysis of Styrene Polymerization; 4.8 Conclusions; References; 5. Copolymerization of Ethylene with Styrene: Design of Efficient Transition Metal Complex Catalysts; 5.1 Introduction; 5.2 Ethylene/Styrene Copolymers: Microstructures, Thermal Properties, and Composition Analyses; 5.3 Ethylene/Styrene Copolymerization Using Transition Metal Complex-Cocatalyst Systems; 5.3.1 Half-Titanocenes, Cp ?TiX(3); 5.3.2 Linked (Constrained Geometry Type) Half-Titanocenes 327 $a5.3.3 Modified Half-Titanocenes, C(p ?)Ti(L)X(2)5.3.4 Non-Cp Titanium Complexes; 5.3.5 Metallocenes; 5.3.6 Others; 5.4 Summary and Outlook; References; 6. Structure and Properties of Tetrabenzo[a,c,g,i]fluorenyl-Based Titanium Catalysts; 6.1 Introduction; 6.2 The Tbf Ligand; 6.3 Tbf Lithium; 6.3.1 Synthesis and Characterization of Tbf Lithium; 6.4 Tbf Titanium(III) Derivatives; 6.4.1 Synthesis of Tbf Titanium(III) Chloride Complexes; 6.4.2 Reaction of TbfTi(III)Cl(2)(THF) (VIII) with Radicals; 6.5 Tbf Titanium(IV) Derivatives; 6.5.1 Synthesis of Tbf Titanium Monophenoxide Complexes 327 $a6.6 Dynamic and Polymerization Behavior of Tetrabenzofluorenyl Titanium Complexes 6.6.1 Styrene Polymerization; 6.7 Conclusions; References; 7. Rare-Earth Metal Complexes as Catalysts for Syndiospecific Styrene Polymerization; 7.1 Introduction; 7.2 Metallocene Catalysts; 7.3 Constrained Geometry Catalysts; 7.4 Half-Sandwich Catalysts; 7.5 Nonmetallocene Catalysts; 7.6 Conclusion; References; 8. Syndiospecific Styrene Polymerization with Heterogenized Transition Metal Catalysts; 8.1 Introduction; 8.2 Kinetics of Syndiospecific Polymerization with Heterogeneous Metallocene Catalysts 327 $a8.2.1 Kinetic Profiles of Heterogeneous SPS Polymerization 330 $aSyndiotactic Polystyrene (SPS), synthesized in a laboratory for the first time in 1985, has become commercialized in a very short time, with wide acceptance on the global plastics market. Written by leading experts from academia and industry from all over the world, Syndiotactic Polystyrene offers a comprehensive review of all aspects of SPS of interest to both science and industry, from preparation and properties to applications. This essential reference to SPS covers: The preparation of syndiotactic polystyrene by half-metallocenes and other transition metal catalysts< 606 $aPolystyrene 606 $aMicrocrystalline polymers 615 0$aPolystyrene. 615 0$aMicrocrystalline polymers. 676 $a668.4/233 700 $aSchellenberg$b Ju?rgen$0915331 701 $aSchellenberg$b Ju?rgen$0915331 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910139971003321 996 $aSyndiotactic polystyrene$92051677 997 $aUNINA LEADER 01819 am 22003253u 450 001 9910765705603321 005 20200108 010 $a9783876902241 024 7 $a10.3726/b12468 035 $a(CKB)4100000007523429 035 $a(OAPEN)1003565 035 $a(EXLCZ)994100000007523429 100 $a20200108d|||| uy 101 0 $ager 135 $auuuuu---auuuu 200 10$aBulgarien 1300 210 $aBern$cPeter Lang International Academic Publishers$d1982 215 $a1 online resource (97) 311 $a3-87690-224-X 327 $aHauptprobleme der Geschichte der bulgarischen Sprache / Iv. Duridanov -- Die Entwicklung der bulgarischen Schriftsprache zur Standardsprache / P. Hill -- Eine neue Modaltheorie und ihre Anwendung auf das Bulgarische / R. Kattein -- Die protobulgarischen Sprachreste im Gegenwartsbulgarischen / M. Moskov -- Die Spezifik der bulgarischen Pronomen / R. Nicolova -- Bemerkungen zur Genese der bulgarisch-russischen literarischen Wechselseitigkeit im Mittelalter / A. Schmu?cker. 330 $aVom 9.-17. Mai 1981 führten in Hamburg die Clemens-von-Ohrid Universität Sofia und die Universität Hamburg aus Anlaß des 1300. Jahrestags der Gründung des 1. Bulgarischen Staates eine "bulgarische Woche" durch. In der Sektion "Sprache und Literatur" sprachen vier Wissenschaftler der Clemens-von-Ohrid-Universität und drei von der Universität Hamburg. Die Texte der Referate legen hier vor, auch um sie über Hamburg hinaus bekannt zu machen. 517 $aSlavistische Beitraege vol. 155 606 $aLiterature & literary studies$2bicssc 615 7$aLiterature & literary studies 676 $a491.8/1 701 0$aHill$b Peter M.$f1945-$0706038 906 $aBOOK 912 $a9910765705603321 996 $aBulgarien 1300$93654307 997 $aUNINA