LEADER 05268nam 2200709Ia 450 001 9910139929903321 005 20200520144314.0 010 $a1-282-30810-6 010 $a9786612308109 010 $a3-527-62890-8 010 $a3-527-62891-6 035 $a(CKB)1000000000799870 035 $a(EBL)482226 035 $a(OCoLC)646844927 035 $a(SSID)ssj0000343749 035 $a(PQKBManifestationID)11267374 035 $a(PQKBTitleCode)TC0000343749 035 $a(PQKBWorkID)10291093 035 $a(PQKB)11127448 035 $a(MiAaPQ)EBC482226 035 $a(Au-PeEL)EBL482226 035 $a(CaPaEBR)ebr10342918 035 $a(CaONFJC)MIL230810 035 $a(EXLCZ)991000000000799870 100 $a20091030d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aTomorrow's chemistry today$b[electronic resource] $econcepts in nanoscience, organic materials and environmental chemistry /$fedited by Bruno Pignataro 205 $a2nd ed. 210 $aWeinheim $cWiley-VCH$dc2009 215 $a1 online resource (458 p.) 300 $aDescription based upon print version of record. 311 $a3-527-32623-5 320 $aIncludes bibliographical references and index. 327 $aTomorrow's Chemistry Today: Concepts in Nanoscience, Organic Materials and Environmental Chemistry, Second Edition; Contents; Preface; List of Contributors; Member Societies; Part One: Self-Organization, Nanoscience and Nanotechnology; 1: Subcomponent Self-Assembly as a Route to New Structures and Materials; 1.1 Introduction; 1.2 Aqueous Cu(I); 1.3 Chirality; 1.4 Construction; 1.4.1 Dicopper Helicates; 1.4.2 Tricopper Helicates; 1.4.3 Catenanes and Macrocycles; 1.4.4 [2 x 2] Tetracopper(I) Grid; 1.5 Sorting; 1.5.1 Sorting Ligand Structures with Cu(I); 1.5.2 Simultaneous Syntheses of Helicates 327 $a1.5.3 Sorting within a Structure1.5.4 Cooperative Selection by Iron and Copper; 1.6 Substitution/Reconfiguration; 1.6.1 New Cascade Reaction; 1.6.2 Hammett Effects; 1.6.3 Helicate Reconfigurations; 1.6.4 Substitution as a Route to Polymeric Helicates; 1.7 Conclusion and Outlook; 1.8 Acknowledgments; 2: Molecular Metal Oxides and Clusters as Building Blocks for Functional Nanoscale Architectures and Potential Nanosystems; 2.1 Introduction; 2.2 From POM Building Blocks to Nanoscale Superclusters; 2.3 From Building Blocks to Functional POM Clusters 327 $a2.3.1 Host-Guest Chemistry of POM-based Superclusters2.3.2 Magnetic and Conducting POMs; 2.3.3 Thermochromic and Thermally Switchable POM Clusters; 2.4 Bringing the Components Together-Towards Prototype Polyoxometalate-based Functional Nanosystems; 2.5 Acknowledgments; 3: Nanostructured Porous Materials: Building Matter from the Bottom Up; 3.1 Introduction; 3.2 Synthesis by Organic Molecule Templates; 3.3 Synthesis by Molecular Self-Assembly: Liquid Crystals and Cooperative Assembly; 3.4 Spatially Constrained Synthesis: Foams, Microemulsions, and Molds; 3.4.1 Microemulsions 327 $a3.4.2 Capping Agents3.4.3 Foams; 3.4.4 Molds; 3.5 Multiscale Self-Assembly; 3.6 Biomimetic Synthesis: Toward a Multidisciplinary Approach; 3.7 Acknowledgments; 4: Strategies Toward Hierarchically Structured Optoelectronically Active Polymers; 4.1 Hierarchically Structured Organic Optoelectronic Materials via Self-Assembly; 4.2 Toward Hierarchically Structured Conjugated Polymers via the Foldamer Approach; 4.3 "Self-Assemble, then Polymerize"-A Complementary Approach and Its Requirements; 4.3.1 Topochemical Polymerization Using Self-Assembled Scaffolds 327 $a4.3.2 Self-Assembly of b-Sheet Forming Oligopeptides and Their Polymer Conjugates4.4 Macromonomer Design and Preparation; 4.5 Hierarchical Self-Organization in Organic Solvents; 4.6 A General Model for the Hierarchical Self-Organization of Oligopeptide-Polymer Conjugates; 4.7 Conversion to Conjugated Polymers by UV Irradiation; 4.8 Conclusions and Perspectives; 4.9 Acknowledgments; 5: Mimicking Nature: Bio-inspired Models of Copper Proteins; 5.1 Environmental Pollution: How Can "Green" Chemistry Help?; 5.2 Copper in Living Organisms; 5.2.1 Type 1 Active Site; 5.2.2 Type 2 Active Site 327 $a5.2.3 Type 3 Active Site 330 $aProviding a glimpse into the future, the young scientists contributing here were considered to be the most important for tomorrow's chemistry and materials science. They present the state of the art in their particular fields of research, with topics ranging from new synthetic pathways and nanotechnology to green chemistry.Of major interest to organic chemists, materials scientists and biochemists. 606 $aChemistry, Organic 606 $aNanoscience 606 $aMaterials science 606 $aEnvironmental chemistry 608 $aElectronic books. 615 0$aChemistry, Organic. 615 0$aNanoscience. 615 0$aMaterials science. 615 0$aEnvironmental chemistry. 676 $a547 701 $aPignataro$b Bruno$0931664 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910139929903321 996 $aTomorrow's chemistry today$92101759 997 $aUNINA