LEADER 05228nam 2200637Ia 450 001 9910139924103321 005 20170810193220.0 010 $a1-4443-0974-9 010 $a1-282-29159-9 010 $a9786612291593 010 $a0-470-68200-0 010 $a0-470-68201-9 035 $a(CKB)1000000000800034 035 $a(EBL)470425 035 $a(OCoLC)609849304 035 $a(SSID)ssj0000307858 035 $a(PQKBManifestationID)11226666 035 $a(PQKBTitleCode)TC0000307858 035 $a(PQKBWorkID)10250865 035 $a(PQKB)10107194 035 $a(MiAaPQ)EBC470425 035 $a(PPN)152542000 035 $a(EXLCZ)991000000000800034 100 $a20090414d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aRecoverable and recyclable catalysts$b[electronic resource] /$fedited by Maurizio Benaglia 210 $aHoboken, N.J. $cWiley$d2009 215 $a1 online resource (494 p.) 300 $aDescription based upon print version of record. 311 $a0-470-68195-0 320 $aIncludes bibliographical references and index. 327 $aRecoverable and Recyclable Catalysts; Contents; Preface; Acknowledgements; Contributors; 1 The Experimental Assay of Catalyst Recovery: General Concepts; 1.1 Introduction; 1.2 Catalyst Precursor vs Catalyst; 1.3 Catalyst vs Catalyst Resting State; 1.4 Catalyst Inventory: Loss Mechanisms; 1.4.1 Catalyst Decomposition; 1.4.2 Catalyst Leaching; 1.5 Evaluation of Catalyst Recovery; 1.5.1 Product Yield, Conversion, or TON as a Function of Cycle: Poor and Potentially Deceptive Criteria; 1.5.2 Reaction Rate or TOF as a Function of Cycle; 1.5.3 Gravimetric and Other Assays of Recovered Catalyst 327 $a1.5.4 Special Caveats when 'Residues' are Recycled1.6 Prospective; References; 2 Surface-functionalized Nanoporous Catalysts for Renewable Chemistry; 2.1 Introduction; 2.1.1 Homogeneous Catalysis vs Heterogeneous Catalysis; 2.1.2 Multi-Site vs Single-Site Heterogeneous Catalysis; 2.2 Immobilization Strategies of Heterogeneous Catalysts; 2.2.1 Supported Materials; 2.2.2 Conventional Methods to Functionalize Silica Surfaces; 2.2.3 Alternative Synthesis of Immobilized Complex Catalysts on a Solid Support; 2.2.4 Techniques for Characterization of Heterogeneous Catalysts 327 $a2.3 Efficient Heterogeneous Catalysts with Enhanced Reactivity and Selectivity with Functionality2.3.1 Surface Interaction of Silica and Immobilized Homogeneous Catalysts; 2.3.2 Introduction of Functionalities and Control of Silica Support Morphology; 2.3.3 Selective Surface Functionalization of Solid Support for Utilization of Nanospace Inside the Porous Structure; 2.3.4 Cooperative Catalysis by Multifunctionalized Heterogeneous Catalyst Systems; 2.3.5 Mesoporous Mixed Metal Oxides for Heterogeneous Catalysts; 2.4 Other Heterogeneous Catalyst Systems on Nonsilica Supports; 2.5 Conclusion 327 $aReferences3 Insoluble Resin-supported Catalysts; 3.1 Introduction; 3.2 Transition Metal Catalyzed C-C Bond Formation Reactions; 3.2.1 Pd-catalyzed Reactions; 3.2.2 Asymmetric Additions of Organozinc Reagents to Aldehydes; 3.2.3 Rh-catalyzed Asymmetric Intermolecular C-H Activation; 3.2.4 Cu-catalyzed Asymmetric Cyclopropanation; 3.3 Oxidation; 3.3.1 Oxidation of Sulfides to Sulfoxide; 3.3.2 Oxidation of Alkanes, Alkenes and Alcohols; 3.3.3 Epoxidation of Alkenes; 3.3.4 Asymmetric Hydroformylation of Olefins; 3.3.5 Asymmetric Dihydroxylation of Alkenes; 3.4 Reduction 327 $a3.4.1 Asymmetric Reduction of Ketones3.4.2 Reduction of Carboxamides to Amines; 3.5 Organocatalyzed Reactions; 3.5.1 Asymmetric Aldol Reaction and Aminoxylation; 3.5.2 Asymmetric Tandem Reaction; 3.5.3 Allylation of Aldehydes; 3.5.4 Nucleophilic Substitution Reactions; 3.6 Annulation Reactions; 3.6.1 Cycloaddition; 3.6.2 Intramolecular Hydroamination; 3.7 Miscellaneous; 3.8 Conclusion; References; 4 Catalysts Bound to Soluble Polymers; 4.1 Introduction; 4.2 Soluble Supports - General Considerations; 4.3 Recent Developments of Soluble Polymer-supported Catalysts 327 $a4.3.1 Attachment of Catalysts to Polymer Supports 330 $aDrawing on international research, Recoverable and Recyclable Catalysts provides the essentials on recoverable and recyclable catalysts. This practical guide explores the general principles of catalyst recovery and recycling, catalysts on insoluble or soluble supports, thermoresponsive catalysts, self-supported catalysts, and more. Each chapter combines basic general principles, practical information on the design and synthesis of catalysts, and strategies for catalyst recovery. The book presents a comparison of several different catalytic systems. This textbook is essential for student 606 $aCatalysts$xRecycling 606 $aCatalysis 615 0$aCatalysts$xRecycling. 615 0$aCatalysis. 676 $a541 676 $a541.395 701 $aBenaglia$b Maurizio$0987880 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910139924103321 996 $aRecoverable and recyclable catalysts$92258731 997 $aUNINA