LEADER 05445nam 2200673Ia 450 001 9910139551803321 005 20200520144314.0 010 $a3-527-65046-6 010 $a1-280-66568-8 010 $a9786613642615 010 $a3-527-65044-X 010 $a3-527-65047-4 035 $a(CKB)2550000000100551 035 $a(EBL)915631 035 $a(OCoLC)798928669 035 $a(SSID)ssj0000654420 035 $a(PQKBManifestationID)11398959 035 $a(PQKBTitleCode)TC0000654420 035 $a(PQKBWorkID)10661888 035 $a(PQKB)10382288 035 $a(MiAaPQ)EBC915631 035 $a(Au-PeEL)EBL915631 035 $a(CaPaEBR)ebr10560661 035 $a(CaONFJC)MIL364261 035 $a(PPN)260291935 035 $a(EXLCZ)992550000000100551 100 $a20120528d2012 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aAryl diazonium salts$b[electronic resource] $enew coupling agents in polymer and surface science /$fedited by Mohamed Mehdi Chehimi 210 $aWeinheim, Germany $cWiley-VCH$d2012 215 $a1 online resource (359 p.) 300 $aDescription based upon print version of record. 311 $a3-527-32998-6 320 $aIncludes bibliographical references and index. 327 $aAryl Diazonium Salts: New Coupling Agents in Polymer and Surface Science; Contents; Preface; List of Contributors; 1: Attachment of Organic Layers to Materials Surfaces by Reduction of Diazonium Salts; 1.1: A Brief Survey of the Chemistry and Electrochemistry of Diazonium Salts; 1.2: The Different Methods that Permit Grafting of Diazonium Salts; 1.2.1: Electrochemistry; 1.2.2: Reducing Substrate, Homolytic Dediazonation, Reaction with the Substrate; 1.2.3: Reducing Reagent; 1.2.4: Neutral and Basic Media; 1.2.5: Ultrasonication; 1.2.6: Heating and Microwave; 1.2.7: Mechanical Grafting 327 $a1.2.8: Photochemistry1.3: The Different Substrates, Diazonium Salts, and Solvents that Can Be Used; 1.3.1: Substrates; 1.3.2: Diazonium Salts; 1.3.3: Solvents; 1.4: Evidence for the Presence of a Bond between the Substrate and the Organic Layer; 1.4.1: Stability of the Layer; 1.4.2: Spectroscopic Evidence for a Bond; 1.5: From Monolayers to Multilayers; 1.5.1: Monolayers; 1.5.2: Layers of Medium Thickness; 1.5.2.1 Thick Layers; 1.6: Structure and Formation of Multilayers; 1.6.1: Chemical Structure; 1.6.2: The Spatial Structure of the Layers; 1.6.3: Compactness of the Layers 327 $a1.6.4: Swelling of the Layer1.6.5: Electron Transfer through the Layers; 1.6.6: The Formation Mechanism of Multilayers; 1.7: Conclusion; References; 2: Aryl-Surface Bonding: A Density Functional Theory (DFT)Simulation Approach; 2.1: Introduction; 2.2: Density Functional Theory; 2.3: Bonding between Aryl and Various Substrates; 2.3.1: On Graphite/Graphene; 2.3.1.1 On the Basal Plane; 2.3.1.2 On the Edges of Graphene; 2.3.2: On Carbon Nanotubes; 2.3.3: On Metal Surfaces; 2.4: Summary and Outlook; Acknowledgments; References; 3: Patterned Molecular Layers on Surfaces 327 $a3.1: Methods Based on Scanning Probe Lithography3.1.1: AFM; 3.1.2: SECM; 3.1.3: Spotting; 3.2: Methods Based on Soft Lithography; 3.2.1: Printing; 3.2.2: Molds; 3.2.3: Nanosphere Lithography; 3.3: Methods Based on Lithography; 3.4: Methods Based on Surface-Directed Patterning; 3.4.1: Modification of Si Surfaces; 3.4.2: Modified Electrode Arrays; 3.5: Summary and Conclusions; References; 4: Analytical Methods for the Characterization of Aryl Layers; 4.1: Introduction; 4.2: Scanning Probe Microscopies; 4.3: UV-VIS Spectroscopy: Transmission, Reflection, and Ellipsometry; 4.4: IR Spectroscopy 327 $a4.4.1: Transmission Spectroscopy4.4.2: Reflection Spectroscopy; 4.4.3: Infrared Spectroscopic Ellipsometry (IRSE); 4.4.4: IRSE Surface Characterization; 4.4.5: In Situ IR Spectroscopy: ATR and IRSE; 4.5: Raman Spectroscopy and Surface-Enhanced Raman Scattering (SERS); 4.6: X-ray Photoelectron Spectroscopy (XPS); 4.7: X-ray Standing Waves (XSW); 4.8: Rutherford Backscattering; 4.9: Time of Flight Secondary Ion Mass Spectroscopy; 4.10: Electrochemistry; 4.11: Contact Angle Measurements; 4.12: Conclusion; References; 5: Modification of Nano-objects by Aryl Diazonium Salts; 5.1: Introduction 327 $a5.2: Electrochemical Modification of Nano-objects by Reduction of Diazonium Salts 330 $aDiazonium compounds are employed as a new class of coupling agents to link polymers, biomacromolecules, and other species (e. g. metallic nanoparticles) to the surface of materials. The resulting high performance materials show improved chemical and physical properties and find widespread applications. The advantage of aryl diazonium salts compared to other surface modifiers lies in their ease of preparation, rapid (electro)reduction, large choice of reactive functional groups, and strong aryl-surface covalent bonding.This unique book summarizes the current knowledge of the surface and 606 $aDiazo compounds 606 $aPolymers$xSurfaces 615 0$aDiazo compounds. 615 0$aPolymers$xSurfaces. 676 $a541.33 676 $a547.86 701 $aChehimi$b Mohamed Mehdi$0892059 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910139551803321 996 $aAryl diazonium salts$91992258 997 $aUNINA