LEADER 04550nam 2200625Ia 450 001 9910139542603321 005 20170814175329.0 010 $a1-282-38025-7 010 $a9786612380259 010 $a3-527-62762-6 010 $a3-527-62763-4 035 $a(CKB)2550000000000470 035 $a(EBL)481730 035 $a(OCoLC)520990571 035 $a(SSID)ssj0000337380 035 $a(PQKBManifestationID)11929312 035 $a(PQKBTitleCode)TC0000337380 035 $a(PQKBWorkID)10289513 035 $a(PQKB)10568460 035 $a(MiAaPQ)EBC481730 035 $a(EXLCZ)992550000000000470 100 $a20090625d2010 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aEsterification$b[electronic resource] $emethods, reactions, and applications 205 $a2nd ed. 210 $aWeinheim $cWiley-VCH$dc2010 215 $a1 online resource (388 p.) 300 $aPrevious ed.: 2003. 311 $a3-527-32289-2 320 $aIncludes bibliographical references and index. 327 $aEsterification; Contents; Preface; Preface to the Second Edition; Introduction; Part One: Methodology; 1: Reaction of Alcohols with Carboxylic Acids and their Derivatives; 1.1 Reaction with Carboxylic Acids; 1.1.1 Without Activator; 1.1.2 Acid Catalysts; 1.1.2.1 Brønsted Acids; 1.1.2.2 Lewis Acids; 1.1.2.3 Solid Acids; 1.1.3 Base Activators; 1.1.4 Carbodiimide Activators; 1.1.5 The Mitsunobu Reaction; 1.1.6 Activation of Carboxylic Acids; 1.1.7 Enzymes; 1.1.8 ?-Acids; 1.2 Reaction with Esters: Transesterification; 1.2.1 Without Activator; 1.2.2 Acid Catalysts; 1.2.2.1 Brønsted Acids 327 $a1.2.2.2 Lewis Acids1.2.2.3 Solid Acids; 1.2.3 Base Activators; 1.2.3.1 Metal Salts; 1.2.3.2 Amines; 1.2.3.3 Others; 1.2.4 Other Activators; 1.2.5 Enzymes; 1.3 Reaction with Acid Anhydrides; 1.3.1 Without Activator; 1.3.2 Acid Catalysts; 1.3.2.1 Brønsted Acids; 1.3.2.2 Lewis Acids; 1.3.2.3 Solid Acids; 1.3.3 Base Activators; 1.3.3.1 Metal Salts; 1.3.3.2 Amines; 1.3.3.3 Phosphines; 1.3.4 Enzymes; 1.3.5 Mixed Anhydrides; 1.4 Reaction with Acid Halides and Other Acyl Derivatives; 1.4.1 Without Activator; 1.4.2 Acid Catalysts; 1.4.2.1 Bønsted Acids; 1.4.2.2 Lewis Acids; 1.4.2.3 Solid Acids 327 $a1.4.3 Base Activators1.4.3.1 Metal Salts; 1.4.3.2 Amines; 1.4.3.3 Phase Transfer Catalyst; 1.4.4 Other Activators; 1.4.5 Enzymes; 2: Use of Tin and Other Metal Alkoxides; 3: Conversion of Carboxylic Acids into Esters without Use of Alcohols; 3.1 Reaction with Diazomethane; 3.2 Reaction with Alkyl Halides; 3.3 Treatment with Other Electrophiles; 4: Ester Interchange Reaction; Part Two: Synthetic Applications; 5: Kinetic Resolution; 5.1 Enzymatic Resolution; 5.2 Nonenzymatic Resolution; 5.3 Dynamic Kinetic Resolution; 5.4 Parallel Kinetic Resolution; 6: Asymmetric Desymmetrization 327 $a7: Miscellaneous Topics7.1 Selective Esterification; 7.1.1 Differentiation between Primary, Secondary, and Tertiary Alcohols, and Phenols; 7.1.2 Differentiation between Identical or Similar Functions; 7.2 Use of Theoretical Amounts of Reactants; 7.3 New Reaction Media; 7.4 New Technologies; 7.5 Application to Natural Products Synthesis; 8: Industrial Uses; 8.1 Ethyl Acetate; 8.2 Acrylic Esters; 8.2.1 Methyl Methacrylate (MMA); 8.2.2 Alkyl Acrylates; 8.3 Polyesters; 8.4 Oils and Fats; 8.4.1 Food Emulsifiers; 8.4.2 Soaps; 8.5 Biodiesel Fuel; 8.6 Amino Acid Esters; 8.7 Macrolides 327 $a8.8 Flavoring Agents and Fragrances8.9 Pyrethroids; Epilogue; References; Index 330 $aGathering together the widespread literature in the field, this monograph acts as a reference guide to this very important chemical reaction. Following an introduction, the book goes on to discuss methodology, before treating synthetic and industrial applications -- the latter being a new focus in this completely revised, updated and extended second edition. A must-have for organic, natural products and catalytic chemists, as well as those working in industry, of for lecturers in chemistry. 606 $aEsterification 606 $aChemistry, Organic 608 $aElectronic books. 615 0$aEsterification. 615 0$aChemistry, Organic. 676 $a547.27 700 $aOtera$b Junzo$0902276 701 $aNishikido$b Joji$0972047 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910139542603321 996 $aEsterification$92210105 997 $aUNINA