LEADER 05522nam 2200697Ia 450 001 9910139538903321 005 20230725044917.0 010 $a1-282-38523-2 010 $a9786612385230 010 $a3-527-62882-7 010 $a3-527-62883-5 035 $a(CKB)2550000000000758 035 $a(EBL)481585 035 $a(OCoLC)566109848 035 $a(SSID)ssj0000342645 035 $a(PQKBManifestationID)11252679 035 $a(PQKBTitleCode)TC0000342645 035 $a(PQKBWorkID)10285698 035 $a(PQKB)11138357 035 $a(MiAaPQ)EBC481585 035 $a(EXLCZ)992550000000000758 100 $a20090825d2010 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aScanning tunneling microscopy in surface science, nanoscience and catalysis /$fedited by Michael Bowker and Philip R. Davies 210 $aWeinheim $cWiley-VCH$dc2010 215 $a1 online resource (260 p.) 300 $aDescription based upon print version of record. 311 $a3-527-31982-4 320 $aIncludes bibliographical references and index. 327 $aScanning Tunneling Microscopy in Surface Science, Nanoscience and Catalysis; Contents; Preface; List of Contributors; 1 Chirality at Metal Surfaces; 1.1 Introduction; 1.1.1 Definition of Chirality; 1.1.2 Nomenclature of Chirality: The (R),(S) Convention; 1.2 Surface Chirality Following Molecular Adsorption; 1.2.1 Achiral Molecules on Achiral Surfaces; 1.2.2 Lattice Matching; 1.2.3 Chiral Molecules on Achiral Surfaces; 1.2.4 Chiral Molecules on Chiral Surfaces; 1.2.5 Chiral Etching; 1.3 Chiral Amplification and Recognition; 1.3.1 Chiral Amplification in Two Dimensions; 1.3.2 Chiral Switching 327 $a1.3.3 Chiral Recognition1.3.4 Prochiral Molecules Interacting with Chiral Surfaces; 1.4 Conclusions; References; 2 The Template Route to Nanostructured Model Catalysts; 2.1 Introduction; 2.2 Surfaces as Two-Dimensional Templates; 2.3 STM Imaging of Oxide Films; 2.4 STM Imaging of Metal Particles on Oxide Films; 2.5 Template-Controlled Growth of Model Catalysts; 2.5.1 Oxides as Templates; 2.5.2 Modified Templates; 2.6 Conclusions; References; 3 In Situ STM Studies of Model Catalysts; 3.1 Introduction; 3.2 Instrumentation; 3.3 Visualizing the Pathway of Catalytic Reactions 327 $a3.3.1 Imaging of Adsorbates and Reaction Intermediates3.3.2 Imaging Chemisorption on Metals; 3.3.3 Determining the Sites for Chemisorption on Oxide Surfaces; 3.3.4 Visualizing Reaction Intermediates and the Mechanism of Hydrogen Oxidation; 3.3.5 Measuring the Reaction Kinetics of CO Oxidation; 3.4 Metal Surfaces at High Pressures; 3.5 In Situ Studies of Supported Model Catalysts; 3.5.1 Monitoring the Growth Kinetics of Supported Metal Catalysts; 3.5.2 Studies of the SMSI Effect; 3.5.3 Sintering Kinetics of Supported Au Clusters; 3.6 Outlook; References 327 $a4 Theory of Scanning Tunneling Microscopy and Applications in Catalysis4.1 Catalysis and Scanning Tunneling Microscopy; 4.2 Image Formation in an STM; 4.3 Simulating Tunneling Currents; 4.4 Simulating Chemical Reactivity; 4.5 Catalytic Water Production; 4.5.1 TiO2: A Catalytic Model System; 4.6 Outlook; References; 5 Characterization and Modification of Electrode Surfaces by In Situ STM; 5.1 Introduction; 5.2 In Situ STM: Principle, Technical Realization and Limitations; 5.2.1 Principle Considerations for In Situ Operation; 5.2.2 Technical Realization; 5.2.2.1 Tip Preparation and Isolation 327 $a5.2.2.2 Electrochemical Cell5.2.2.3 Vibration Damping; 5.2.3 Limitations; 5.3 Imaging Single-Crystal Surfaces of Catalytically Relevant Systems; 5.3.1 Preparation and Imaging of Metal Single-Crystal Surfaces; 5.3.2 Bimetallic Surfaces; 5.4 Strategies for Nanostructuring Surfaces; 5.4.1 Oxidation-Reduction Cycles for Roughening and Faceting Surfaces; 5.4.2 Surface Modification by an STM: An Overview; 5.4.3 Metal Nanocluster Deposition via Jump-to-Contact; References; 6 STM Imaging of Oxide Nanolayer Model Systems; 6.1 Introduction; 6.2 Experimental Aspects and Technical Developments 327 $a6.3 Case Studies: Selected Oxide-Metal Systems 330 $aHere, top international authors in the field of STM and surface science present first-class contributions on this hot topic, bringing the reader up to date with the latest developments in this rapidly advancing field. The focus is on the nanoscale, particularly in relation to catalysis, involving developments in our understanding of the nature of the surfaces of oxides and nanoparticulate materials, as well as adsorption, and includes in-situ studies of catalysis on such model materials. Of high interest to practitioners of surface science, nanoscience, STM and catalysis. 606 $aScanning tunneling microscopy 606 $aSurface chemistry 606 $aSurfaces (Physics) 606 $aNanoscience 615 0$aScanning tunneling microscopy. 615 0$aSurface chemistry. 615 0$aSurfaces (Physics) 615 0$aNanoscience. 676 $a502.825 686 $a530$2sdnb 686 $a540$2sdnb 686 $aUH 6320$2rvk 701 $aBowker$b M$g(Michael)$0982670 701 $aDavies$b P. R$g(Philip Rosser),$f1964-$0935902 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910139538903321 996 $aScanning tunneling microscopy in surface science, nanoscience and catalysis$92242608 997 $aUNINA