LEADER 04455nam 2200625Ia 450 001 9910139364603321 005 20200520144314.0 010 $a1-119-96467-9 010 $a1-282-55013-6 010 $a9786612550133 010 $a0-470-68949-8 010 $a0-470-68950-1 035 $a(CKB)2520000000006779 035 $a(EBL)487734 035 $a(OCoLC)605909917 035 $a(SSID)ssj0000423397 035 $a(PQKBManifestationID)11291593 035 $a(PQKBTitleCode)TC0000423397 035 $a(PQKBWorkID)10439177 035 $a(PQKB)10654573 035 $a(MiAaPQ)EBC487734 035 $a(EXLCZ)992520000000006779 100 $a20091021d2010 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aMolecular orbitals and organic chemical reactions /$fIan Fleming 205 $aReference ed. 210 $aHoboken, N.J. $cWiley$d2010 215 $a1 online resource (529 p.) 300 $aDescription based upon print version of record 311 $a0-470-74658-0 320 $aIncludes bibliographical references and index. 327 $aCONTENTS; Preface; 1 Molecular Orbital Theory; 1.1 The Atomic Orbitals of a Hydrogen Atom; 1.2 Molecules Made from Hydrogen Atoms; 1.3 C-H and C-C Bonds; 1.4 Conjugation-Hu?ckel Theory; 1.5 Aromaticity; 1.6 Strained Bonds-Cyclopropanes and Cyclobutanes; 1.7 Heteronuclear Bonds, C-M, C-X and C=O; 1.8 The Tau Bond Model; 1.9 Spectroscopic Methods; 2 Molecular Orbitals and the Structures of Organic Molecules; 2.1 The Effects of Conjugation; 2.2 Hyperconjugation- Conjugation; 2.3 The Configurations and Conformations of Molecules; 2.4 The Effect of Conjugation on Electron Distribution 327 $a2.5 Other Noncovalent Interactions3 Chemical Reactions-How Far and How Fast; 3.1 Factors Affecting the Position of an Equilibrium; 3.2 The Principle of Hard and Soft Acids and Bases (HSAB); 3.3 Transition Structures; 3.4 The Perturbation Theory of Reactivity; 3.5 The Salem-Klopman Equation; 3.6 Hard and Soft Nucleophiles and Electrophiles; 3.7 Other Factors Affecting Chemical Reactivity; 4 Ionic Reactions-Reactivity; 4.1 Single Electron Transfer (SET) in Ionic Reactions; 4.2 Nucleophilicity; 4.3 Ambident Nucleophiles; 4.4 Electrophilicity; 4.5 Ambident Electrophiles; 4.6 Carbenes 327 $a5 Ionic Reactions-Stereochemistry5.1 The Stereochemistry of the FundamentalOrganic Reactions; 5.2 Diastereoselectivity; 6 Thermal Pericyclic Reactions; 6.1 The Four Classes of Pericyclic Reactions; 6.2 Evidence for the Concertedness of Bond Makingand Breaking; 6.3 Symmetry-allowed and Symmetry-forbidden Reactions; 6.4 Explanations for the Woodward-Hoffmann Rules; 6.5 Secondary Effects; 7 Radical Reactions; 7.1 Nucleophilic and Electrophilic Radicals; 7.2 The Abstraction of Hydrogen and Halogen Atoms; 7.3 The Addition of Radicals to Bonds 327 $a7.4 Synthetic Applications of the Chemoselectivity of Radicals7.5 Stereochemistry in some Radical Reactions; 7.6 Ambident Radicals; 7.7 Radical Coupling; 8 Photochemical Reactions; 8.1 Photochemical Reactions in General; 8.2 Photochemical Ionic Reactions; 8.3 Photochemical Pericyclic Reactions and Related Stepwise Reactions; 8.4 Photochemically Induced Radical Reactions; 8.5 Chemiluminescence; References; Index 330 $aWinner of the PROSE Award for Chemistry & Physics 2010 Acknowledging the very best in professional and scholarly publishing, the annual PROSE Awards recognise publishers' and authors' commitment to pioneering works of research and for contributing to the conception, production, and design of landmark works in their fields. Judged by peer publishers, librarians, and medical professionals, Wiley are pleased to congratulate Professor Ian Fleming, winner of the PROSE Award in Chemistry and Physics for Molecular Orbitals and Organic Chemical Reactions. Molecular orbital theory is 606 $aMolecular orbitals 606 $aChemical bonds 606 $aPhysical organic chemistry 615 0$aMolecular orbitals. 615 0$aChemical bonds. 615 0$aPhysical organic chemistry. 676 $a547/.2 700 $aFleming$b Ian$f1935-$0845628 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910139364603321 996 $aMolecular orbitals and organic chemical reactions$91887799 997 $aUNINA