LEADER 05287nam 2200613 a 450 001 9910139248603321 005 20170815104447.0 010 $a1-118-55773-5 010 $a1-299-31531-3 010 $a1-118-61766-5 035 $a(CKB)2560000000100612 035 $a(EBL)1143617 035 $a(OCoLC)830161668 035 $a(SSID)ssj0000833368 035 $a(PQKBManifestationID)11436137 035 $a(PQKBTitleCode)TC0000833368 035 $a(PQKBWorkID)10935619 035 $a(PQKB)11634691 035 $a(MiAaPQ)EBC1143617 035 $a(EXLCZ)992560000000100612 100 $a20130325d2010 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aHandbook of heterogeneous kinematics$b[electronic resource] /$fMichel Soustelle 210 $aLondon $cISTE ;$aHoboken, N.J. $cWiley$d2010 215 $a1 online resource (961 p.) 225 1 $aISTE 300 $aFirst published in 4 volumes entitled: Cine?tique he?te?roge?ne, France : Hermes Science/Lavoisier, 2006 and 2007. 311 $a1-84821-100-7 320 $aIncludes bibliographical references and index. 327 $aCover; Handbook of Heterogenous Kinetics; Title Page; Copyright Page; Table of Contents; Preface; List of Symbols; Chapter 1. Definitions and Experimental Approach; 1.1. Thermal transformations of solids; 1.2. Classification of transformations; 1.2.1. Transformation without formation of a new solid phase; 1.2.2. Transformation with formation of a new solid phase; 1.3. Speed and rate of reaction; 1.3.1. Speed of reaction; 1.3.2. Fractional extent and rate of a reaction; 1.3.3. Volumes of the phases and coefficient of expansion of the reaction; 1.4. Reaction zones of a transformation 327 $a1.4.1. Definition1.4.2. Classification; 1.4.3. Sizes of a reaction zone; 1.5. Chemical characterizations; 1.5.1. Analyses of the gas phases; 1.5.2. Elementary analyses of the solids; 1.6. Structural characterizations of the solids; 1.7. Textural characterizations of the solids; 1.7.1. The marker method; 1.7.2. The cavity method; 1.8. Characterization of the evolution of the systems; 1.8.1. Curves of evolution: definitions; 1.8.2. Curves of evolution: experimental obtaining; 1.8.3. Curves of evolution: obtained laws; 1.9. Influence of various variables on speed; 1.9.1. Influence of temperature 327 $a1.9.2. Influence of partial pressures of gases1.9.3. Influence of the shapes and sizes of solid particles; Chapter 2. The Real Solid: Structure Elements and Quasi-Chemical Reactions; 2.1. Structure elements of a solid; 2.1.1. Definition of a structure element; 2.1.2. Binary solids; 2.1.3. Symbolic notation of structure elements; 2.1.4. Building unit of a solid; 2.1.5. Description and composition of a solid; 2.2. Structure elements of a stoichiometric binary solid; 2.2.1. Schottky disorder; 2.2.2. Frenkel disorder; 2.2.3. Antistructure disorder; 2.2.4. S.A. disorder 327 $a2.3. Structure elements of a non-stoichiometric binary solid2.3.1. Distance from stoichiometry and structure element; 2.3.2. The approximation of Wagner of the prevalent defect for ionic solids; 2.3.3. More complex binary compounds; 2.4. Extension to non-binary compounds; 2.4.1. The pseudo-binary approximation; 2.4.2. Generalization of the approximation of the prevalent defect; 2.5. Quasi-chemical reactions; 2.5.1. Definition and characteristics of quasi-chemical reactions; 2.5.2. Homogenous quasi-chemical reactions in the solid; 2.5.3. The interphase reactions 327 $a2.5.4. Reactions of solid destruction2.6. Introduction of foreign elements into a solid; 2.6.1. Concepts of impurity and doping agent; 2.6.2. The controlled atomic imperfection in stoichiometric solids; 2.6.3. The controlled electronic imperfection in non-stoichiometric solids; 2.6.4. Concept of induced valence; Chapter 3. Thermodynamics of Heterogenous Systems; 3.1. Introduction: aims of thermodynamics; 3.2. General survey of thermodynamics of equilibrium; 3.2.1. Chemical potential of a component in a phase; 3.2.2. Variance of a system at equilibrium 327 $a3.2.3. Associated extensive properties of a transformation, partial molar properties 330 $aThis book presents all the theoretical and practical basements of heterogeneous kinetics and reactivity of solids. It applies the new concepts of reactivity and spatial function, introduced by the author, for both nucleation and growth processes, with a unified presentation of the reactivity of bulk and powder solids, including gas-solid reactions, thermal decompositions, solid-solid reactions, reactions of solid solutions, and coalescence of solid grains. It also contains many exercises and problems with solutions included, allowing readers to understand and use all the concepts and methods d 410 0$aISTE 606 $aChemical kinetics$vHandbooks, manuals, etc 608 $aElectronic books. 615 0$aChemical kinetics 676 $a541.0421 676 $a541/.394 700 $aSoustelle$b Michel$0854349 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910139248603321 996 $aHandbook of heterogeneous kinematics$92250764 997 $aUNINA