LEADER 05335nam 2200637 450 001 9910139131903321 005 20170822111336.0 010 $a1-118-92452-5 010 $a1-118-92453-3 010 $a1-118-92454-1 035 $a(CKB)2550000001338920 035 $a(EBL)1753757 035 $a(OCoLC)885018939 035 $a(SSID)ssj0001340537 035 $a(PQKBManifestationID)11778300 035 $a(PQKBTitleCode)TC0001340537 035 $a(PQKBWorkID)11381034 035 $a(PQKB)10381959 035 $a(MiAaPQ)EBC1753757 035 $a(PPN)20109021X 035 $a(EXLCZ)992550000001338920 100 $a20140815h20142014 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aArrow pushing in inorganic chemistry $ea logical approach to the chemistry of the main group elements /$fAbhik Ghosh, Steffen Berg 210 1$aHoboken, New Jersey :$cJohn Wiley & Sons, Ltd.,$d2014. 210 4$d©2014 215 $a1 online resource (347 p.) 300 $aDescription based upon print version of record. 311 $a1-118-17398-8 311 $a1-322-00785-3 320 $aIncludes bibliographical references and index. 327 $aCover; Title Page; Contents; Foreword; Preface; Acknowledgments; Chapter 1 A Collection of Basic Concepts; 1.1 Nucleophiles and Electrophiles: The SN2 Paradigm; 1.2 What Makes for a Good Nucleophile?; 1.3 Hard and Soft Acids and Bases: The HSAB Principle; 1.4 pKa Values: What Makes for a Good Leaving Group?; 1.5 Redox Potentials; 1.6 Thermodynamic Control: Bond Dissociation Energies (BDEs); 1.7 Bimolecular \beta-Elimination (E2); 1.8 Proton Transfers (PTs); 1.9 Elementary Associative and Dissociative Processes (A and D); 1.10 Two-Step Ionic Mechanisms: The SN2-Si Pathway 327 $a1.11 Two-Step Ionic Mechanisms: The SN1 and E1 Pathways1.12 Electrophilic Addition to Carbon-Carbon Multiple Bonds; 1.13 Electrophilic Substitution on Aromatics: Addition-Elimination; 1.14 Nucleophilic Addition to Carbon-Heteroatom Multiple Bonds; 1.15 Carbanions and Related Synthetic Intermediates; 1.16 Carbenes; 1.17 Oxidative Additions and Reductive Eliminations; 1.18 Migrations; 1.19 Ligand Exchange Reactions; 1.20 Radical Reactions; 1.21 Pericyclic Reactions; 1.22 Arrow Pushing: Organic Paradigms; 1.23 Inorganic Arrow Pushing: Thinking Like a Lone Pair 327 $a1.24 Definitions: Valence, Oxidation State, Formal Charge, and Coordination Number1.25 Elements of Bonding in Hypervalent Compounds; 1.26 The \lambda Convention; 1.27 The Inert Pair Effect; 1.28 Summary; Further Reading; Chapter 2 The s-Block Elements: Alkali and Alkaline Earth Metals; 2.1 Solubility; 2.2 The s-Block Metals as Reducing Agents; 2.3 Reductive Couplings; 2.4 Dissolving Metal Reactions; 2.5 Organolithium and Organomagnesium Compounds; 2.6 Dihydrogen Activation by Frustrated Lewis Pairs (FLPs); 2.7 A MgI-MgI Bond; 2.8 Summary; Further Reading; Chapter 3 Group 13 Elements 327 $a3.1 Group 13 Compounds as Lewis Acids3.2 Hydroboration; 3.3 Group 13-Based Reducing Agents; 3.4 From Borazine to Gallium Arsenide: 13-15 Compounds; 3.5 Low-Oxidation-State Compounds; 3.6 The Boryl Anion; 3.7 Indium-Mediated Allylations; 3.8 Thallium Reagents; 3.9 Summary; Further Reading; Chapter 4 Group 14 Elements; 4.1 Silyl Protecting Groups; 4.2 A Case Study: Peterson Olefination; 4.3 Silanes; 4.4 The \beta-Silicon Effect: Allylsilanes; 4.5 Silyl Anions; 4.6 Organostannanes; 4.7 Polystannanes; 4.8* Carbene and Alkene Analogs; 4.9* Alkyne Analogs; 4.10 Silyl Cations 327 $a4.11 Glycol Cleavage by Lead Tetraacetate4.12 Summary; Further Reading; Chapter 5A Nitrogen; 5A.1 Ammonia and Some Other Common Nitrogen Nucleophiles; 5A.2 Some Common Nitrogen Electrophiles: Oxides, Oxoacids, and Oxoanions; 5A.3 N-N Bonded Molecules: Synthesis of Hydrazine; 5A.4 Multiple Bond Formation: Synthesis of Sodium Azide; 5A.5 Thermal Decomposition of NH4NO2 and NH4NO3; 5A.6 Diazonium Salts; 5A.7 Azo Compounds and Diazene; 5A.8* Imines and Related Functional Groups: The Wolff-Kishner Reduction and the Shapiro Reaction; 5A.9 Diazo Compounds 327 $a5A.10 Nitrenes and Nitrenoids: The Curtius Rearrangement 330 $aInvolved as it is with 95% of the periodic table, inorganic chemistry is one of the foundational subjects of scientific study. Inorganic catalysts are used in crucial industrial processes and the field, to a significant extent, also forms the basis of nanotechnology. Unfortunately, the subject is not a popular one for undergraduates. This book aims to take a step to change this state of affairs by presenting a mechanistic, logical introduction to the subject. Organic teaching places heavy emphasis on reaction mechanisms - ""arrow-pushing"" - and the authors of this book have found that a mec 606 $aChemistry, Inorganic$xExperiments 606 $aChemistry, Inorganic$vLaboratory manuals 615 0$aChemistry, Inorganic$xExperiments. 615 0$aChemistry, Inorganic 676 $a540.151 700 $aGhosh$b Abhik$0878045 702 $aBerg$b Steffen 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910139131903321 996 $aArrow pushing in inorganic chemistry$91960253 997 $aUNINA LEADER 01433nam 2200385 n 450 001 996385746403316 005 20221108052956.0 035 $a(CKB)1000000000609312 035 $a(EEBO)2240956504 035 $a(UnM)99867889 035 $a(EXLCZ)991000000000609312 100 $a19940601d1652 uy | 101 0 $aeng 135 $aurbn||||a|bb| 200 14$aThe secrets of angling$b[electronic resource] $eteaching, the choicest tooles baits and seasons, for the taking of any fish, in pond or river: practised and familiarly opened in three bookes. By J.D. Esquire. Augmented with many approved expe[...]ments. By W. Lauson 210 $aLondon $cPrinted by T.H. for John Hari[son..] and are to be sold by Francis Coles, a[..] his shop in the Old Bayly$d1652 215 $a[70] p 300 $aJ.D. = John Dennys. 300 $aIn verse. 300 $aSignatures: A-D Eā“ (-A1). 300 $aAnnotation in Thomason copy: "Aprill. 6.". 300 $aReproduction of the original in the British Library. 330 $aeebo-0018 606 $aFishing$zEngland$vEarly works to 1800 615 0$aFishing 700 $aDennys$b John$fd. 1609.$01005211 701 $aLawson$b William$ffl. 1618.$01002607 801 0$bCu-RivES 801 1$bCu-RivES 801 2$bCStRLIN 801 2$bWaOLN 906 $aBOOK 912 $a996385746403316 996 $aThe secrets of angling$92310573 997 $aUNISA