LEADER 05714nam 22007933u 450 001 9910139027103321 005 20210114065432.0 010 $a1-118-54037-9 010 $a1-118-54035-2 010 $a1-299-44917-4 010 $a1-118-54036-0 035 $a(CKB)2550000001018576 035 $a(EBL)1160913 035 $a(OCoLC)841906531 035 $a(SSID)ssj0000904818 035 $a(PQKBManifestationID)11582011 035 $a(PQKBTitleCode)TC0000904818 035 $a(PQKBWorkID)10924548 035 $a(PQKB)10155426 035 $a(MiAaPQ)EBC1160913 035 $a(PPN)242544770 035 $a(EXLCZ)992550000001018576 100 $a20131014d2013|||| u|| | 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aLiquid Polymorphism $eAdvances in Chemical Physics$hVolume 152 210 $aHoboken $cWiley$d2013 215 $a1 online resource (654 p.) 225 1 $aAdvances in Chemical Physics, v. 152 300 $aDescription based upon print version of record. 311 $a1-118-45344-1 327 $aLiquid Polymorphism: Advances In Chemical Physics; CONTRIBUTORS TO VOLUME 152; FOREWORD; PREFACE; PREFACE TO THE SERIES; CONTENTS; Electron Spin Resonance Studies of Supercooled Water; I. Introduction; II. Outline of ESR Spectroscopy; A. Spin Probes; B. Rigid-Limit and Motional Narrowing of the Lineshape; C. Accessible Range of the Rotational Dynamics; III. ESR Spectroscopy of Spin Probes: Basic Theoretical Introduction; A. Spin Hamiltonian; B. Lineshape Analysis; 1. No Tumbling: Powder Lineshape; 2. Tumbling: Motional Narrowing of the ESR Lineshape 327 $aIV. ESR Studies of Liquid Water and Aqueous Solutions: A ReviewV. ESR Studies of Confined Water in Polycrystalline Ice; A. Water Confinement in Polycrystalline Ice; B. Location of Paramagnetic Solutes in Water-Ice Mixtures; C. Rotational Dynamics of TEMPOL in Interstitial Water of Polycrystalline Ice; 1. Spin Probe Mobility Above 130K; 2. Dynamical Heterogeneities; 3. Temperature Dependence of the Spin Probe Reorientation; 4. Breakdown of the Debye-Stokes-Einstein Law; 5. Spin Probe Sensing of the Water Static Heterogeneities; 6. Missing Evidence of Additional Impurities in Interstitial Water 327 $aVI. SummaryReferences; Pressure-Driven Liquid-Liquid Transformations and Corresponding Bizarre Viscosity Behavior; I. Introduction; II. Methods; III. Results and Discussions; A. Se; B. AsS; C. As2S3; D. B2O3; IV. Conclusions; References; The Stability Limit and Other Open Questions on Water at Negative Pressure; I. Introduction; II. What is Negative Pressure?; III. The Phase Diagram of Water; IV. Experimental Methods to Generate Tension; A. Acoustic Cavitation; B. Metastable Vapor-Liquid Equilibrium; C. Berthelot Tube; D. Centrifuge Method; V. Limit(s) of Metastability 327 $aA. Comparison Between the Different MethodsB. Origin of the Discrepancy in the Limits of Metastability; C. Remaining Issues with Inclusions; D. Path-Dependent Nucleation; VI. Other Topics in the Study of Liquids Under Tension; A. Equation of State of Water at Negative Pressure; B. Other Properties of Liquid at Negative Pressure; VII. Perspectives; References; Water-Like Anomalies of Core-Softened Fluids: Dependenceon the Trajectories in (P?T ) Space; I. Introduction; II. System and Methods; III. Results and Discussion; A. Diffusion Anomaly; B. Density Anomaly; C. Structural Anomaly 327 $aIV. Rosenfeld ScalingV. Conclusions; References; High-Frequency Dynamics of Liquids Through a Liquid-Liquid Transition: The Case of CS; I. Introduction; II. The Case of Liquid Cesium; III. The Experiment; IV. Results; V. Discussion; VI. Conclusions; References; The Liquid-Liquid Phase Transition, Anomalous Properties, and Glass Behavior of Polymorphic Liquids; I. Introduction; II. Polymorphic Liquids: Phase Diagram, Anomalous Properties, and Glass Behavior; A. Liquid-Liquid Phase Transition; B. Supercritical Region: Anomalous Properties; C. Glass Polymorphism 327 $aIII. Computer Simulation Models of Polymorphic Liquids 330 $aThe Advances in Chemical Physics series-the cutting edge of research in chemical physics The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series presents contributions from internationally renowned chemists and serves as the perfect supplement to any advanced graduate class de 410 0$aAdvances in Chemical Physics ;$vv. 152. 606 $aChemistry, Physical and theoretical 606 $aElectron 606 $aSpectroscopy 606 $aPolymorphism (Crystallography) 606 $aLiquids 606 $aChemical & Materials Engineering$2HILCC 606 $aEngineering & Applied Sciences$2HILCC 606 $aMaterials Science$2HILCC 615 4$aChemistry, Physical and theoretical. 615 4$aElectron. 615 4$aSpectroscopy. 615 0$aPolymorphism (Crystallography) 615 0$aLiquids 615 7$aChemical & Materials Engineering 615 7$aEngineering & Applied Sciences 615 7$aMaterials Science 676 $a541.2 676 $a541.3 700 $aStanley$b H. E$01000560 702 $aStanley$b H. Eugene 801 0$bAU-PeEL 801 1$bAU-PeEL 801 2$bAU-PeEL 906 $aBOOK 912 $a9910139027103321 996 $aLiquid Polymorphism$92296575 997 $aUNINA