LEADER 05442nam 2200613 a 450 001 9910139023803321 005 20200520144314.0 010 $a1-118-59749-4 010 $a1-118-59750-8 010 $a1-299-44941-7 010 $a1-118-59751-6 035 $a(CKB)2550000001018597 035 $a(EBL)1162069 035 $a(OCoLC)836403046 035 $a(MiAaPQ)EBC1162069 035 $a(DLC) 2013008600 035 $a(Au-PeEL)EBL1162069 035 $a(CaPaEBR)ebr10683260 035 $a(CaONFJC)MIL476191 035 $a(PPN)187227896 035 $a(EXLCZ)992550000001018597 100 $a20130422d2013 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 10$aStatistical physics$b[electronic resource] $ean entropic approach /$fIan Ford 210 $aChichester $cWiley$d2013 215 $a1 online resource (282 p.) 300 $aIncludes index. 311 $a1-119-97531-X 311 $a1-119-97530-1 320 $aIncludes bibliographical references and index. 327 $aCover; Title Page; Copyright; Contents; Preface; Chapter 1 Disorder or Uncertainty?; Chapter 2 Classical Thermodynamics; 2.1 The Classical Laws of Thermodynamics; 2.2 Macroscopic State Variables and Thermodynamic Processes; 2.3 Properties of the Ideal Classical Gas; 2.4 Thermodynamic Processing of the Ideal Gas; 2.5 Entropy of the Ideal Gas; 2.6 Entropy Change in Free Expansion of an Ideal Gas; 2.7 Entropy Change due to Nonquasistatic Heat Transfer; 2.8 Cyclic Thermodynamic Processes, the Clausius Inequality and Carnot's Theorem; 2.9 Generality of the Clausius Expression for Entropy Change 327 $a2.10 Entropy Change due to Nonquasistatic Work2.11 Fundamental Relation of Thermodynamics; 2.12 Entropy Change due to Nonquasistatic Particle Transfer; 2.13 Entropy Change due to Nonquasistatic Volume Exchange; 2.14 General Thermodynamic Driving; 2.15 Reversible and Irreversible Processes; 2.16 Statements of the Second Law; 2.17 Classical Thermodynamics: the Salient Points; Exercises; Chapter 3 Applications of Classical Thermodynamics; 3.1 Fluid Flow and Throttling Processes; 3.2 Thermodynamic Potentials and Availability; 3.2.1 Helmholtz Free Energy; 3.2.2 Why Free Energy? 327 $a3.2.3 Contrast between Equilibria3.2.4 Gibbs Free Energy; 3.2.5 Grand Potential; 3.3 Maxwell Relations; 3.4 Nonideal Classical Gas; 3.5 Relationship between Heat Capacities; 3.6 General Expression for an Adiabat; 3.7 Determination of Entropy from a Heat Capacity; 3.8 Determination of Entropy from an Equation of State; 3.9 Phase Transitions and Phase Diagrams; 3.9.1 Conditions for Coexistence; 3.9.2 Clausius-Clapeyron Equation; 3.9.3 The Maxwell Equal Areas Construction; 3.9.4 Metastability and Nucleation; 3.10 Work Processes without Volume Change; 3.11 Consequences of the Third Law 327 $a3.12 Limitations of Classical ThermodynamicsExercises; Chapter 4 Core Ideas of Statistical Thermodynamics; 4.1 The Nature of Probability; 4.2 Dynamics of Complex Systems; 4.2.1 The Principle of Equal a Priori Probabilities; 4.2.2 Microstate Enumeration; 4.3 Microstates and Macrostates; 4.4 Boltzmann's Principle and the Second Law; 4.5 Statistical Ensembles; 4.6 Statistical Thermodynamics: the Salient Points; Exercises; Chapter 5 Statistical Thermodynamics of a System of Harmonic Oscillators; 5.1 Microstate Enumeration; 5.2 Microcanonical Ensemble; 5.3 Canonical Ensemble 327 $a5.4 The Thermodynamic Limit5.5 Temperature and the Zeroth Law of Thermodynamics; 5.6 Generalisation; Exercises; Chapter 6 The Boltzmann Factor and the Canonical Partition Function; 6.1 Simple Applications of the Boltzmann Factor; 6.1.1 Maxwell-Boltzmann Distribution; 6.1.2 Single Classical Oscillator and the Equipartition Theorem; 6.1.3 Isothermal Atmosphere Model; 6.1.4 Escape Problems and Reaction Rates; 6.2 Mathematical Properties of the Canonical Partition Function; 6.3 Two-Level Paramagnet; 6.4 Single Quantum Oscillator; 6.5 Heat Capacity of a Diatomic Molecular Gas 327 $a6.6 Einstein Model of the Heat Capacity of Solids 330 $a"This undergraduate textbook provides students with a statistical mechanical foundation to the classical laws of thermodynamics through a comprehensive treatment of the basics of classical thermodynamics, equilibrium statistical mechanics, irreversible thermodynamics, and statistical mechanics of non-equilibrium phenomena. The concept of entropy is studied starting from the ideal gas law, known to every undergraduate. By considering various thermodynamic processes, it then explores the concept's generality. An accessible style enables undergraduates to easily follow the presentation without much prior knowledge. The focus on entropy distinguishes the book from many other treatments of this subject"--$cProvided by publisher. 330 $a"Focuses from the beginning on entropy as the important quantity and introduces it thoroughly in the context of classical thermodynamics"--$cProvided by publisher. 606 $aStatistical thermodynamics 615 0$aStatistical thermodynamics. 676 $a536.7015195 686 $aSCI065000$2bisacsh 700 $aFord$b Ian$0618953 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910139023803321 996 $aStatistical physics$91070670 997 $aUNINA