LEADER 05306nam 2200709 450 001 9910138963403321 005 20200520144314.0 010 $a1-118-67646-7 010 $a1-118-67644-0 010 $a1-118-67645-9 035 $a(CKB)2550000001189689 035 $a(EBL)1598816 035 $a(SSID)ssj0001108259 035 $a(PQKBManifestationID)11700768 035 $a(PQKBTitleCode)TC0001108259 035 $a(PQKBWorkID)11086664 035 $a(PQKB)10743141 035 $a(OCoLC)858778394 035 $a(MiAaPQ)EBC1598816 035 $a(DLC) 2013038434 035 $a(Au-PeEL)EBL1598816 035 $a(CaPaEBR)ebr10829808 035 $a(CaONFJC)MIL568614 035 $a(OCoLC)869094745 035 $a(PPN)198180314 035 $a(EXLCZ)992550000001189689 100 $a20140209h20142014 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aGreen energetic materials /$fTore Brinck, editor 210 1$aChichester, West Sussex, United Kingdom :$cJohn Wiley & Sons,$d2014. 210 4$dİ2014 215 $a1 online resource (304 p.) 300 $aDescription based upon print version of record. 311 $a1-119-94129-6 311 $a1-306-37363-8 320 $aIncludes bibliographical references and index. 327 $aGreen Energetic Materials; Contents; List of Contributors; Preface; 1. Introduction to Green Energetic Materials; 1.1 Introduction; 1.2 Green Chemistry and Energetic Materials; 1.3 Green Propellants in Civil Space Travel; 1.3.1 Green Oxidizers to Replace Ammonium Perchlorate; 1.3.2 Green Liquid Propellants to Replace Hydrazine; 1.3.3 Electric Propulsion; 1.4 Conclusions; References; 2. Theoretical Design of Green Energetic Materials: Predicting Stability, Detection, Synthesis and Performance; 2.1 Introduction; 2.2 Computational Methods; 2.3 Green Propellant Components; 2.3.1 Trinitramide 327 $a2.3.1.1 Synthesis and Detection2.3.1.2 Properties and Performance; 2.3.2 Energetic Anions Rich in Oxygen and Nitrogen; 2.3.2.1 Trinitrogen Dioxide Anion; 2.3.2.2 1-Nitro-2-oxo-3-Amino-Triazene Anion; 2.3.3 The Pentazolate Anion and its Oxy-Derivatives; 2.3.3.1 Kinetic Stability; 2.3.3.2 Spectroscopic Detection; 2.3.3.3 Synthesis; 2.3.3.4 Performance; 2.3.4 Tetrahedral N4; 2.3.4.1 Potential Energy Surface; 2.3.4.2 Spectroscopic Detection; 2.3.4.3 Synthesis; 2.3.4.4 Thermodynamic Stability and Performance; 2.4 Conclusions; References 327 $a3. Some Perspectives on Sensitivity to Initiation of Detonation3.1 Energetic Materials and Green Chemistry; 3.2 Sensitivity: Some Background; 3.3 Sensitivity Relationships; 3.4 Sensitivity: Some Relevant Factors; 3.4.1 Amino Substituents; 3.4.2 Layered (Graphite-Like) Crystal Lattice; 3.4.3 Free Space in the Crystal Lattice; 3.4.4 Weak Trigger Bonds; 3.4.5 Molecular Electrostatic Potentials; 3.5 Summary; Acknowledgments; References; 4. Advances Toward the Development of "Green" Pyrotechnics; 4.1 Introduction; 4.2 The Foundation of "Green" Pyrotechnics 327 $a4.3 Development of Perchlorate-Free Pyrotechnics4.3.1 Perchlorate-Free Illuminating Pyrotechnics; 4.3.2 Perchlorate-Free Simulators; 4.4 Removal of Heavy Metals from Pyrotechnic Formulations; 4.4.1 Barium-Free Green-Light Emitting Illuminants; 4.4.2 Barium-Free Incendiary Compositions; 4.4.3 Lead-Free Pyrotechnic Compositions; 4.4.4 Chromium-Free Pyrotechnic Compositions; 4.5 Removal of Chlorinated Organic Compounds from Pyrotechnic Formulations; 4.5.1 Chlorine-Free Illuminating Compositions; 4.6 Environmentally Friendly Smoke Compositions 327 $a4.6.1 Environmentally Friendly Colored Smoke Compositions4.6.2 Environmentally Friendly White Smoke Compositions; 4.7 Conclusions; Acknowledgments; Abbreviations; References; 5. Green Primary Explosives; 5.1 Introduction; 5.1.1 What is a Primary Explosive?; 5.1.1.1 Common Initiating Devices: Detonators/Primers/Blasting Caps; 5.1.2 The Case for Green Primary Explosives; 5.1.3 Legacy Primary Explosives; 5.1.3.1 Lead Azide (LA); 5.1.3.2 Lead Styphnate (LS); 5.2 Green Primary Explosive Candidates; 5.2.1 Inorganic Compounds; 5.2.1.1 Silver Azide (SA); 5.2.1.2 Other Inorganic Azides 327 $a5.2.1.3 Nickel Hydrazine Nitrate (NHN) 330 $a Since the end of the 20th century it has been increasingly realised that the use, or production, of many energetic materials leads to the release of substances which are harmful to both humans and the environment. To address this, the principles of green chemistry can be applied to the design of new products and their manufacturing processes, to create green energetic materials that are virtually free of environmental hazards and toxicity issues during manufacturing, storage, use and disposal. Active research is underway to develop new ingredients and formulations, green synthetic methods a 606 $aFuel 606 $aExplosives 606 $aGreen chemistry 615 0$aFuel. 615 0$aExplosives. 615 0$aGreen chemistry. 676 $a662.6 701 $aBrinck$b Tore$0878820 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910138963403321 996 $aGreen energetic materials$91962093 997 $aUNINA