LEADER 05252nam 2200661 a 450 001 9910137856303321 005 20190722112800.0 010 $a3-527-63600-5 010 $a1-283-14092-6 010 $a9786613140920 010 $a3-527-63599-8 010 $a3-527-63601-3 035 $a(CKB)3280000000000152 035 $a(EBL)697811 035 $a(OCoLC)739118524 035 $a(SSID)ssj0000543910 035 $a(PQKBManifestationID)11381928 035 $a(PQKBTitleCode)TC0000543910 035 $a(PQKBWorkID)10532501 035 $a(PQKB)11495647 035 $a(MiAaPQ)EBC697811 035 $a(PPN)168391619 035 $a(EXLCZ)993280000000000152 100 $a20111121d2011 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aHomogeneous catalysts$b[electronic resource] $eactivity, stability, deactivation /$fPiet W.N.M. van Leeuwen and John C. Chadwick 210 $aWeinheim, Germany $cWiley -VCH$dc2011 215 $a1 online resource (420 p.) 300 $aDescription based upon print version of record 311 $a3-527-32329-5 320 $aIncludes bibliographic references and index 327 $aHomogeneous Catalysts: Activity - Stability - Deactivation; Contents; Preface; 1 Elementary Steps; 1.1 Introduction; 1.2 Metal Deposition; 1.2.1 Ligand Loss; 1.2.2 Loss of H+, Reductive Elimination of HX; 1.2.3 Reductive Elimination of C-, N-, O-Donor Fragments; 1.2.4 Metallic Nanoparticles; 1.3 Ligand Decomposition by Oxidation; 1.3.1 General; 1.3.2 Oxidation; 1.3.2.1 Catalysis Using O2; 1.3.2.2 Catalysis Using Hydroperoxides; 1.4 Phosphines; 1.4.1 Introduction; 1.4.2 Oxidation of Phosphines; 1.4.3 Oxidative Addition of a P-C Bond to a Low-Valent Metal 327 $a1.4.4 Nucleophilic Attack at Phosphorus1.4.5 Aryl Exchange Via Phosphonium Intermediates; 1.4.6 Aryl Exchange Via Metallophosphoranes; 1.5 Phosphites; 1.6 Imines and Pyridines; 1.7 Carbenes; 1.7.1 Introduction to NHCs as Ligands; 1.7.2 Reductive Elimination of NHCs; 1.7.3 Carbene Decomposition in Metathesis Catalysts; 1.8 Reactions of Metal-Carbon and Metal-Hydride Bonds; 1.8.1 Reactions with Protic Reagents; 1.8.2 Reactions of Zirconium and Titanium Alkyl Catalysts; 1.9 Reactions Blocking the Active Sites; 1.9.1 Polar Impurities; 1.9.2 Dimer Formation; 1.9.3 Ligand Metallation; References 327 $a2 Early Transition Metal Catalysts for Olefin Polymerization2.1 Ziegler-Natta Catalysts; 2.1.1 Introduction; 2.1.2 Effect of Catalyst Poisons; 2.1.3 TiCl3 Catalysts; 2.1.4 MgCl2-supported Catalysts; 2.1.4.1 MgCl2/TiCl4/Ethyl Benzoate Catalysts; 2.1.4.2 MgCl2/TiCl4/Diester Catalysts; 2.1.4.3 MgCl2/TiCl4/Diether Catalysts; 2.1.5 Ethene Polymerization; 2.2 Metallocenes; 2.2.1 Introduction; 2.2.2 Metallocene/MAO Systems; 2.2.3 Metallocene/Borate Systems; 2.3 Other Single-Center Catalysts; 2.3.1 Constrained Geometry and Half-Sandwich Complexes; 2.3.2 Octahedral Complexes 327 $a2.3.3 Diamide and Other Complexes2.4 Vanadium-Based Catalysts; 2.5 Chromium-Based Catalysts; 2.6 Conclusions; References; 3 Late Transition Metal Catalysts for Olefin Polymerization; 3.1 Nickel- and Palladium-based Catalysts; 3.1.1 Diimine Complexes; 3.1.2 Neutral Nickel(II) Complexes; 3.1.3 Other Nickel(II) and Palladium(II) Complexes; 3.2 Iron- and Cobalt-based Catalysts; 3.2.1 Bis(imino)Pyridyl Complexes; 3.3 Conclusions; References; 4 Effects of Immobilization of Catalysts for Olefin Polymerization; 4.1 Introduction; 4.2 Metallocenes and Related Complexes 327 $a4.2.1 Immobilized MAO/Metallocene Systems4.2.2 Immobilized Borane and Borate Activators; 4.2.3 Superacidic Supports; 4.2.4 MgCl2-Supported Systems; 4.3 Other Titanium and Zirconium Complexes; 4.3.1 Constrained Geometry Complexes; 4.3.2 Octahedral Complexes; 4.4 Vanadium Complexes; 4.5 Chromium Complexes; 4.6 Nickel Complexes; 4.7 Iron Complexes; 4.8 Conclusions; References; 5 Dormant Species in Transition Metal-Catalyzed Olefin Polymerization; 5.1 Introduction; 5.2 Ziegler-Natta Catalysts; 5.2.1 Ethene Polymerization; 5.2.2 Propene Polymerization 327 $a5.3 Metallocenes and Related Early Transition Metal Catalysts 330 $aThis first book to illuminate this important aspect of chemical synthesis improves the lifetime of catalysts, thus reducing material and saving energy, costs and waste.The international panel of expert authors describes the studies that have been conducted concerning the way homogeneous catalysts decompose, and the differences between homogeneous and heterogeneous catalysts. The result is a ready reference for organic, catalytic, polymer and complex chemists, as well as those working in industry and with/on organometallics 606 $aCatalysts 606 $aAlkenes 615 0$aCatalysts. 615 0$aAlkenes. 676 $a541.395 676 $a660.2995 676 $a660/.2995 700 $aLeeuwen$b P. W. N. M. van$g(Piet W. N. M.)$043994 701 $aChadwick$b John C$0983425 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910137856303321 996 $aHomogeneous catalysts$92244980 997 $aUNINA