LEADER 05305nam 22006613u 450 001 9910133857603321 005 20210114214918.0 010 $a3-527-65223-X 010 $a3-527-65225-6 010 $a1-299-47604-X 010 $a3-527-65226-4 035 $a(CKB)3360000000455833 035 $a(EBL)1158353 035 $a(OCoLC)833766359 035 $a(SSID)ssj0000904709 035 $a(PQKBManifestationID)12446841 035 $a(PQKBTitleCode)TC0000904709 035 $a(PQKBWorkID)10921887 035 $a(PQKB)10730259 035 $a(MiAaPQ)EBC1158353 035 $a(EXLCZ)993360000000455833 100 $a20130418d2013|||| u|| | 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aAsymmetric Synthesis II$b[electronic resource] $eMore Methods and Applications 210 $aWeinheim $cWiley$d2013 215 $a1 online resource (432 p.) 300 $aDescription based upon print version of record. 311 $a3-527-32921-8 327 $aAsymmetric Synthesis; Contents; List of Contributors; 1 Catalytic Enantioselective Alkylation of Prochiral Ketone Enolates; Background; Strategy and Results; Asymmetric Allylic Alkylation in Total Synthesis; Conclusions; CV of Corey M. Reeves; CV of Brian M. Stoltz; References; 2 Point-to-Planar Chirality Transfer in Total Synthesis: Scalable and Programmable Synthesis of Haouamine A and Its Atropisomer; Introduction; Synthetic Strategy Featuring Point-to-Planar Chirality Transfer; Programmable Synthesis of Haouamine A and Its Atropisomer; CV of Noah Z. Burns; CV of Phil S. Baran; References 327 $a3 Tethered AminohydroxylationIntroduction and Background; Tethered Aminohydroxylation; a) First Generation of Reoxidants; b) N-Sulfonyloxy Carbamates; c) Carbonyloxycarbamates as Reoxidants for Osmium; Amide-Based Reoxidants; Evidence for the Mechanism of the TA Reaction; Applications in Organic Synthesis; Conclusion and Future Work; CV of Timothy J. Donohoe; CV of Stefanie Mesch; References; 4 Organocatalyzed Transformations of a, b-Unsaturated Carbonyl Compounds through Iminium Ion Intermediates; CV of Nicholas C. O. Tomkinson; CV of Julian H. Rowley; References 327 $a5 The Renaissance of Silicon-Stereogenic Silanes: A Personal AccountBackground; Results; a) Intermolecular Chirality Transfer from Silicon to Carbon: Diastereoselective Palladium(II)-Catalyzed C-Si Bond Formation; b) Silicon-Stereogenic Silane as Stereochemical Probe: B(C6F5)3-Catalyzed Carbonyl Reduction; c) Kinetic Resolution with Silicon-Stereogenic Silanes: Cu-H-Catalyzed Diastereoselective Si-O Coupling; Conclusion; CV of Martin Oestreich; CV of Andreas Weickgenannt; References; 6 Asymmetric Dienamine Activation; Introduction; Historic Background; Results; Conclusion 327 $aCV of Mathias ChristmannReferences; 7 Asymmetric Brønsted Acid Catalysis; Introduction and Background; Strategy; Results; Summary; CV of Iuliana Atodiresei; CV of Uxue Uria; CV of Magnus Rueping; References; 8 Quaternary Stereogenic Centers by Enantioselective b-Carbon Eliminations from tert-Cyclobutanols; Background; Objective: Enantioselective Formation of Quaternary Stereogenic Centers in Combination with Reactive Alkyl-Rhodium Intermediates; Selective Generation of the Alkyl-Rhodium Species and Its Downstream Reactivities; CV of Nicolai Cramer; CV of Tobias Seiser; References 327 $a9 Total Synthesis of Oseltamivir and ABT-341 Using One-Pot TechnologyIntroduction; Results; a) Total Synthesis of (-)-Oseltamivir via Two One-Pot Processes; b) Total Synthesis of ABT-341 by One-Pot Sequence; Conclusions; CV of Yujiro Hayashi; CV of Hayato Ishikawa; References; 10 Enantioselective Annulations with Chiral N-Mesityl N-Heterocyclic Carbenes; Introduction; Catalytic Generation of Chiral Enolate Equivalents; Catalytic Generation of Homoenolate Equivalents; Enantioselective Cascade Reactions Catalyzed by Chiral N-Heterocyclic Carbenes 327 $aCatalytic Annulations via a, b-Unsaturated Acyl Azoliums 330 $aContinuing the proven and successful concept of the well-received textbook ""Asymmetric Synthesis - The Essentials"", this is a brief and timely update on the latest developments in asymmetric synthesis and selected applications in natural product synthesis, chemical industry and materials science. As such, it covers a broad range of topics in all important areas, including metal catalysis, organocatalysis, physical organic chemistry, and analytical chemistry.Each contribution is similarly structured, while the short biographies of the experts are a useful tool for students selecting t 606 $aAsymmetric synthesis 606 $aChemistry$2HILCC 606 $aPhysical Sciences & Mathematics$2HILCC 606 $aOrganic Chemistry$2HILCC 608 $aElectronic books. 615 0$aAsymmetric synthesis 615 7$aChemistry 615 7$aPhysical Sciences & Mathematics 615 7$aOrganic Chemistry 676 $a541.39 700 $aChristmann$b Mathias$0923341 701 $aBr?se$b Stefan$0923342 801 0$bAU-PeEL 801 1$bAU-PeEL 801 2$bAU-PeEL 906 $aBOOK 912 $a9910133857603321 996 $aAsymmetric Synthesis II$92072113 997 $aUNINA