LEADER 05478nam 2200697 a 450 001 9910133583703321 005 20230725052432.0 010 $a0-470-93476-X 010 $a1-283-02554-X 010 $a9786613025548 010 $a0-470-92899-9 010 $a0-470-92900-6 035 $a(CKB)3400000000000288 035 $a(EBL)674991 035 $a(OCoLC)710974947 035 $a(SSID)ssj0000476987 035 $a(PQKBManifestationID)12160649 035 $a(PQKBTitleCode)TC0000476987 035 $a(PQKBWorkID)10495909 035 $a(PQKB)11608844 035 $a(MiAaPQ)EBC674991 035 $a(Au-PeEL)EBL674991 035 $a(CaPaEBR)ebr10454778 035 $a(CaONFJC)MIL302554 035 $a(EXLCZ)993400000000000288 100 $a20100716d2011 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aHyperbranched polymers$b[electronic resource] $esynthesis, properties, and applications /$fedited by Deyue Yan, Chao Gao, Holger Frey 210 $aHoboken, N.J. $cWiley$d2011 215 $a1 online resource (482 p.) 225 1 $aWiley series on polymer engineering and technology 300 $aDescription based upon print version of record. 311 $a0-471-78014-6 320 $aIncludes bibliographical references and index. 327 $aCONTENTS; Preface; Contributors; 1. Promising Dendritic Materials: An Introduction to HyperbranchedPolymers; 1.1 Importance of Branching; 1.2 Polymer Architecture; 1.3 Dendritic Polymers; 1.4 Hyperbranched Polymers; 1.4.1 Concept and History; 1.4.2 Structure and Properties; 1.4.3 Synthesis Philosophy; 1.4.4 Applications; 1.5 Conclusions; 1.6 References; 2. Polycondensation of AB x Monomers; 2.1 Introduction; 2.2 Statistical Consideration; 2.2.1 Polymerization Behavior; 2.2.2 Degree of Branching; 2.3 Polymerization of AB x -Type Monomers; 2.3.1 C-C Coupling Reactions 327 $a2.3.1.1 Metal-Catalyzed Cross Couplings2.3.1.2 Diels-Alder Reactions; 2.3.1.3 Nucleophilic Substitution by Activated Methylenes; 2.3.1.4 Electrophilic Acylations; 2.3.2 C-O Coupling Reactions; 2.3.2.1 Nucleophilic Substitution Reactions by Phenoxides orAlkoxides; 2.3.2.2 Esterification of Carboxylic Acid Derivatives; 2.3.2.3 Ring-Opening Reaction of Epoxides; 2.3.3 C-N Coupling Reactions; 2.3.3.1 Condensation of Amines and Carboxylic AcidDerivatives; 2.3.3.2 Nucleophilic Addition of Amines; 2.3.3.3 Other C-N Coupling Reactions; 2.3.4 Si-C or Si-O Coupling Reactions 327 $a2.3.4.1 Hydrosilylation Reactions2.3.4.2 Condensation Reactions; 2.3.4.3 Other Si-Containing Reactions; 2.3.5 Other Coupling Reactions; 2.3.5.1 C-O or C-N Coupling Reactions of Isocyanates; 2.3.5.2 C-S Coupling Reactions; 2.4 References; 3. Synthesis of Hyperbranched Polymers via Polymerization ofFunctionally Symmetric Monomer Pairs; 3.1 Introduction; 3.2 Theoretical Treatment of A 2 + B 3 Polymerization; 3.3 Polymerization of Symmetrical Monomer Pairs; 3.3.1 Polycondensation of A 2 and B 3 Monomers; 3.3.1.1 Polyamides; 3.3.1.2 Polyimides; 3.3.1.3 Polyethers; 3.3.1.4 Polyesters 327 $a3.3.1.5 Polycarbonates3.3.1.6 Polyurethanes; 3.3.2 Proton-Transfer Polymerization of A2 and B3 Monomers; 3.3.3 The Michael Addition Polymerization of A2 and B3 Monomers; 3.4 Conclusions; 3.5 References; 4. Synthesis of Hyperbranched Polymers via Polymerization ofAsymmetric Monomer Pairs; 4.1 Introduction; 4.2 General Description of Polymerization of Asymmetric MonomerPairs; 4.3 Hyperbranched Polymers Prepared by Polymerization of AsymmetricMonomer Pairs; 4.3.1 Poly(Sulfoneamine); 4.3.2 Poly(Ester Amine); 4.3.3 Poly(Amidoamine); 4.3.4 Multihydroxyl Hyperbranched Poly(Amine Ester)s 327 $a4.3.5 Poly(Ester Amide)s4.3.6 Polyesters; 4.3.7 Poly(Urea-Urethane)s; 4.3.8 Other Polymers; 4.3.9 Highly Branched Copolymers; 4.4 Conclusions; 4.5 References; 5. Self-Condensing Vinyl Polymerization; 5.1 Introduction; 5.2 Self-Condensing Vinyl Polymerization; 5.2.1 General Principles; 5.2.2 Various Mechanisms of SCVP; 5.2.3 Kinetics and MWD; 5.2.4 Degree of Branching; 5.2.5 Comparison with Experimental Data; 5.3 Self-Condensing Vinyl Copolymerization (SCVCP); 5.3.1 Experimental Data; 5.3.2 Kinetics and MWD; 5.3.3 Degree of Branching; 5.3.4 Comparison with Experimental Data 327 $a5.4 Self-Condensing Processes in Presence of Initiators 330 $aA much-needed overview of the state of the art of hyperbranched polymers The last two decades have seen a surge of interest in hyperbranched polymers due to their ease of synthesis on a large scale and their promising applications in diverse fields, from medicine to nanotechnology. Written by leading scientists in academia and industry, this book provides for the first time a comprehensive overview of the topic, bringing together in one complete volume a wealth of information previously available only in articles scattered across the literature. Drawing on their work at the 410 0$aWiley series on polymer engineering and technology. 606 $aDendrimers 606 $aPolymers 615 0$aDendrimers. 615 0$aPolymers. 676 $a668.9 701 $aYan$b Deyue$0893867 701 $aGao$b Chao$0893868 701 $aFrey$b Holger$0893869 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910133583703321 996 $aHyperbranched polymers$91996677 997 $aUNINA