LEADER 03214nam 2200445 450 001 9910647204103321 005 20230327223837.0 035 $a(CKB)5680000000300263 035 $a(NjHacI)995680000000300263 035 $a(EXLCZ)995680000000300263 100 $a20230327d2023 uy 0 101 0 $aeng 135 $aur||||||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 00$aCovalent Organic Frameworks /$fedited by Yanan Gao and Fei Lu 210 1$aLondon :$cIntechOpen,$d2023. 210 4$dİ2023 215 $a1 online resource (ix, 122 pages) $cillustrations 311 $a1-80356-959-X 311 $a1-80356-960-3 320 $aIncludes bibliographical references. 327 $aPreface -- Chapter 1 Interfacial Synthesis of 2D COF Thin Films by Tao Zhang and Yuxiang Zhao -- Chapter 2 Covalent Organic Frameworks for Ion Conduction by Fei Lu and Yanan Gao -- Chapter 3 Photoredox Catalysis by Covalent Organic Frameworks by Shuai Bi -- Chapter 4 Photocatalysis of Covalent Organic Frameworks by Hui Liu and Yingjie Zhao -- Chapter 5 Applications of Covalent Organic Frameworks (COFs) in Oncotherapy by Guiyang Zhang. 330 $aIn recent decades, artificial porous structures have attracted increasing enthusiasm from researchers inspired by the fascinating molecular pores in nature and their unique biological functions. Although substantial achievements in porous materials have been realized, the construction of topologically designed pores is still challenging. Recently, the emergence of covalent organic frameworks (COFs), which are constructed based on organic and polymer chemistry, has made it possible to design artificial pores with controlled pore size, topology and interface properties. COFs are crystalline porous materials constructed by the precise reticulation of organic building blocks via dynamic covalent bonds. Distinct from non-covalent interactions which tend to produce isostructures, covalent bonds enable accurate pore design owing to their predetermined reaction pathways. In addition, the appropriate polycondensation of organic building units enables the formation of extended two-dimensional (2D) and three-dimensional (3D) polymer architectures with periodically ordered skeletons and well-defined pores. With their large surface area, tailorable structures, and tunable chemistry, COFs are regarded as potentially superior candidates for various applications including catalysis, energy storage and conversion, mass transport and biotechnology. This book examines the historic achievement of COFs, providing clear and comprehensive guidance for researchers on their structural design, synthetic protocols and functional exploration. 606 $aPorous materials 606 $aNanostructured materials 606 $aCrystalline polymers 615 0$aPorous materials. 615 0$aNanostructured materials. 615 0$aCrystalline polymers. 676 $a547.7 702 $aGao$b Yanan 702 $aLu$b Fei 801 0$bNjHacI 801 1$bNjHacl 906 $aBOOK 912 $a9910647204103321 996 $aCovalent Organic Frameworks$93014928 997 $aUNINA LEADER 04828nam 2200625 450 001 9910132344403321 005 20230807212133.0 010 $a3-527-67274-5 010 $a3-527-67270-2 010 $a3-527-67285-0 035 $a(CKB)3710000000264763 035 $a(EBL)1819344 035 $a(SSID)ssj0001407705 035 $a(PQKBManifestationID)11755962 035 $a(PQKBTitleCode)TC0001407705 035 $a(PQKBWorkID)11411374 035 $a(PQKB)10172615 035 $a(MiAaPQ)EBC1819344 035 $a(Au-PeEL)EBL1819344 035 $a(CaPaEBR)ebr10986564 035 $a(CaONFJC)MIL663053 035 $a(OCoLC)893739710 035 $a(EXLCZ)993710000000264763 100 $a20141202h20152015 uy| 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aCatalytic arylation methods $efrom the academic lab to industrial processes /$fAnthony J. Burke and Carolina Silva Marques 210 1$aWeinheim, Germany :$cWiley-VCH Verlag GmbH & KGaA,$d[2015] 210 4$dİ2015 215 $a1 online resource (1058 p.) 300 $aDescription based upon print version of record. 311 $a1-322-31771-2 311 $a3-527-33518-8 320 $aIncludes bibliographical references and index. 327 $aCover; Related Titles; Title Page; Copyright; Dedication; Preface; List of Abbreviations; Chapter 1: Cross-Coupling Arylations: Precedents and Rapid HistoricalReview of the Field; 1.1 Metal-Catalyzed Cross-Couplings: From Its Origins to the Nobel Prize and Beyond; 1.2 Arylation: What Is So Special?; 1.3 Recent New Developments; 1.4 Selected Experiments from the Literature; References; Chapter 2: Amine, Phenol, Alcohol, and Thiol Arylation; 2.1 Introduction; 2.2 Pd-Catalyzed Processes; 2.3 Cu-Catalyzed and Promoted Arylations: (CAr-N Bond Formation); 2.4 Fe-Catalyzed Arylations 327 $a2.5 Ni-Catalyzed Reactions2.6 Co-Catalyzed Arylations; 2.7 Mn-Catalyzed Arylations; 2.8 Cd-Catalyzed Arylations; 2.9 Bi(III) and Indium Oxide-Catalyzed Thiol Arylations; 2.10 Conclusions and Final Comment; 2.11 Selected Experiments from the Literature; References; Chapter 3: Decarboxylative Coupling Techniques; 3.1 Introduction; 3.2 Pd-Catalyzed Versions; 3.3 Other Metal-Catalyzed Versions; 3.4 Conclusions; 3.5 Selected Experiments; References; Chapter 4: C-H Bond Activation for Arylations; 4.1 Introduction; 4.2 C(sp2)-H Activations; 4.3 Conclusions 327 $a4.4 Selected Experiments from the LiteratureReferences; Chapter 5: Conjugate Additions; 5.1 Conjugate Additions: A Powerful Tool for Appending Organic Residues to Cyclic and Acyclic Substrates; 5.2 Applications of Rh Catalysts; 5.3 Applications of Pd Catalysts; 5.4 Applications of Ru and Other Catalysts; 5.5 Conclusions; 5.6 Selected Experiments; References; Chapter 6: Imine Arylations - Synthesis of Arylamines; 6.1 Arylation of C=N Bonds: Simple Access to Chiral Amine Units; 6.2 Application of Rh Catalysts; 6.3 Application of Pd Catalysts; 6.4 Application of Ru and Other Catalysts 327 $a6.5 The Petasis-Akritopoulou Reaction6.6 Conclusions; 6.7 Selected Experiments; References; Chapter 7: Carbonyl Group Arylation; 7.1 Introduction; 7.2 Application of Rh Catalysts; 7.3 Application of Pd Catalysts; 7.4 Application of Ru and Other Catalysts; 7.5 Conclusions; 7.6 Selected Experiments; References; Chapter 8: ?-Arylation Processes; 8.1 Introduction; 8.2 Arylation of Enolates and Equivalents; 8.3 Other Metal-Catalyzed ?-Arylations; 8.4 Conclusions; 8.5 Selected Experiments; References; Chapter 9: Catalytic Cycloaddition Aromatization Processes; 9.1 Introduction 327 $a9.2 Cycloaddition Events9.3 Radical-Based Cycloaromatization Processes; 9.4 Conclusions; 9.5 Selected Experiments from the Literature; References; Index; End User License Agreement 330 $aA current view of the challenging field of catalytic arylation reactions. Clearly structured, the chapters in this one-stop resource are arranged according to the reaction type, and focus on novel, efficient and sustainable processes, rather than the well-known and established cross-coupling methods.The entire contents are written by two authors with academic and industrial expertise to ensure consistent coverage of the latest developments in the field, as well as industrial applications, such as C-H activation, iron and gold-catalyzed coupling reactions, cycloadditions or novel methodologies 606 $aArylation 615 0$aArylation. 676 $a541.395 700 $aBurke$b Anthony J.$0994780 702 $aMarques$b Carolina Silva 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910132344403321 996 $aCatalytic arylation methods$92278565 997 $aUNINA LEADER 01440nam 2200301Ia 450 001 996386827003316 005 20221108033727.0 035 $a(CKB)4940000000081717 035 $a(EEBO)2248501403 035 $a(OCoLC)ocm14974848e 035 $a(OCoLC)14974848 035 $a(EXLCZ)994940000000081717 100 $a19861215d1690 uy | 101 0 $aeng 135 $aurbn||||a|bb| 200 12$aA compleat history and mystery of the Old and New Testament$hThe first volume$b[electronic resource] $elogically discuss'd and theologically improved in three distinct volumes, the first beginning at the creation of the world and ending at Moses, the second continuing the history from Joshuah till the birth of Christ, third from the birth of Christ to the death of the last and longest living apostle, John the Divine : the like undertaking (in such a manner and method) being never attempted before /$fby Christopher Ness .. 210 $aLondon $cPrinted by T. Snowdon for the author and are to be sold by Tho. Parkhurst ...$d1690 215 $a[8], 468 p 300 $aReproduction of original in the Union Theological Seminary Library, New York. 330 $aeebo-0160 700 $aNess$b Christopher$f1621-1705.$01002120 801 0$bEAF 801 1$bEAF 801 2$bWaOLN 906 $aBOOK 912 $a996386827003316 996 $aA compleat history and mystery of the Old and New Testament$92351383 997 $aUNISA