LEADER 05767nam 2200745 450 001 9910132173603321 005 20200520144314.0 010 $a1-118-68281-5 010 $a1-118-68276-9 010 $a1-118-68274-2 035 $a(CKB)3710000000230543 035 $a(EBL)1780722 035 $a(SSID)ssj0001333317 035 $a(PQKBManifestationID)12563357 035 $a(PQKBTitleCode)TC0001333317 035 $a(PQKBWorkID)11396191 035 $a(PQKB)11416783 035 $a(PQKBManifestationID)16048520 035 $a(PQKB)23191016 035 $a(MiAaPQ)EBC1780722 035 $a(DLC) 2014019037 035 $a(Au-PeEL)EBL1780722 035 $a(CaPaEBR)ebr10929007 035 $a(CaONFJC)MIL642289 035 $a(OCoLC)890530598 035 $a(PPN)198219180 035 $a(EXLCZ)993710000000230543 100 $a20140918h20142014 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aLuminescence of lanthanide ions in coordination compounds and nanomaterials /$fedited by Ana de Bettencourt-Dias 210 1$aChichester, England :$cWiley,$d2014. 210 4$dİ2014 215 $a1 online resource (387 p.) 300 $aDescription based upon print version of record. 311 $a1-119-95083-X 311 $a1-322-11038-7 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aLuminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials; Contents; List of Contributors; Preface; 1 Introduction to Lanthanide Ion Luminescence; 1.1 History of Lanthanide Ion Luminescence; 1.2 Electronic Configuration of the +III Oxidation State; 1.2.1 The 4f Orbitals; 1.2.2 Energy Level Term Symbols; 1.3 The Nature of the f-f Transitions; 1.3.1 Hamiltonian in Central Field Approximation and Coulomb Interactions; 1.3.2 Spin-Orbit Coupling; 1.3.3 Crystal Field or Stark Effects; 1.3.4 The Crystal Field Parameters Bkq and Symmetry; 1.3.5 Energies of Crystal Field Split Terms 327 $a1.3.6 Zeeman Effect 1.3.7 Point Charge Electrostatic Model; 1.3.8 Other Methods to Estimate Crystal Field Parameters; 1.3.9 Allowed and Forbidden f-f Transitions; 1.3.10 Induced Electric Dipole Transitions and Their Intensity - Judd-Ofelt Theory; 1.3.11 Transition Probabilities and Branching Ratios; 1.3.12 Hypersensitive Transitions; 1.3.13 Emission Efficiency and Rate Constants; 1.4 Sensitisation Mechanism; 1.4.1 The Antenna Effect; 1.4.2 Non-Radiative Quenching; References; 2 Spectroscopic Techniques and Instrumentation; 2.1 Introduction; 2.2 Instrumentation in Luminescence Spectroscopy 327 $a2.2.1 Challenges in Design and Interpretation of Lanthanide Luminescence Experiments 2.2.2 Common Luminescence Experiments; 2.2.3 Basic Design Elements and Configurations in Luminescence Spectrometers; 2.2.4 Luminescence Spectrometer Components and Characteristics; 2.2.5 Recent Advances in Luminescence Instrumentation; 2.3 Measurement of Quantum Yields of Luminescence in the Solid State and in Solution; 2.3.1 Measurement Against a Standard in Solution; 2.3.2 Measurement Against a Standard in the Solid State; 2.3.3 Absolute Measurement with an Integrating Sphere; 2.4 Excited State Lifetimes 327 $a2.4.1 Number of Coordinated Solvent Molecules References; 3 Circularly Polarised Luminescence; 3.1 Introduction; 3.1.1 General Aspects: Molecular Chirality; 3.1.2 Chiroptical Tools: from CD to CPL Spectroscopy; 3.2 Theoretical Principles; 3.2.1 General Theory; 3.2.2 CPL Intensity Calculations, Selection Rules, Luminescence Selectivity, and Spectra-Structure Relationship; 3.3 CPL Measurements; 3.3.1 Instrumentation; 3.3.2 Calibration and Standards; 3.3.3 Artifacts in CPL Measurements; 3.3.4 Proposed Instrumental Improvements to Record Eu(III)-Based CPL Signals; 3.4 Survey of CPL Applications 327 $a3.4.1 Ln(III)-Containing Systems 3.4.2 Ln(III) Complexes with Achiral Ligands; 3.4.3 Ln(III) Complexes with Chiral Ligands; 3.5 Chiral Ln(III) Complexes to Probe Biologically Relevant Systems; 3.5.1 Sensing through Coordination to the Metal Centre; 3.5.2 Sensing through Coordination to the Antenna/Receptor Groups; 3.6 Concluding Remarks; References; 4 Luminescence Bioimaging with Lanthanide Complexes; 4.1 Introduction; 4.2 Luminescence Microscopy; 4.2.1 Classical Optical Microscopy: a Short Survey; 4.2.2 Principle of Luminescence Microscopy 327 $a4.2.3 Principle of Time-resolved Luminescence Microscopy 330 $aThis comprehensive book presents the theoretical principles, current applications and latest research developments in the field of luminescent lanthanide complexes; a rapidly developing area of research which is attracting increasing interest amongst the scientific community. Luminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials begins with an introduction to the basic theoretical and practical aspects of lanthanide ion luminescence, and the spectroscopic techniques used to evaluate the efficiency of luminescence. Subsequent chapters introduce a variety of different app 606 $aNanostructured materials 606 $aLuminescence 606 $aRare earth metals$xOptical properties 606 $aCoordination compounds 615 0$aNanostructured materials. 615 0$aLuminescence. 615 0$aRare earth metals$xOptical properties. 615 0$aCoordination compounds. 676 $a546/.41 702 $aBettencourt-Dias$b Ana de 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910132173603321 996 $aLuminescence of lanthanide ions in coordination compounds and nanomaterials$92026193 997 $aUNINA