LEADER 05678nam 2200733 450 001 9910132156503321 005 20170821202941.0 010 $a1-118-67074-4 010 $a1-118-67075-2 010 $a1-118-67073-6 035 $a(CKB)3710000000250140 035 $a(EBL)1798776 035 $a(OCoLC)892240559 035 $a(SSID)ssj0001347520 035 $a(PQKBManifestationID)12603796 035 $a(PQKBTitleCode)TC0001347520 035 $a(PQKBWorkID)11351158 035 $a(PQKB)11360673 035 $a(PQKBManifestationID)16039689 035 $a(PQKB)23165098 035 $a(MiAaPQ)EBC1798776 035 $a(DLC) 2014018459 035 $a(MiAaPQ)EBC7076142 035 $a(Au-PeEL)EBL7076142 035 $a(PPN)220082944 035 $a(EXLCZ)993710000000250140 100 $a20141022h20152015 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aFundamentals and applications of organic electrochemistry $esynthesis, materials, devices /$fToshio Fuchigami, Mahito Atobe, Shinsuke Inagi 210 1$aChichester, England :$cWiley,$d2015. 210 4$dİ2015 215 $a1 online resource (241 p.) 300 $aDescription based upon print version of record. 311 $a1-322-19612-5 311 $a1-118-65317-3 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aFundamentals and Applications of Organic Electrochemistry: Synthesis, Materials, Devices; Contents; About the Authors; Preface; Introduction; 1. Fundamental Principles of Organic Electrochemistry: Fundamental Aspects of Electrochemistry Dealing with Organic Molecules; 1.1 FORMATION OF ELECTRICAL DOUBLE LAYER; 1.2 ELECTRODE POTENTIALS (REDOX POTENTIALS); 1.3 ACTIVATION ENERGY AND OVERPOTENTIAL; 1.4 CURRENTS CONTROLLED BY ELECTRON TRANSFER AND MASS TRANSPORT; References; 2. Method for Study of Organic Electrochemistry: Electrochemical Measurements of Organic Molecules; 2.1 WORKING ELECTRODES 327 $a2.2 REFERENCE ELECTRODES2.3 AUXILIARY ELECTRODES; 2.4 SOLVENTS AND SUPPORTING ELECTROLYTES; 2.5 CELLS AND POWER SOURCES; 2.6 STEADY-STATE AND NON-STEADY-STATES POLARIZATION CURVES; 2.7 POTENTIALS IN ELECTROCHEMICAL MEASUREMENTS; 2.8 UTILIZATION OF VOLTAMMETRY FOR THE STUDY OF ORGANIC ELECTROSYNTHESIS; 2.8.1 Voltammetric Analysis for Selective Electrosynthesis; 2.8.2 Clarification of the Reaction Mechanism; 2.8.3 Voltammetry for Selection of Mediator; 2.8.4 Voltammetry for Selection of Electrode Material; References; 3. Methods for Organic Electrosynthesis; 3.1 SELECTION OF ELECTROLYTIC CELLS 327 $a3.2 CONSTANT CURRENT ELECTROLYSIS AND CONSTANT POTENTIAL ELECTROLYSIS3.3 DIRECT ELECTROLYSIS AND INDIRECT ELECTROLYSIS; 3.4 ELECTRODE MATERIALS AND REFERENCE ELECTRODES; 3.5 ELECTROLYTIC SOLVENTS AND SUPPORTING ELECTROLYTES; 3.6 STIRRING; 3.7 TRACKING OF REACTANT AND PRODUCT; 3.8 WORK-UP, ISOLATION AND DETERMINATION OF PRODUCTS; 3.9 CURRENT EFFICIENCY AND EFFECT OF THE POWER UNIT; References; 4. Organic Electrode Reactions; 4.1 GENERAL CHARACTERISTICS OF ELECTRODE REACTIONS; 4.2 MECHANISM OF ORGANIC ELECTRODE REACTIONS; 4.3 CHARACTERISTICS OF ORGANIC ELECTROLYTIC REACTIONS; 4.3.1 Umpolung 327 $a4.3.2 Selectivity4.3.2.1 Chemoselectivity; 4.3.2.2 Reaction Pathway Selectivity; 4.3.2.3 Regioselectivity; 4.3.2.4 Stereoselectivity; 4.3.2.5 Selectivity Depending on Electrode Materials; 4.4 MOLECULAR ORBITALS AND ELECTRONS RELATED TO ELECTRON TRANSFER; 4.5 ELECTROAUXILIARIES; 4.5.1 Electroauxiliaries Based on Molecular Orbital Interactions; 4.5.2 Electroauxiliaries Based on Readily Electron-Transferable Functional Groups; 4.5.3 Electroauxiliaries Based on Intermolecular Coordination Effects; 4.5.4 Electroauxiliaries Based on Intramolecular Coordination Effects 327 $a4.6 REACTION PATTERN OF ORGANIC ELECTRODE REACTIONS4.6.1 Transformation Type of Functional Group; 4.6.2 Addition Type; 4.6.3 Insertion Type; 4.6.4 Substitution Type; 4.6.5 Substitutive Exchange Type; 4.6.6 Elimination Type; 4.6.7 Dimerization Type; 4.6.8 Crossed Dimerization; 4.6.9 Cyclization Type; 4.6.10 Polymorphism Formation Type; 4.6.11 Polymerization Type; 4.6.12 Cleavage Type; 4.6.13 Metalation Type; 4.6.14 Asymmetric Synthesis Type; 4.7 ELECTROCHEMICALLY GENERATED REACTIVE SPECIES; 4.7.1 Carbon Species; 4.7.1.1 Anodically Generated Carbon Species 327 $a4.7.1.2 Cathodically Generated Carbon Species 330 $aThis textbook is an accessible overview of the broad field of organic electrochemistry, covering the fundamentals and applications of contemporary organic electrochemistry. The book begins with an introduction to the fundamental aspects of electrode electron transfer and methods for the electrochemical measurement of organic molecules. It then goes on to discuss organic electrosynthesis of molecules and macromolecules, including detailed experimental information for the electrochemical synthesis of organic compounds and conducting polymers. Later chapters highlight new methodology for organic 606 $aOrganic electrochemistry 606 $aElectrochemistry 606 $aChemistry, Organic 615 0$aOrganic electrochemistry. 615 0$aElectrochemistry. 615 0$aChemistry, Organic. 676 $a547/.137 700 $aFuchigami$b Toshio$0895600 702 $aAtobe$b Mahito$f1969- 702 $aInagi$b Shinsuke 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910132156503321 996 $aFundamentals and applications of organic electrochemistry$92000721 997 $aUNINA