LEADER 05892nam 2200781 450 001 9910131583003321 005 20200520144314.0 010 $a1-119-11770-4 010 $a1-119-11769-0 010 $a1-119-11771-2 035 $a(CKB)3710000000458811 035 $a(EBL)1964129 035 $a(SSID)ssj0001531222 035 $a(PQKBManifestationID)12582718 035 $a(PQKBTitleCode)TC0001531222 035 $a(PQKBWorkID)11533137 035 $a(PQKB)10851655 035 $a(PQKBManifestationID)16038859 035 $a(PQKB)24176069 035 $a(MiAaPQ)EBC4043044 035 $a(DLC) 2015027731 035 $a(MiAaPQ)EBC1964129 035 $a(Au-PeEL)EBL4043044 035 $a(CaPaEBR)ebr11088031 035 $a(CaONFJC)MIL820157 035 $a(OCoLC)913890603 035 $a(Au-PeEL)EBL1964129 035 $a(PPN)190116811 035 $a(EXLCZ)993710000000458811 100 $a20150817h20152015 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 00$aReactions and mechanisms in thermal analysis of advanced materials /$fedited by Atul Tiwari and Baldev Raj 205 $a1st ed. 210 1$aSalem, Massachusetts ;$aHoboken, New Jersey :$cScrivener Publishing :$cJohn Wiley & Sons, Inc.,$d2015. 210 4$dİ2015 215 $a1 online resource (612 pages) 225 0 $aMaterials Degradation and Failure Series 300 $aDescription based upon print version of record. 311 $a1-119-11757-7 320 $aIncludes bibliographical references and index. 327 $aCover; Title Page; Copyright Page; Contents; Preface; Part 1: Degradation of Polymers; 1 Thermal Stability of Organic Monolayers Covalently Grafted on Silicon Surfaces; 1.1 Introduction; 1.1.1 Hydrogen-Terminated Si Surfaces; 1.2 Alkyl-Grafted Surfaces; 1.2.1 Preparation; 1.2.2 Thermal Stability of Alkyl-Grafted Surfaces; 1.2.3 Case of Substituted Alkyl Surfaces; 1.3 Alkoxy-Grafted Surfaces; 1.3.1 Preparation; 1.3.2 Thermal Stability of Alkoxy-Grafted Surfaces; 1.4 Surfaces Grafted with Aryl Groups; 1.4.1 Preparation; 1.4.2 Thermal Stability; 1.5 Surfaces Grafted via Si-N Linkages 327 $a1.5.1 Preparation1.5.2 Thermal Stability; 1.5.2.1 The Thermal Treatment of the Si Surface with NH3; 1.5.2.2 Thermal Stability of the Modified Surfaces; 1.6 Summary; References; 2 Thermal Analysis to Discriminate the Stability of Biomedical Ultrahigh-Molecular-Weight Polyethylenes Formulations; 2.1 Introduction; 2.2 Suitability of TGA Analysis for the Study of Stability of Medical Polyethylene; 2.2.1 Introduction; 2.2.2 Degradation Curves of UHMWPE Depending on the Reaction Atmosphere; 2.2.3 Decomposition Processes of UHMWPE in Air; 2.2.3.1 Thermo-oxidation Process 327 $a2.2.3.2 Thermal Degradation Process of UHMWPE2.2.4 Irradiation Effects on the Thermogravimetric Curves of UHMWPE; 2.2.5 Stabilization of Polyethylene against Thermo-oxidative Degradation; 2.3 Activation Energies of Degradation Processes in the Thermal Decomposition of UHMWPE; References; 3 Materials Obtained by Solid-State Thermal Decomposition of Coordination Compounds and Metal-Organic Coordination Polymers; 3.1 Introduction; 3.2 Coordination Compounds and Metal-Organic Coordination Polymers as Precursors of Oxides; 3.2.1 Coordination Compounds with Carboxylic Acid as Ligand 327 $a3.2.2 Coordination's Compounds as Precursors in the Combustion Synthesis of Oxides3.2.3 Metal-Organic Coordination Polymers as Precursors of Oxides; 3.3 Coordination Compounds and Metal-Organic Coordination Polymers as Precursors of Sulfides; 3.4 Coordination Compounds as Precursors of Composites; 3.5 Coordination Compounds and Metal-Organic Coordination Polymers as Precursors of New Complexes; 3.6 Coordination Compounds and Metal-Organic Coordination Polymers as Precursor of Metals; 3.7 Coordination Compounds as Precursor of Nitrides; 3.8 Other Materials; 3.9 Conclusions; References 327 $a4 Methods for Limiting the Flammability of High-Density Polyethylene with Magnesium Hydroxide4.1 Introduction; 4.2 Experimental Part; 4.2.1 Materials; 4.2.2 Sample Preparation; 4.2.3 Methods of Testing; 4.3 Results and Discussion; 4.3.1 Thermal Stability; 4.3.2 Flammability; 4.3.2.1 UL-94 Test; 4.3.2.2 Limiting Oxygen Index (LOI); 4.3.2.3 Cone Calorimetry; 4.3.3 Mechanical Properties; 4.3.4 Microstructure of Fracture Surface of Composites; 4.4 Conclusions; References; 5 Thermal Analysis in the Study of Polymer (Bio)-degradation; 5.1 Introduction; 5.2 Differential Scanning Calorimetry 327 $a5.2.1 Melting Profile 330 $aStrong bonds form stronger materials. For this reason, the investigation on thermal degradation of materials is a significantly important area in research and development activities. The analysis of thermal stability can be used to assess the behavior of materials in the aggressive environmental conditions, which in turn provides valuable information about the service life span of the materiel. Unlike other books published so far that have focused on either the fundamentals of thermal analysis or the degradation pattern of the materials, this book is specifically on the mechanism of degrada 410 0$aMaterials Degradation and Failure 606 $aMaterials at high temperatures 606 $aMaterials$xDeterioration 606 $aMaterials$xAnalysis 615 0$aMaterials at high temperatures. 615 0$aMaterials$xDeterioration. 615 0$aMaterials$xAnalysis. 676 $a620.1/1217 702 $aTiwari$b Atul 702 $aRaj$b Baldev 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910131583003321 996 $aReactions and mechanisms in thermal analysis of advanced materials$91924562 997 $aUNINA