LEADER 04278nam 2200589 450 001 9910131529403321 005 20211025112838.0 010 $a1-119-17856-8 010 $a1-119-17854-1 010 $a1-119-17855-X 035 $a(CKB)3710000000498555 035 $a(EBL)4444935 035 $a(MiAaPQ)EBC4444935 035 $a(Au-PeEL)EBL4444935 035 $a(CaPaEBR)ebr11251270 035 $a(CaONFJC)MIL847004 035 $a(OCoLC)945764293 035 $a(EXLCZ)993710000000498555 100 $a20160916d2015 uy| 0 101 0 $aeng 135 $aur|n|---||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 10$aChemical equilibria /$fMichel Soustelle 210 1$aHoboken, NJ :$cWiley,$d2015. 215 $a1 online resource (179 p.) 225 1 $aChemical engineering series : chemical thermodynamics set ;$vvolume 4 300 $aDescription based upon print version of record. 311 $a1-84821-867-2 320 $aIncludes bibliographical references and index. 327 $aTable of Contents; Title; Copyright; Preface; Notations and Symbols; 1: Physico-Chemical Transformations and Equilibria; 1.1. Characteristic parameters of physico-chemical transformations; 1.2. Entropy production during the course of a transformation in a closed system; 1.3. Affinity of a transformation; 1.4. De Donder's inequality - direction of the transformations and equilibrium conditions; 1.5. Heats of transformation; 1.6. Set of points representing the equilibrium states of a transformation; 1.7. Closed systems accommodating multiple reactions 327 $a1.8. Direction of evolution and equilibrium conditions in an open system1.9. Azeotropic transformations; 2: Properties of States of Physico-Chemical Equilibrium; 2.1. Laws of displacement of an equilibrium; 2.2. Properties of all the equilibria in a system; 2.3. Phase laws; 2.4. Indifferent states; 2.5. Thermodynamically-equivalent systems; 2.6. Stability of equilibria; 3: Molecular Chemical Equilibria; 3.1. Law of mass action - equilibrium constants; 3.2. Graphical representations of equilibria - pole diagrams; 3.3. Representation of the evolution of an equilibrium with the temperature 327 $a3.4. Binary diagrams for chemical equilibrium3.5. Ternary diagrams of chemical equilibria; 3.6. Quaternary diagrams of chemical equilibria; 4: Determination of the Values Associated with Reactions - Equilibrium Calculations; 4.1. Reminders of a few thermodynamic relations; 4.2. Enthalpies of reaction - thermochemistry; 4.3. Reaction entropies; 4.4. Specific heat capacities; 4.5. Experimental determination of the equilibrium constants; 4.6. Calculation of the equilibrium constants on the basis of other thermodynamic data 327 $a4.7. Determination of the equilibrium constants on the basis of spectral data and statistical thermodynamics4.8. Thermodynamic tables and databanks; 4.9. Estimation of thermodynamic data; 4.10. Thermodynamic calculations for complex systems; APPENDICES; Appendix 1: Recap on the Reference States of Solutions; A1.1. Concentration and molar fraction; A1.2. Chemical potentials and activity coefficients; A1.3. Characterization of the imperfection of a real solution by the excess Gibbs energy; Appendix 2: Recap of statistical thermodynamics; A2.1. The three branches of statistics 327 $aA2.2. Partition functions of a molecule objectA2.3. Canonical partition function; A2.4. Canonical partition functions and thermodynamic functions; A2.5. Equilibrium constants and molecular partition functions; Bibliography; Index; End User License Agreement 410 0$aChemical engineering series (ISTE Ltd.) 606 $aThermodynamics$xMathematical models 606 $aChemical equilibrium$xMathematical models 606 $aPhase transformations (Statistical physics) 615 0$aThermodynamics$xMathematical models. 615 0$aChemical equilibrium$xMathematical models. 615 0$aPhase transformations (Statistical physics) 676 $a541.392 700 $aSoustelle$b Michel$0854349 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910131529403321 996 $aChemical equilibria$92278635 997 $aUNINA