LEADER 05647nam 2200709 450 001 9910131282303321 005 20230807214439.0 010 $a1-119-00642-2 010 $a1-119-00622-8 010 $a1-119-00632-5 035 $a(CKB)3710000000397660 035 $a(EBL)1895902 035 $a(SSID)ssj0001460052 035 $a(PQKBManifestationID)12562797 035 $a(PQKBTitleCode)TC0001460052 035 $a(PQKBWorkID)11465735 035 $a(PQKB)11732885 035 $a(MiAaPQ)EBC1895902 035 $a(DLC) 2014047257 035 $a(Au-PeEL)EBL1895902 035 $a(CaPaEBR)ebr11043787 035 $a(CaONFJC)MIL770114 035 $a(OCoLC)897510777 035 $a(EXLCZ)993710000000397660 100 $a20150509h20152015 uy 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt 182 $cc 183 $acr 200 00$aStereoselective multiple bond-forming transformations in organic synthesis /$fedited by Jean Rodriguez and Damien Bonne ; foreword by Dieter Enders ; contributors, Muriel Amatore [and thirty-nine others] 210 1$aHoboken, New Jersey :$cWiley,$d2015. 210 4$d©2015 215 $a1 online resource (472 p.) 300 $aDescription based upon print version of record. 311 $a1-118-67271-2 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aCover; Title Page; Copyright; Contents; List of Contributors; Foreword; Preface; Chapter 1 Definitions and Classifications of MBFTs; 1.1 Introduction; 1.2 Definitions; 1.3 Conclusion and Outlook; References; Part I Stereoselective Synthesis of Heterocycles; Chapter 2 Five-Membered Heterocycles; 2.1 Introduction; 2.2 Monocyclic Targets; 2.2.1 1,3-Dipolar Cycloaddition; 2.2.2 Michael Addition-Initiated Domino Process; 2.2.3 Multicomponent Reactions; 2.2.4 Carbohalogenation Reactions; 2.2.5 Radical Processes; 2.3 Fused Polycyclic Targets; 2.3.1 Cycloaddition Reactions 327 $a2.3.2 Domino Cyclization Reactions 2.4 Bridged Polycyclic Targets; 2.5 Conclusion and Outlook; References; Chapter 3 Six-Membered Heterocycles; 3.1 Introduction; 3.2 Monocyclic Targets; 3.2.1 Nitrogen-Only Heterocycles; 3.2.2 Oxygen-Containing Heterocycles; 3.3 Fused Polycyclic Targets; 3.3.1 Nitrogen-Only Fused Polycyclic Targets; 3.3.2 Oxygen-Containing Fused Polycyclic Targets; 3.3.3 Sulfur-Containing Fused Polycyclic Targets; 3.4 Bridged Polycyclic Targets; 3.4.1 General Procedure for the Preparation of 2,6-DABCO-Derived Compounds 138; 3.5 Polycyclic Spiro Targets; 3.6 Summary and Outlook 327 $aReferences Chapter 4 Other Heterocycles; 4.1 Introduction; 4.2 Synthesis of Medium-Sized Monocyclic, Fused and Bridged Polycyclic Heterocycles; 4.2.1 Ring Synthesis by Ring Transformation via Rearrangements/Ring Expansions; 4.2.2 Ring Synthesis by Annulation; 4.3 Summary and Outlook; References; Part II Stereoselective Synthesis of Carbocycles; Chapter 5 Three- and Four-Membered Carbocycles; 5.1 Introduction; 5.2 Cyclopropane Derivatives; 5.2.1 Organocatalysis and Related Reactions [Michael-Initiated Ring-Closure (MIRC) Reactions]; 5.2.2 Organometallics and Metal Catalysis 327 $a5.2.3 Lewis Acid-Promoted Sequences 5.2.4 Pericyclic Domino Strategies; 5.2.5 Radical Domino Strategies; 5.3 Cyclobutane Derivatives; 5.3.1 Organocatalyzed Cyclobutanations; 5.3.2 Organometallics and Metal Catalysis; 5.3.3 Acid- or Base-Promoted Transformations; 5.3.4 Multicomponent Reactions (MCRs); 5.4 Summary and Outlook; References; Chapter 6 Five-Membered Carbocycles; 6.1 Introduction; 6.2 Monocyclic Targets; 6.2.1 Metal-Catalyzed Reactions; 6.2.2 Organocatalytic Reactions; 6.2.3 Miscellaneous Reactions; 6.3 Fused Polycyclic Targets; 6.3.1 Metal-Catalyzed Reactions 327 $a6.3.2 Organocatalytic Reactions 6.3.3 Lewis Acid-Catalyzed Reactions; 6.3.4 Miscellaneous Reactions; 6.4 Bridged Polycyclic Targets; 6.5 Conclusion and Outlook; References; Chapter 7 Stereoselective Synthesis of Six-Membered Carbocycles; 7.1 Introduction; 7.2 Metal-Catalyzed Stereoselective Multiple Bond-Forming Transformations; 7.2.1 Introduction; 7.2.2 Cycloadditions; 7.2.3 Metal-Catalyzed Cascades as Formal [2+2+2] Cycloadditions; 7.2.4 Metal-Catalyzed Cycloisomerization Cascades; 7.3 Enantioselective Organocatalyzed Synthesis of Six-Membered Rings 327 $a7.3.1 Organocatalyzed Miscellaneous Reactions 330 $aMake synthesis more green, efficient, and economical Stereoselective multiple bond-forming transformations (MBFTs), which use one synthetic operation to selectively create at least two chemical bonds, decrease the total number of steps and increase atom economy while maximizing structural complexity and the functional diversity. In consequence, they reduce the amount of waste, money, and negative environmental impact of chemical processes. Combining such an important research topic with green chemistry, this book helps chemists identify sustainable stereoselective MBFTs. 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