LEADER 04856nam 2200697 450 001 9910132192503321 005 20200520144314.0 010 $a1-118-69440-6 010 $a1-118-69434-1 010 $a1-118-69438-4 035 $a(CKB)3710000000125533 035 $a(EBL)1707088 035 $a(SSID)ssj0001226559 035 $a(PQKBManifestationID)11816831 035 $a(PQKBTitleCode)TC0001226559 035 $a(PQKBWorkID)11273871 035 $a(PQKB)10343971 035 $a(MiAaPQ)EBC1707088 035 $a(DLC) 2014012721 035 $a(Au-PeEL)EBL1707088 035 $a(CaPaEBR)ebr10881042 035 $a(CaONFJC)MIL621886 035 $a(OCoLC)881417058 035 $a(PPN)220104115 035 $a(EXLCZ)993710000000125533 100 $a20140618h20142014 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aDevelopments in electrochemistry $escience inspired by Martin Fleischmann /$feditors, Derek Pletcher, Zhong-Qun Tian, David E. Williams 210 1$aChichester, England :$cWiley,$d2014. 210 4$d©2014 215 $a1 online resource (393 p.) 300 $aIncludes index. 311 $a1-306-90635-0 311 $a1-118-69443-0 320 $aIncludes bibliographical references at the end of each chapters and index. 327 $aDevelopments in Electrochemistry; Contents; List of Contributors; 1 Martin Fleischmann - The Scientist and the Person; The Publications of Martin Fleischmann; 2 A Critical Review of the Methods Available for Quantitative Evaluation of Electrode Kinetics at Stationary Macrodisk Electrodes; 2.1 DC Cyclic Voltammetry; 2.1.1 Principles; 2.1.2 Processing DC Cyclic Voltammetric Data; 2.1.3 Semiintegration; 2.2 AC Voltammetry; 2.2.1 Advanced Methods of Theory-Experiment Comparison; 2.3 Experimental Studies; 2.3.1 Reduction of [Ru(NH3)6]3+ in an Aqueous Medium 327 $a4.2 Electrochemical Nucleation with Diffusion-Controlled Growth4.3 Mathematical Modeling of Nucleation and Growth Processes; 4.4 The Nature of Active Sites; 4.5 Induction Times and the Onset of Electrochemical Phase Formation Processes; 4.6 Conclusion; References; 5 Organic Electrosynthesis; 5.1 Indirect Electrolysis; 5.2 Intermediates for Families of Reactions; 5.3 Selective Fluorination; 5.4 Two-Phase Electrolysis; 5.5 Electrode Materials; 5.6 Towards Pharmaceutical Products; 5.7 Future Prospects; References; 6 Electrochemical Engineering and Cell Design 327 $a6.1 Principles of Electrochemical Reactor Design6.1.1 Cell Potential; 6.1.2 The Rate of Chemical Change; 6.2 Decisions During the Process of Cell Design; 6.2.1 Strategic Decisions; 6.2.2 Divided and Undivided Cells; 6.2.3 Monopolar and Bipolar Electrical Connections to Electrodes; 6.2.4 Scaling the Cell Current; 6.2.5 Porous 3D Electrode Structures; 6.2.6 Interelectrode Gap; 6.3 The Influence of Electrochemical Engineering on the Chlor-Alkali Industry; 6.4 Parallel Plate Cells; 6.5 Redox Flow Batteries; 6.6 Rotating Cylinder Electrode Cells; 6.7 Conclusions; References 327 $a7 Electrochemical Surface-Enhanced Raman Spectroscopy (EC-SERS): Early History, Principles, Methods, and Experiments7.1 Early History of Electrochemical Surface-Enhanced Raman Spectroscopy; 7.2 Principles and Methods of SERS; 7.2.1 Electromagnetic Enhancement of SERS; 7.2.2 Key Factors Influencing SERS; 7.2.3 "Borrowing SERS Activity" Methods; 7.2.4 Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy; 7.3 Features of EC-SERS; 7.3.1 Electrochemical Double Layer of EC-SERS Systems; 7.3.2 Electrolyte Solutions and Solvent Dependency; 7.4 EC-SERS Experiments 327 $a7.4.1 Measurement Procedures for EC-SERS 330 $aMartin Fleischmann was truly one of the 'fathers' of modern electrochemistry having made major contributions to diverse topics within electrochemical science and technology. 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