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[et al.]$gprefazione di Vittorio Gregotti 210 $aRoma$aBari$cLaterza$d1992 215 $aXIII, 439 p., [18] p. di tav.$cill.$d25 cm 225 1 $aGrandi opere 454 0$12001$a<>Stil in den technischen und tektonischen Künsten oder praktische Ästhetik$933103 610 0 $aArte$aTeorie 610 0 $aArte decorativa 700 1$aSemper,$bGottfried$f<1803-1879>$010638 702 1$aBurelli,$bAugusto Romano 702 1$aGregotti,$bVittorio$f<1927- > 801 0$aIT$bUNINA$gRICA$2UNIMARC 901 $aBK 912 $a990000235710403321 952 $aARCH B 1602$b9026$fFARBC 952 $aMON B 792$b4502 a$fFARBC 952 $aMON B 793$b4502 b$fFARBC 952 $aC 136 CAN$bURB 1929/498$fDARPU 952 $a11.193$b1044$fDARST 959 $aDARPU 959 $aFARBC 959 $aDARST 996 $aStil in den technischen und tektonischen Künsten oder praktische Ästhetik$933103 997 $aUNINA LEADER 05436nam 2200697Ia 450 001 9910146107903321 005 20170926031809.0 010 $a1-282-02819-7 010 $a9786612028199 010 $a0-470-74277-1 010 $a0-470-74280-1 035 $a(CKB)1000000000724221 035 $a(EBL)437443 035 $a(OCoLC)352839830 035 $a(SSID)ssj0000204824 035 $a(PQKBManifestationID)11199489 035 $a(PQKBTitleCode)TC0000204824 035 $a(PQKBWorkID)10190038 035 $a(PQKB)11535459 035 $a(MiAaPQ)EBC437443 035 $a(EXLCZ)991000000000724221 100 $a20081105d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aMolecular chemistry of sol-gel derived nanomaterials$b[electronic resource] /$fRobert Corriu, Nguye?n Trong Anh 210 $aChichester, U.K. $cWiley$dc2009 215 $a1 online resource (212 p.) 300 $a"Originally published in French by E?cole Polytechnique"--T.p. verso. 300 $aIncludes index. 311 $a0-470-72117-0 327 $aMolecular Chemistry of Sol-Gel Derived Nanomaterials; Contents; Preface; About the Authors; 1 Molecular Chemistry and Nanosciences; 1.1 INTRODUCTION; 1.2 SCOPE AND ORIGIN OF NANOSCIENCES: THE 'TOP-DOWN' AND 'BOTTOM-UP' APPROACHES; 1.3 CHEMICAL MUTATION: FROM AN EXPLORATORY TO A CREATIVE SCIENCE; 1.4 CARBON AND CERAMIC FIBERS: THE NANOMATERIAL 'ANCESTORS'; 1.4.1 Carbon Fibers; 1.4.2 SiC, Si3N4 Ceramic Fibers; 1.5 CONCLUSIONS; REFERENCES; 2 Nano-Objects; 2.1 INTRODUCTION; 2.2 PRESENTATION OF NANO-OBJECTS; 2.3 SYNTHESIS OF NANO-OBJECTS; 2.4 THE NANO-OBJECT: ENTRY INTO NANOSCIENCES 327 $a2.4.1 Nano-Objects and the Exploration of the NanoworldREFERENCES; 3 Introduction to Material Chemistry; 3.1 GENERAL REMARKS; 3.1.1 The Difference Between Materials and Chemical Compounds; 3.1.2 Examples of Shaping and Use; 3.2 INORGANIC MATERIALS: CRYSTALS AND GLASSES; 3.3 THERMODYNAMICALLY CONTROLLED ORGANIC-INORGANIC HYBRID MATERIALS; 3.3.1 Crystalline Molecular Materials; 3.3.2 Materials Derived from Hydrothermal Synthesis; 3.4 CERAMIC MATERIALS OBTAINED FROM ORGANOMETALLIC POLYMERS: CERAMICS WITH INTERPENETRATING NETWORKS; 3.5 INORGANIC POLYMER MATERIALS (SOL-GEL PROCESS) 327 $a3.5.1 Inorganic Polymerization: An Introduction3.5.2 Physical Characteristics of the Solid Obtained; 3.5.3 Control of the Texture of Materials; 3.5.4 Solid State NMR: A Very Useful Tool; 3.6 INORGANIC POLYMERIZATION AND MOLECULAR CHEMISTRY; 3.7 SILICA AND MOLECULAR CHEMISTRY: A DREAM TEAM; 3.7.1 Introduction to the Chemistry of Other Oxides; 3.7.2 Generalization to Other Types of Combinations; REFERENCES; 4 From Nano-Object to Nanomaterial; 4.1 THE DIFFERENT TYPES OF NANOMATERIALS; 4.2 INORGANIC POLYMERIZATION: A MAJOR ROUTE TO NANOMATERIALS; 4.3 NANOCOMPOSITE MATERIALS 327 $a4.3.1 Nanocomposites in Silica Matrices4.3.2 Some Developments of Nanocomposites; 4.3.3 Presentation of Potential New Matrices; 4.4 GRAFTED MATERIALS; 4.4.1 Advantages of Solid Supports; 4.4.2 General Remarks; 4.5 SELECTIVE SEPARATION; 4.6 MATERIALS OBTAINED BY POLYCONDENSATION OF MONOSUBSTITUTED TRIALKOXYSILANES; 4.7 MULTISTAGE SYNTHESES - CASCADE REACTIONS; REFERENCES; 5 Nanostructured Materials; 5.1 GENERAL REMARKS; 5.2 SYNTHESIS OF HYBRID NANOMATERIALS; 5.2.1 General Remarks; 5.2.2 Why Silicon and Silica?; 5.2.3 Main Silylation Methods. Some Examples of Synthesis 327 $a5.3 NANOSTRUCTURED HYBRID MATERIALS5.3.1 Examples of the Materials; 5.3.2 Description of Nanostructured Hybrid Materials; 5.3.3 Some Characteristics; 5.4 KINETIC CONTROL OF THE TEXTURE OF NANOSTRUCTURED HYBRID MATERIALS; 5.5 SUPRAMOLECULAR SELF-ORGANIZATION INDUCED BY HYDROGEN BONDS; 5.6 SUPRAMOLECULAR SELF-ORGANIZATION INDUCED BY WEAK VAN DER WAALS TYPE BONDS; 5.6.1 What do We Mean by Self-Organization?; 5.6.2 Chemical Behavior and Self-Organization; 5.6.3 Study of Self-Organization; 5.6.4 Generalization of the Self-Organization Phenomenon; 5.6.5 Study of Tetrahedral Systems 327 $a5.6.6 Kinetic Control of Self-Organization 330 $aPresenting the wide range of synthetic possibilities opened by sol-gel processes in the field of organic-inorganic materials, Molecular Chemistry of Sol-Gel Derived Nanomaterials discusses the state of the art in the synthesis of the various nanomaterials. The text includes examples of applications, including photoluminescent nanocomposites, grafted nanomaterials for selective separations of ions or isotopes, for cascade syntheses, chelation of transition metals and lanthanides by lamellar structured nanomaterials, and immobilized enzymes on mesoporous nanomaterials. 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