LEADER 01377nam0 22003253i 450 001 PUV1353874 005 20231121125622.0 010 $a9788873957829 100 $a20130403d2012 ||||0itac50 ba 101 | $aita 102 $ait 181 1$6z01$ai $bxxxe 182 1$6z01$an 200 1 $a˜Il œCodice veronese in trasparenza$egenesi e formazione del testo delle Istituzioni di Gaio$fFilippo Briguglio 210 $aBologna$cBononia university press$d2012 215 $aXIV, 338 p.$cill.$d24 cm. 225 | $aSeminario giuridico della Universitą di Bologna$v261 410 0$1001CFI0012430$12001 $aSeminario giuridico della Universitą di Bologna$v261$171201$aUniversitą degli studi di Bologna$b : Seminario giuridico$3CFIV007480 606 $aDiritto romano$2FIR$3RMLC001962$9N 676 $a340.54$9Diritto romano$v21 700 1$aBriguglio$b, Filippo$3PALV041250$0241168 790 1$aBriguglio$b, Philippus$3MODV649514$zBriguglio, Filippo 801 3$aIT$bIT-01$c20130403 850 $aIT-FR0098 899 $aBiblioteca Area Giuridico Economica$bFR0098 912 $aPUV1353874 950 0$aBiblioteca Area Giuridico Economica$d 53DEG 25 94$e 53DEG0000002115 VMN A4 $fA $h20120101$i20130403 977 $a 53 996 $aCodice veronese in trasparenza$9830323 997 $aUNICAS LEADER 05725nam 2200793Ia 450 001 9910828353703321 005 20200520144314.0 010 $a9786612490880 010 $a9781282490888 010 $a1282490885 010 $a9780470584118 010 $a0470584114 010 $a9780470584101 010 $a0470584106 035 $a(CKB)2550000000007166 035 $a(EBL)484868 035 $a(SSID)ssj0000335547 035 $a(PQKBManifestationID)11230182 035 $a(PQKBTitleCode)TC0000335547 035 $a(PQKBWorkID)10272548 035 $a(PQKB)10859431 035 $a(Au-PeEL)EBL484868 035 $a(CaPaEBR)ebr10361290 035 $a(CaONFJC)MIL249088 035 $a(PPN)160471532 035 $a(FINmELB)ELB178848 035 $a(MiAaPQ)EBC484868 035 $a(OCoLC)521031694 035 $a(Perlego)2753799 035 $a(EXLCZ)992550000000007166 100 $a20090814d2010 uy 0 101 0 $aeng 135 $aurcn||||||||| 181 $ctxt 182 $cc 183 $acr 200 00$aCarbon-centered free radicals and radical cations $estructure, reactivity, and dynamics /$fedited by Malcolm D. Forbes 205 $a1st ed. 210 $aHoboken, NJ $cWiely$dc2010 215 $a1 online resource (395 p.) 225 1 $aWiley Series of Reactive Intermediates in Chemistry and Biology ;$vv.2 300 $aIncludes index. 311 08$a9780470390092 311 08$a0470390093 327 $aCARBON-CENTERED FREE RADICALS AND RADICAL CATIONS; CONTENTS; About the Volume Editor; Preface to Series; Introduction; Contributors; 1. A Brief History of Carbon Radicals; 2. Intermolecular Radical Additions to Alkynes: Cascade-Type Radical Cyclizations; 2.1 Introduction; 2.2 Cascade Reactions Involving Radicals of Second Row Elements; 2.2.1 Cascade Reactions Initiated by Addition of C-Centered Radicals to Alkynes; 2.2.2 Cascade Reactions Initiated by Addition of O-Centered Radicals to Alkynes (Self-Terminating Radical Oxygenations) 327 $a2.2.3 Cascade Reactions Initiated by Addition of N-Centered Radicals to Alkynes 2.3 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.3.1 Cascade Reactions Initiated by Addition of Sn-Centered Radicals to Alkynes; 2.4 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.4.1 Cascade Reactions Initiated by Addition of S-Centered Radicals to Alkynes; 2.4.2 Cascade Reactions Initiated by Addition of Se-Centered Radicals to Alkynes 327 $a2.5 Cascade Reactions Initiated by Addition of Higher Main Group (V)-Centered Radicals to Alkynes 2.5.1 Cascade Reactions Initiated by Addition of P-Centered Radicals to Alkynes; 3. Radical Cation Fragmentation Reactions in Organic Synthesis; 3.1 Introduction; 3.1.1 Oxidative Carbon-Carbon Bond Cleavage; 3.1.2 Thermodynamic and Kinetic Considerations; 3.1.3 Reactive Intermediate Lifetime; 3.2 Electron Transfer-Initiated Cyclization Reactions; 3.2.1 Rate Enhancement and Mechanistic Studies; 3.2.2 Development of a Catalytic Aerobic Protocol; 3.2.3 Oxidative Cascade Reactions 327 $a3.3 Oxidative Acyliminium Ion Formation 3.4 Carbon-Carbon Bond Formation; 3.4.1 Chemoselectivity and Reactivity; 3.4.2 Reaction Scope; 3.5 Summary and Outlook; 4. Selectivity in Radical Cation Cycloadditions; 4.1 Introduction; 4.2 Mechanism and the Origin of the Rate Acceleration; 4.3 Selectivity in Radical Cation Cycloadditions; 4.4 Chemoselectivity; 4.4.1 Effect of Dienophile Substituents on Chemoselectivity; 4.4.2 Effect of Sensitizers and Solvents on Chemoselectivity; 4.4.3 Effect of Concentrations on Chemoselectivity; 4.4.4 Effect of Electron-Rich Dienophiles on Chemoselectivity 327 $a4.5 Regioselectivity 4.6 Periselectivity; 4.6.1 Effects of Solvent and Concentration on Periselectivity; 4.6.2 Effect of Diene/Dienophile Redox Potentials on Periselectivity; 4.6.3 Substituent and Steric Effects on Periselectivity; 4.6.4 Quantifying Periselectivity Through Ion Pair Association; 4.7 Endo/Exo Selectivity; 4.7.1 Effects of Secondary Orbital Interaction and Solvents on Endo/Exo Selectivity; 4.7.2 Effect of Sensitizer on Endo/Exo Selectivity; 4.7.3 Ion Pairs and Endo/Exo Selectivities; 4.8 Conclusions; 5. The Stability of Carbon-Centered Radicals; 5.1 Introduction 327 $a5.1.1 The Consequences of Different Stability Definitions: How Stable Are Ethyl and Fluoromethyl Radicals? 330 $aCovers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using 410 0$aWiley Series of Reactive Intermediates in Chemistry and Biology 606 $aFree radicals (Chemistry) 606 $aCarbon, Activated 606 $aReactivity (Chemistry) 606 $aCations 615 0$aFree radicals (Chemistry) 615 0$aCarbon, Activated. 615 0$aReactivity (Chemistry) 615 0$aCations. 676 $a547.1224 701 $aForbes$b Malcolm D. E.$f1960-$0882912 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910828353703321 996 $aCarbon-centered free radicals and radical cations$91972365 997 $aUNINA