LEADER 01917oem 2200517Ia 450 001 9910696683703321 005 20080529150857.0 035 $a(CKB)5470000002380021 035 $a(OCoLC)52817629 035 $a(EXLCZ)995470000002380021 100 $a20030808d2003 ca 101 0 $aeng 120 $ab|||||||||||| 121 $a||||||||| 124 $bd 135 $aurcnu|||m|||| 181 $ccrd$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aGeologic map of upper Clayhole Valley and vicinity, Mohave County, northwestern Arizona$b[electronic resource] /$fby George H. Billingsley, and Susan S. Priest 205 $aVersion 1.0. 210 1$aFlagstaff, Ariz. :$cU.S. Geological Survey,$d2003. 215 $a1 electronic map $cHTML, digital, PDF file 225 1 $aU.S. Geological Survey miscellaneous field studies ;$v2418 300 $aRelief shown by contours and spot heights 300 $aTitle from HTML index page (viewed Aug. 8, 2003). 300 $a"Prepared in cooperation with the National Park Service and the Bureau of Land Management"--PDF file. 300 $aAccompanied by pamphlet (28 p.) 300 $aIncludes location map in pamphlet file. 320 $aIncludes bibliographical references in pamphlet (pages 19-21). 606 $aGeology$zArizona$zMohave County$vMaps 608 $aMaps.$2lcgft 615 0$aGeology 700 $aBillingsley$b George H$01392318 701 $aPriest$b Susan S$01391637 712 02$aUnited States.$bNational Park Service. 712 02$aUnited States.$bBureau of Land Management. 712 02$aGeological Survey (U.S.) 801 0$bGIS 801 1$bGIS 801 2$bOCLCQ 801 2$bGPO 906 $aBOOK 912 $a9910696683703321 996 $aGeologic map of upper Clayhole Valley and vicinity, Mohave County, northwestern Arizona$93467673 997 $aUNINA LEADER 01214nam0 22003133i 450 001 NAP0298908 005 20231121125600.0 010 $a2870312148 100 $a20160202d2003 ||||0itac50 ba 101 | $afre 102 $abe 181 1$6z01$ai $bxxxe 182 1$6z01$an 200 1 $aArs et ratio$esciences, art et metiers dans la philosophie hellenistique et romaine$eactes du colloque international organise a Creteil, Fontenay et Paris du 16 au 18 octobre 1997$fedite par C. 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Gigandet 210 $aBruxelles$cLatomus$d2003 215 $a273 p.$d24 cm 225 | $aCollection Latomus$v273 410 0$1001CFI0068341$12001 $aCollection Latomus$v273 702 1$aGigandet$b, Alain$3PUVV343749$4070 702 1$aBesnier$b, Bernard$3RAVV042259$4070 702 1$aLévy$b, Carlos$3VEAV026625$4070 801 3$aIT$bIT-01$c20160202 850 $aIT-FR0017 899 $aBiblioteca umanistica Giorgio Aprea$bFR0017 $eN 912 $aNAP0298908 950 0$aBiblioteca umanistica Giorgio Aprea$d 52MAG 5/1942$e 52FLS0000275465 VMN RS $fA $h20171004$i20171004 977 $a 52 996 $aArs et ratio$9942246 997 $aUNICAS LEADER 05154nam 2200589 a 450 001 9910830708303321 005 20230617035343.0 010 $a1-280-51959-2 010 $a9786610519590 010 $a3-527-60393-X 010 $a3-527-60419-7 035 $a(CKB)1000000000376383 035 $a(EBL)482113 035 $a(OCoLC)68623535 035 $a(SSID)ssj0000204331 035 $a(PQKBManifestationID)11172942 035 $a(PQKBTitleCode)TC0000204331 035 $a(PQKBWorkID)10176359 035 $a(PQKB)10538143 035 $a(MiAaPQ)EBC482113 035 $a(EXLCZ)991000000000376383 100 $a20041018d2004 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aModern fluoroorganic chemistry$b[electronic resource] $esynthesis, reactivity, applications /$fPeer Kirsch 210 $aWeinheim $cWiley-VCH$dc2004 215 $a1 online resource (322 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30691-9 320 $aIncludes bibliographical references and index. 327 $aModern Fluoroorganic Chemistry; Contents; Preface; List of Abbreviations; 1 Introduction; 1.1 Why Organofluorine Chemistry?; 1.2 History; 1.3 The Basic Materials; 1.3.1 Hydrofluoric Acid; 1.3.2 Fluorine; 1.4 The Unique Properties of Organofluorine Compounds; 1.4.1 Physical Properties; 1.4.2 Chemical Properties; 1.4.3 Ecological Impact; 1.4.3.1 Ozone Depletion by Chlorofluorocarbons; 1.4.3.2 Greenhouse Effect; 1.4.4 Physiological Properties; 1.4.5 Analysis of Fluorochemicals: (19)F NMR Spectroscopy; 2 Synthesis of Complex Organofluorine Compounds; 2.1 Introduction of Fluorine 327 $a2.1.1 Perfluorination and Selective Direct Fluorination2.1.2 Electrochemical Fluorination (ECF); 2.1.3 Nucleophilic Fluorination; 2.1.3.1 Finkelstein Exchange; 2.1.3.2 "Naked" Fluoride; 2.1.3.3 Lewis Acid-assisted Fluorination; 2.1.3.4 The "General Fluorine Effect"; 2.1.3.5 Amine-Hydrogen Fluoride and Ether-Hydrogen Fluoride Reagents; 2.1.3.6 Hydrofluorination, Halofluorination, and Epoxide Ring Opening; 2.1.4 Synthesis and Reactivity of Fluoroaromatic Compounds; 2.1.4.1 Synthesis of Fluoroaromatic Compounds; 2.1.4.2 Reductive Aromatization; 2.1.4.3 The Balz-Schiemann Reaction 327 $a2.1.4.4 The Fluoroformate Process2.1.4.5 Transition Metal-assisted Oxidative Fluorination; 2.1.4.6 The Halex Process; 2.1.4.7 Think Negative! - "Orthogonal" Reactivity of Perfluoroaromatic and Perfluoroolefinic Systems; 2.1.4.8 The "Special Fluorine Effect"; 2.1.4.9 Aromatic Nucleophilic Sustitution; 2.1.4.10 Activation of the Carbon-Fluorine Bond by Transition Metals; 2.1.4.11 Activation of Fluoroaromatic Compounds by ortho-Metalation; 2.1.5 Transformations of Functional Groups; 2.1.5.1 Hydroxy into Fluoro; 2.1.5.2 Conversion of Carbonyl into gem-Difluoromethylene 327 $a2.1.5.3 Carboxyl into Trifluoromethyl2.1.5.4 Oxidative Fluorodesulfuration; 2.1.6 "Electrophilic" Fluorination; 2.1.6.1 Xenon Difluoride; 2.1.6.2 Perchloryl Fluoride and Hypofluorides; 2.1.6.3 "NF"-Reagents; 2.2 Perfluoroalkylation; 2.2.1 Radical Perfluoroalkylation; 2.2.1.1 Structure, Properties, and Reactivity of Perfluoroalkyl Radicals; 2.2.1.2 Preparatively Useful Reactions of Perfluoroalkyl Radicals; 2.2.1.3 "Inverse" Radical Addition of Alkyl Radicals to Perfluoroolefins; 2.2.2 Nucleophilic Perfluoroalkylation; 2.2.2.1 Properties, Stability, and Reactivity of Fluorinated Carbanions 327 $a2.2.2.2 Perfluoroalkyl Metal Compounds2.2.2.3 Perfluoroalkyl Silanes; 2.2.3 "Electrophilic" Perfluoroalkylation; 2.2.3.1 Properties and Stability of Fluorinated Carbocations; 2.2.3.2 Aryl Perfluoroalkyl Iodonium Salts; 2.2.3.3 Perfluoroalkyl Sulfonium, Selenonium, Telluronium, and Oxonium Salts; 2.2.4 Difluorocarbene and Fluorinated Cyclopropanes; 2.3 Selected Fluorinated Structures and Reaction Types; 2.3.1 Difluoromethylation and Halodifluoromethylation; 2.3.2 The Perfluoroalkoxy Group; 2.3.3 The Perfluoroalkylthio Group and Sulfur-based Super-electron-withdrawing Groups 327 $a2.3.4 The Pentafluorosulfuranyl Group and Related Structures 330 $aIn this handbook, Peer Kirsch clearly shows that this exciting field is no longer an exotic area of research. Aimed primarily at synthetic chemists wanting to gain a deeper understanding of the fascinating implications of including the highly unusual element fluorine in organic compounds, the main part of the book presents a wide range of synthetic methodologies and the experimental procedures selected undeniably show that this can be done with standard laboratory equipment. To round off, the author looks at fluorous chemistry and the applications of organofluorine compounds in liquid crystals 606 $aOrganofluorine compounds 615 0$aOrganofluorine compounds. 676 $a547.02 676 $a547.6 700 $aKirsch$b Peer$01606153 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830708303321 996 $aModern fluoroorganic chemistry$93931795 997 $aUNINA