LEADER 05695nam 2200685 a 450 001 9910816824503321 005 20240314011432.0 010 $a1-118-62999-X 010 $a1-118-62987-6 010 $a1-118-63016-5 035 $a(CKB)2670000000392108 035 $a(EBL)1273519 035 $a(OCoLC)830124718 035 $a(SSID)ssj0000917547 035 $a(PQKBManifestationID)11576131 035 $a(PQKBTitleCode)TC0000917547 035 $a(PQKBWorkID)10891946 035 $a(PQKB)10727329 035 $a(MiAaPQ)EBC1273519 035 $a(DLC) 2013010397 035 $a(Au-PeEL)EBL1273519 035 $a(CaPaEBR)ebr10731784 035 $a(CaONFJC)MIL504424 035 $a(PPN)219563942 035 $a(EXLCZ)992670000000392108 100 $a20150303d2013 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aTransition-metal-mediated aromatic ring construction /$fedited by Ken Tanaka 205 $a1st ed. 210 $aHoboken, N.J. $cWiley$dc2013 215 $a1 online resource (831 p.) 300 $aDescription based upon print version of record. 311 $a1-118-14892-4 320 $aIncludes bibliographical references and index. 327 $aTRANSITION-METAL-MEDIATEDAROMATIC RING CONSTRUCTION; CONTENTS; CONTRIBUTORS; PREFACE; PART I [2 + 2 + 2] AND RELATED CYCLOADDITION REACTIONS; 1 Cobalt-Mediated [2+2+2] Cycloaddition; 1.1 Introduction; 1.2 Synthesis of Benzenes; 1.2.1 New Catalytic Systems; 1.2.2 New Cyclization Partners; 1.2.3 Chemo- and Regioselectivity Issues; 1.3 Synthesis of Heterocycles; 1.3.1 New Catalytic Systems; 1.3.2 New Cyclization Partners; 1.3.3 Chemo- and Regioselectivity Issues; 1.4 Mechanistic Aspects; 1.5 Synthetic Applications; 1.5.1 Natural Products and Naturally Occurring Scaffolds; 1.5.2 Polyphenylenes 327 $a1.6 Summary and OutlookReferences; 2 Nickel-Mediated [2+2+2] Cycloaddition; 2.1 Introduction; 2.2 Synthesis of Benzenes; 2.3 Cycloaddition of Alkynes and Nitriles; 2.4 Cycloaddition of Alkynes and Imines; 2.5 Cycloaddition of Alkynes and Carbon Dioxide; 2.6 Cycloaddition of Alkynes and Isocyanates; 2.7 Cycloaddition of Alkynes and Carbodiimide; 2.8 Cycloaddition of Diynes and Ketenes; 2.9 Cycloaddition of Arynes; 2.10 Mechanism; 2.10.1 Coupling of Alkynes and Allene; 2.10.2 Cycloaddition of Alkyne and Nitrile; 2.10.3 Cycloaddition of Alkynes and Heterocumulenes; 2.10.4 Cycloaddition of Arynes 327 $a2.11 Summary and OutlookReferences; 3 Ruthenium-Mediated [2+2+2] Cycloaddition; 3.1 Introduction; 3.2 Synthesis of Benzenes; 3.2.1 Cyclotrimerization; 3.2.2 Cross-Cyclotrimerization; 3.2.3 Partially Intramolecular Cyclotrimerizations; 3.2.4 Fully Intramolecular Cyclotrimerization; 3.2.5 Cyclotrimerization of Alkynylboronates and 1-Haloalkynes; 3.3 Synthesis of Heterocycles; 3.3.1 Cyclocotrimerization of Alkynes with Nitriles to Form Pyridines; 3.3.2 Cyclocotrimerization of Alkynes with Heterocumulenes; 3.4 Mechanism of Ruthenium-Catalyzed [2+2+2] Cycloadditions; 3.5 Synthetic Applications 327 $a3.5.1 Synthesis of Biologically Interesting Molecules3.5.2 Synthesis of Polyaromatic Functional Molecules; 3.6 Summary and Outlook; References; 4 Rhodium-Mediated [2+2+2] Cycloaddition; 4.1 Introduction; 4.2 Synthesis of Benzenes; 4.2.1 Intermolecular Reactions Catalyzed by Neutral Rhodium Complexes; 4.2.2 Intermolecular Reactions Catalyzed by Cationic Rhodium Complexes; 4.2.3 Intramolecular Reactions Catalyzed by Neutral Rhodium Complexes; 4.2.4 Intramolecular Reactions Catalyzed by Cationic Rhodium Complexes; 4.3 Synthesis of Pyridines; 4.3.1 Intermolecular Reactions 327 $a4.3.2 Intramolecular Reactions4.4 Synthesis of Pyridones and Related Heterocycles; 4.4.1 Intermolecular Reactions; 4.4.2 Intramolecular Reactions; 4.5 Summary and Outlook; References; 5 Iridium-Mediated [2+2+2] Cycloaddition; 5.1 Introduction; 5.2 Synthesis of Benzene Derivatives; 5.3 Synthesis of Heterocyclic Compounds; 5.4 Mechanistic Aspects; 5.5 Summary and Outlook; References; 6 [2+2+2] and Related Cycloadditions Mediated by Other Transition Metals; 6.1 Introduction; 6.2 Palladium-Catalyzed [2+2+2] and [2+2+1] Cycloadditions; 6.2.1 [2+2+2] Cycloaddition; 6.2.2 [2+2+1] Cycloaddition 327 $a6.3 Iron-Catalyzed [2+2+2] Cycloaddition 330 $a"Recent significant advances with transition-metal-mediated reactions have opened promising new routes to complex aromatic compounds and have been the subject of intense research in recent years. Featuring practical and efficient reactions to help organic chemists synthesize an important class of compounds, Transition-Metal-Mediated Aromatic Ring Construction provides a valuable guide to methods, synthetic routes, and strategies to construct aromatic rings. 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