01256nam 2200337Ia 450 99638774460331620221108102650.0(CKB)4940000000085650(EEBO)2240872140(OCoLC)38876069(EXLCZ)99494000000008565019980331d1658 uy |engurbn||||a|bb|Mankinds jubilee, or, Good tidings of great joy for all people[electronic resource] plainly discovered by Scripture texts ... shewing that there is a common salvation of all men ... /written by Christopher Wade, An. Dom 1658London Written for the use and benefit of Thomas Gibbs1658[10], 112 pErrata: p. 112.Imperfect: stained.Reproduction of original in: William Andrews Clark Memorial Library, University of California, Los Angeles.eebo-0189SalvationEarly works to 1800SalvationWade Christopher17th cent.1007732EAEEAEWaOLNBOOK996387744603316Mankinds jubilee, or, Good tidings of great joy for all people2322299UNISA04034nam 22007095 450 991073579600332120251008154952.0981-9941-21-010.1007/978-981-99-4121-6(MiAaPQ)EBC30663095(Au-PeEL)EBL30663095(DE-He213)978-981-99-4121-6(PPN)272251925(CKB)27857098300041(EXLCZ)992785709830004120230724d2023 u| 0engurcnu||||||||txtrdacontentcrdamediacrrdacarrierIron-Catalyzed C-H/C-H Coupling for Synthesis of Functional Small Molecules and Polymers /by Takahiro Doba1st ed. 2023.Singapore :Springer Nature Singapore :Imprint: Springer,2023.1 online resource (xiv, 153 pages) illustrations (some color)Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5061Print version: Doba, Takahiro Iron-Catalyzed C-H/C-H Coupling for Synthesis of Functional Small Molecules and Polymers Singapore : Springer,c2023 9789819941209 Includes bibliographical references.1. General Introduction -- 2. Iron-Catalyzed Regioselective Thienyl C–H/C–H Homocoupling -- 3. Development of a Synthetic Method for Tridentate Phosphine Ligands -- 4. Iron-Catalyzed Regioselective Thienyl C–H/C–H Polycondensation -- 5. Iron-Catalyzed Oxidative C–H Alkenylation of Thiophenes with Enamines -- 6. Conclusions and Perspectives. .This thesis describes the development of iron-catalyzed thienyl C–H/C–H coupling. This is applied to the synthesis of highly conjugated and electron-rich thiophene compounds of interest in materials science by utilization of low redox potential of iron in combination with a mild oxalate oxidant. Transition-metal-catalyzed C(sp2)–H/C(sp2)–H coupling has attracted much attention as one of the most straightforward methods to construct C(sp2)–C(sp2) bonds. However, application of this ideal transformation to the synthesis of redox-sensitive pi-materials was hindered by the requirement of a strong oxidant for catalyst turnover. This limitation originates primarily from the large redox potential of conventional transition-metal catalysts such as palladium and rhodium. This thesis shows that the efficiency of C–H activation was significantly improved by introduction of a new conjugated tridentate phosphine ligand, giving direct access to polymeric thiophene materials from simple thiophene monomers. Considering the importance of environmentally friendly organic synthesis in terms of UN Sustainable Development Goals, the reactions described herein highlight the potential of iron, the most abundant transition-metal on earth, for the direct synthesis of functional small molecules and polymers of importance in energy device applications.Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5061Organometallic chemistryChemistryCatalysisMaterialsForce and energyPolymerizationOrganometallic ChemistryChemical SynthesisCatalysisMaterials for Energy and CatalysisPolymer SynthesisOrganometallic chemistry.Chemistry.Catalysis.Materials.Force and energy.Polymerization.Organometallic Chemistry.Chemical Synthesis.Catalysis.Materials for Energy and Catalysis.Polymer Synthesis.547Doba Takahiro1379293MiAaPQMiAaPQMiAaPQBOOK9910735796003321Iron-Catalyzed C-H3418728UNINA