01621nam 2200337Ia 450 99638533090331620200824132647.0(CKB)4940000000075528(EEBO)2240930438(OCoLC)ocm12193729e(OCoLC)12193729(EXLCZ)99494000000007552819850624d1670 uy |engurbn||||a|bb|Campanella revived, or, An enquiry into the history of the Royal Society, whether the virtuosi there do not pursue the projects of Campanella for the reducing England unto Popery[electronic resource] being the extract of a letter to a person of honour from H.S. with another letter to Sir N.N. relating the cause of the quarrel betwixt H.S. and the R.S. and an apology against some of their cavils : with a postscript concerning the quarrel depending betwixt H.S. and Dr. MerrettLondon Printed for the author1670[6], 22 pReproduction of original in Osler Library, McGill University.Attributed to Henry Stubbs [Stubbe]. cf. NUC pre-1956.Includes a discussion of Tommaso Campanella's De monarchia hispanica.eebo-0107Stubbe Henry1632-1676.1001567EAAEAAm/cWaOLNBOOK996385330903316Campanella revived, or, An enquiry into the history of the Royal Society, whether the virtuosi there do not pursue the projects of Campanella for the reducing England unto Popery2366662UNISA05179nam 2200625Ia 450 991083053070332120230725041532.01-282-68724-797866126872420-470-68190-X0-470-68189-6(CKB)2520000000006780(EBL)477857(OCoLC)592756314(SSID)ssj0000339805(PQKBManifestationID)11215288(PQKBTitleCode)TC0000339805(PQKBWorkID)10364900(PQKB)10365764(MiAaPQ)EBC477857(EXLCZ)99252000000000678020090807d2010 uy 0engur|n|---|||||txtccrLewis basicity and affinity scales[electronic resource] data and measurement /Christian Laurence, Jean-Franc ʹois GalChichester Wiley20101 online resource (490 p.)Description based upon print version of record.0-470-74957-1 Lewis Basicity and Affinity Scales; Contents; Preface; 1 Lewis Basicity and Affinity Measurement: Definitions and Context; 1.1 The Br ̈onsted Definition of Acids and Bases; 1.2 Scales of Br ̈onsted Basicity and Affinity in Solution; 1.3 Scales of Br ̈onsted Basicity and Affinity in the Gas Phase; 1.4 The Lewis Definition of Acids and Bases; 1.5 Quantum Chemical Descriptions of Lewis Acid/Base Complexes; 1.5.1 Valence-Bond Model; 1.5.2 Perturbation Molecular Orbital Theory; 1.5.3 Variational Supermolecular Method and Energy Decomposition Schemes; 1.5.4 Natural Bond Orbital Theory1.5.5 Quantum Theory of Atoms in Molecules1.6 Measurement of Lewis Basicity; 1.6.1 Gas-phase Reactions; 1.6.2 Solution Reactions; 1.6.3 Standard State Transformations; 1.6.4 Choice of Solvent; 1.7 Measurement of Lewis Affinity; 1.8 The Role of the Solvent; 1.9 Spectroscopic Scales of Basicity (Affinity); 1.10 Polybasic Compounds; 1.11 Attempts at a Quantitative Formulation of the Lewis Definition of Acids and Bases; 1.11.1 Hard and Soft Acids and Bases; 1.11.2 The ECW and ECT Models; 1.11.3 The Beta and Xi Equation; 1.11.4 A Chemometric Approach1.11.5 Quantum Chemical Descriptors for Basicity Scales1.12 Concluding Remarks and Content of Chapters 2-7; References; 2 The Donor Number or SbCl5 Affinity Scale; 2.1 Structure of SbCl5 Complexes; 2.2 Definition of the Donor Number Scale; 2.3 Experimental Determination of the Donor Number; 2.4 The Donor Number Scale: Data; 2.5 Critical Discussion; References; 3 The BF3 Affinity Scale; 3.1 Structure of BF3 Complexes; 3.2 Definition of the BF3 Affinity Scale; 3.3 Experimental Determination of the BF3 Affinity Scale; 3.4 The BF3 Affinity Scale: Data; 3.5 Discussion; 3.5.1 Medium Effects3.5.2 Hardness of BF33.5.3 Comparison of the BF3 and SbCl5 Affinity Scales; 3.5.4 Computation of the BF3 Affinity; 3.6 Conclusion; References; 4 Thermodynamic and Spectroscopic Scales of Hydrogen-Bond Basicity and Affinity; 4.1 Structure of Hydrogen-Bonded Complexes; 4.2 Hydrogen-Bond Basicity Scales: Early Works; 4.3 The 4-Fluorophenol Hydrogen-Bond Basicity Scale; 4.3.1 Definition; 4.3.2 Method of Determination; 4.3.3 Polyfunctional Hydrogen-Bond Acceptors; 4.3.4 Data; 4.3.5 Range of Validity of the Scale; 4.4 Hydrogen-Bond Affinity Scales: Early Studies4.5 The 4-Fluorophenol Affinity Scale4.6 Comparison of 4-Fluorophenol Affinity and Basicity Scales; 4.7 Spectroscopic Scales; 4.7.1 Infrared Shift of Methanol; 4.7.2 Solvatochromic Shifts of 4-Nitrophenol and 4-Nitroaniline; 4.8 Conclusion; References; 5 Thermodynamic and Spectroscopic Scales of Halogen-Bond Basicity and Affinity; 5.1 Structure of Halogen-Bonded Complexes; 5.2 The Diiodine Basicity Scale; 5.2.1 Definition of the Scale; 5.2.2 Methods for the Determination of Diiodine Complexation Constants; 5.2.3 Temperature Correction; 5.2.4 Solvent Effects; 5.2.5 Data5.3 Is the Diiodine Basicity Scale a General Halogen-Bond Basicity Scale?The Lewis concept of acids and bases is discussed in every general, organic and inorganic chemistry textbook. This is usually just a descriptive treatment, as it is not possible to devise a single numerical scale suitable for all occasions. However quantitative Lewis acid-base chemistry can be developed by compiling reaction-specific basicity scales which can be used in specific branches of chemistry and biochemistry. Lewis Basicity and Affinity Scales: Data and Measurementbrings together for the first time a comprehensive range of Lewis basicity/affinity data in one volume. More tLewis acidsChemistryLewis acids.Chemistry.541.39541.395546.24Laurence Christian1666537Gal Jean-Franc ʹois1666538MiAaPQMiAaPQMiAaPQBOOK9910830530703321Lewis basicity and affinity scales4025845UNINA