05288nam 22006374a 450 99620553790331620230828225222.01-280-74823-097866107482350-470-98858-41-4051-7293-2(CKB)1000000000341918(EBL)284280(OCoLC)86087477(SSID)ssj0000216316(PQKBManifestationID)11912287(PQKBTitleCode)TC0000216316(PQKBWorkID)10194360(PQKB)10942310(MiAaPQ)EBC284280(EXLCZ)99100000000034191820060303d2006 uy 0engur|n|---|||||txtccrOrganofluorine chemistry[electronic resource] /Kenji UneyamaOxford ;Ames, Iowa Blackwell Pub.20061 online resource (352 p.)Description based upon print version of record.1-4051-2561-6 Includes bibliographical references and index.Organofluorine Chemistry; Contents; Preface; 1 Fundamentals in Organic Fluorine Chemistry; 1.1 Some physical properties of organic fluorine compounds; 1.1.1 Effect of the fluorine atom on the molecular orbital energy levels of organic molecules and refractive index; 1.1.2 Boiling points; 1.1.3 Miscibility; 1.1.4 Lipophilicity; 1.1.5 Gas solubility; 1.1.6 Surface tension; 1.1.7 Summary; 1.2 Electronic effect; 1.2.1 Electronic effects of the fluorine atom: insight fromHammett substituent constants; 1.2.2 Electronic effects on acidity, bond length, and bond energy of fluoroorganic molecules1.2.3 Halogen bonding1.2.4 Electronic effect on the destabilization of carbonyl and imono groups; 1.2.5 pi-pi Stacking of fluoroaromatics; 1.2.6 Increased p-character (Bent's rule) and low-lying LUMO in carbon-fluorine bonding orbitals; 1.2.7 Negative hyperconjugation; 1.2.8 Electron-donating effect (stabilization of carbocation); 1.2.9 Effect of fluorine substituents on the structure, stability, and reactivity of fluoroalkyl radicals; 1.3 Steric effects of fluorine substituents; References; 2 Unique Reactions Induced by Fluorine; 2.1 Nucleophilic substitution on fluoroaromatic rings2.2 SN2' reactions of alkenes bearing a trifluoromethyl group2.3 Nucleophilic substitution on the gem-difluoromethylene double bond; 2.4 Single electron transfer reaction of perfluoroalkyl halides; 2.5 Fluorine-activated electrophilic reagents (F-X and XFn); 2.5.1 Halogen monofluoride (F-halogen); 2.5.2 Bromine trifluoride (BrF3); 2.5.3 Iodine pentafluoride (IF5); 2.5.4 Iodoarene difluoride (ArIF2); 2.5.5 Benzeneselenenyl fluoride (PhSeF); 2.5.6 tert-Butyl and methyl hypofluorites; 2.5.7 Hypofluorous acid - MeCN complex (HOF - MeCN); References3 Reactions Activated by a Strong Interaction Between Fluorine and Other Atoms3.1 Reaction induced by F-Li interaction; 3.1.1 Li-F interaction in aromatic C-F bonds; 3.1.2 Li-F interaction in aliphatic C-F bonds; 3.2 The fluorine-aluminum interaction; 3.3 Reactions induced by F-Si interaction; 3.3.1 Fluoride-ion mediated desilylative alkylations; 3.4 Reactions induced by B-F interaction; 3.5 Reactions activated by a strong interaction between fluorine and Sm, Yb, Sn, Ti; References; 4 Hydrogen Bonding in Organofluorine Compounds; 4.1 Organofluorine as a hydrogen-bonding acceptor4.1.1 Definition and classifications of hydrogen bonds4.1.2 Some examples of O-H · · · F-C and N-H· · ·F -C hydrogen-bonding systems; 4.1.3 Some examples on nonconventional hydrogen bonding: C-H· · ·F-C interactions; 4.1.4 Summary of organic fluorine as hydrogen-bonding acceptor; 4.2 Hydrogen bonding of B-fluorinated alcohols, its structural character, and utilization in organic syntheses; 4.2.1 Use of TFE and HFIP for protonating agents and/or protonating solvents; 4.2.2 Use of TFE and HFIP for cation-stabilizing solvents; References; 5 Fluorinated Ligands for Selective Catalytic Reactions5.1 Ligands with fluorine-substituted aryl groupsThe replacement of hydrogen with fluorine in organic molecules can profoundly influence their chemical and physical properties, leading to a range of compounds with highly desirable properties. These molecules are of interest across the wide spectrum of industrial and academic organic chemistry, so that organofluorine chemistry is economically highly important.Organofluorine Chemistry will help chemists to develop a systematic knowledge of the chemistry of fluorine with a view towards its application in the design of new reactions and syntheses, and the creation of novel fluorinated moOrganofluorine compoundsSynthesisHydrogen bondingLigands (Biochemistry)Organofluorine compoundsSynthesis.Hydrogen bonding.Ligands (Biochemistry)547.02547/.02Uneyama Kenji860648MiAaPQMiAaPQMiAaPQBOOK996205537903316Organofluorine chemistry1920507UNISA04450nam 2200769 450 991078051500332120230912140426.01-4426-8361-997866120032331-282-00323-210.3138/9781442683617(CKB)2430000000000780(EBL)3254801(OCoLC)923068270(SSID)ssj0000313540(PQKBManifestationID)11925286(PQKBTitleCode)TC0000313540(PQKBWorkID)10367032(PQKB)11390965(CaBNvSL)thg00600121(DE-B1597)465132(OCoLC)1004872610(OCoLC)944177158(DE-B1597)9781442683617(Au-PeEL)EBL4672268(CaPaEBR)ebr11257942(OCoLC)958562733(VaAlCD)20.500.12592/jxfqg2(schport)gibson_crkn/2009-12-01/6/418261(MiAaPQ)EBC4672268(OCoLC)815763530(MdBmJHUP)musev2_105550(MiAaPQ)EBC3254801(EXLCZ)99243000000000078020160922h20022002 uy 0engur|n|---|||||txtrdacontentcrdamediacrrdacarrierWomen's legal strategies in Canada /editor, Radha JhappanToronto ;Buffalo, [New York] ;London :University of Toronto Press,2002.©20021 online resource (418 pages)Description based upon print version of record.0-8020-7667-X 0-8020-0721-X Includes bibliographical references.Introduction : why do law? -- Introduction : feminist adventures in law / Radha Jhappan -- Feminist movement in law : beyond privileged and privileging theory / Sheila McIntyre -- Equality strategies -- Women's (in)equality before and after the charter / Diana Majury -- Towards a democratic practice of feminist litigation? : LEAF's changing approach to Charter equality / Lise Gotell -- The equality pit or the rehabilitation of justice? / Radha Jhappan -- Race and citizenship -- Negotiating the citizenship divide: foreign domestic worker policy and legal jurisprudence / Daiva Stasiulis and Abigail B. Bakan -- Beyond the confinement of gender: locating the space of legal existence for racialized women / Joanne St. Lewis -- Family and reproduction -- Abortion litigation / Sheilah L. Martin -- Legal as political strategies in the Canadian women's movement : who's speaking? who's listening? / Susan Philips.Have Canadian women gained from their pursuit of legal remedies to social, political, economic, and cultural inequalities? Is law a fruitful avenue for such struggles? Using liberal feminist, postmodern, critical, race, and queer theory, these essays confront the anti-rights critiques of the legal Left regarding the use of law in general and the Charter in particular. Several chapters explicitly examine the strategic limits and possibilities of the substantive equality rights approaches pursued by LEAF (The Women's Legal Education and Action Fund). Others focus on legal strategies mobilized in discreet areas of law and public policy by foreign domestic workers and racialized women, lesbians, women seeking reproductive freedom, women in the childcare movement, and anti-violence advocates. Recognizing the diversity of women across class, citizenship, race and ethnicity, sexual identity, culture, and (dis)ability, this collection evaluates the efficacy of the wide range of legal and political strategies women have employed, particularly in this post-Charter era. Women's Legal Strategies in Canada is the most comprehensive account of these important issues and will surely become the standard work in the field.WomenLegal status, laws, etcCanadaWomen's rightsCanadaFeminist jurisprudenceCanadaCanadafastElectronic books. WomenLegal status, laws, etc.Women's rightsFeminist jurisprudence342.71/0878Jhappan RadhaMiAaPQMiAaPQMiAaPQBOOK9910780515003321Women's legal strategies in Canada3760158UNINA