05126nam 2200613Ia 450 99620316330331620230213211431.01-282-36259-30-470-14360-60-470-14400-9(CKB)1000000000376797(EBL)456247(OCoLC)609844933(SSID)ssj0000715396(PQKBManifestationID)11442925(PQKBTitleCode)TC0000715396(PQKBWorkID)10700621(PQKB)11712589(MiAaPQ)EBC456247(EXLCZ)99100000000037679720750609d1969 uy 0engur|n|---|||||txtccrStochastic processes in chemical physics[electronic resource] /edited by K.E. ShulerNew York Interscience19691 online resource (408 p.)Advances in chemical physics ;v. 15Description based upon print version of record.0-471-78967-4 Includes bibliographical references and index.Stochastic Processes in Chemical Physics; CONTENTS; Probabilistic and Dynamic Approaches to the Theory of Stochastic Processes; I. Introduction; II. Probabilistic Preliminaries; III. Master Equations; IV. Langevin Equation; Quantum States and Dissipative Processes; I. Introduction; II. Einstein's Theory of Spontaneous Emission in Unstable Particles; III. Mechanisms of Dissipation; IV. Probability Amplitudes and Quantum Time; V. Quantum States of Finite Lifetime; VI. Kinetic Equations : Feynman Diagrams and Correlation Diagrams; VII. Boltzmann ApproximationVIII. Physical Particles and EntropyIX. Kinetic Equations and Quantum States; X. Conclusions and Perspectives; Relaxed Motion in Irreversible Molecular Statistics; I. The Basic Enigma; II. The Basic Macroscopic Functions; III. The Boundary Forces; IV. The information Content of Probability Statements; V. Heuristic Introduction to Relaxed Motion; VI. Plan of Explicit Calculation; VII. Solution in a Siniplitied Case: "Vestiginal Forces"; VIII-IX. Calculation of the Information Integrals; X. The Variational Principle; XI. The Linear Approximation; XII. GeneralizationThermal Fluctuations in Nonlinear SystemsI. Introduction: The Linear Case; II. The Nonlinear Problem; III. The Master Equation; IV. Expansion of the Master Equation; V. Additional Remarks; VI. The Microscopic Description; VII. The Microscopic Equations of Motion; Error Bounds and Spectral Densities; I. Introduction; II. Properties of Spectral Densities; III. Error Bounds for Averages of Spectral Densities; A. Error Bounds for the Response to a Damped Harmonic Perturbation; B. Error Bounds for Cumulative Distribution; C. Error Bounds for Second-Order Perturbation EnergiesIV. Extrapolation Methods for Spectral DensitiesV. Summary and Discussion; A Stochastic Theory of Line Shape; I. Introduction; II. Random Frequency Modulation; III. Two, Simple Examples; a. Two State Jump Modulation; b. Gaussian Modulation; IV. Collapse of an NMR Multiplet; V. Low Field Spin Resonance; VI. Spectrum of Excitations to a Doublet with a Random Modulation; VII. Random Stark Modulation of a Hydrogen Atom; VIII. Line Shape of Mossbauer Spectra; IX. Concluding Remarks; A Stochastic Model for Neutron Scattering by Simple Liquids; I. Model CalculationsII. Scattering from H2 in Liquid ArgonFluctuations in Autocorrelation Functions in Diffusing Systems; I. Introduction; II. Definitions; III. Method; IV. Results; A. Harmonically Bound Particle; B. Particle in a Box; C. Plane Rotor; D. Spherical Rotor; V. Relaxation Times; VI. Discussion; Stochastic Theory of Chemical Rate Processes; I. Introduction; II. Random Walk Model of Unimolecular Decomposition; III. Exactly Solvable Elementary Reactions; IV. Selected Applications; A. Kinetics of Reactant Isolation; B. Reaction Kinetics on Linear Lattices with Neighbor EffectsC. Kinetics of Photochemical Reactions in Nucleic Acid DerivativesThe Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.Advances in chemical physics ;v. 15.Stochastic processesChemistry, Physical and theoreticalStochastic processes.Chemistry, Physical and theoretical.519.2Shuler Kurt E(Kurt Egon),1922-12917MiAaPQMiAaPQMiAaPQBOOK996203163303316Stochastic processes in chemical physics3004704UNISA