05178nam 2200613Ia 450 99620315860331620230421044557.01-281-75869-897866117586913-527-61553-93-527-61552-0(CKB)1000000000376822(EBL)482276(OCoLC)261559573(SSID)ssj0000120434(PQKBManifestationID)11142893(PQKBTitleCode)TC0000120434(PQKBWorkID)10092814(PQKB)11294570(MiAaPQ)EBC482276(EXLCZ)99100000000037682219941123d1995 uy 0engur|n|---|||||txtccrChemical kinetics of solids[electronic resource] /Hermann SchmalzriedWeinheim ;New York VCHc19951 online resource (452 p.)Description based upon print version of record.3-527-29094-X Includes bibliographical references and indexes.Chemical Kinetics of Solids; Preface; Table of Contents; Symbols and Definitions; 1 Introduction; 1.1 Scope; 1.2 Historical Remarks; 1.3 Four Basic Kinetic Situations; 1.3.1 Homogeneous Reactions: Point Defect Relaxation; 1.3.2 Steady State Flux of Point Defects in a Binary Compound; 1.3.3 The Kinetics of an Interface Reaction; 1.3.4 Kinetics of Compound Formation: A + B = AB; References; 2 Thermodynamics of Point Defects; 2.1 Introduction; 2.2 Thermodynamics of Crystals; 2.2.1 Phenomenological Approach; 2.2.2 Remarks on Statistical Thermodynamics of Point Defects2.3 Some Practical Aspects of Point Defect Thermodynamics2.4 Point Defects in Solid Solutions; 2.5 Conclusions; References; 3 One- and Two-Dimensional Defects in Crystals; 3.1 Introduction; 3.2 Dislocations; 3.2.1 Strain, Stress, and Energy; 3.2.2 Kinetic Effects Due to Dislocations; 3.3 Grain Boundaries; 3.3.1 Structure and Energy of Grain Boundaries; 3.3.2 Phase Boundaries in Solids; 3.4 Mobility of Dislocations, Grain Boundaries, and Phase Boundaries; References; 4 Basic Kinetic Concepts and Situations; 4.1 Introduction; 4.1.1 Systematics of Solid State Chemical Processes4.2 The Concepts of Irreversible Thermodynamics4.2.1 Structure Element Fluxes; 4.3 Diffusion; 4.3.1 Introduction; 4.3.2 Fickian Transport; 4.3.3 Chemical Diffusion; 4.4 Transport in Ionic Solids; 4.4.1 Introduction; 4.4.2 Transport in Binary Ionic Crystals AX; 4.5 Transport Across Phase Boundaries; 4.5.1 Introduction. Equilibrium Phase Boundaries; 4.5.2 Non-Equilibrium Phase Boundaries; 4.6 Transport in Semiconductors; Junctions; 4.6.1 Introduction; 4.6.2 The (p-n) Junction; 4.7 Basic Rate Equations for Homogeneous Reactions; 4.7.1 Introduction; 4.7.2 Rate Equations; References5 Kinetics and Dynamics. Local Equilibrium5.1 Introduction; 5.1.1 Linear Response; 5.1.2 Transition State; 5.1.3 Brownian Motion; 5.2 Kinetic Parameters and Dynamics; 5.2.1 Phenomenological Coefficients and Kinetic Theory; 5.2.2 Correlation of Atomic Jumps; 5.2.3 Conductivity of Ionic Crystals: Frequency Dependence; 5.2.4 Diffusive Motion and Phonons; 5.3 Relaxation of Irregular Structure Elements; 5.3.1 Introduction; 5.3.2 Relaxation of Structure Elements in Nonstoichiometric Compounds A1-δ0; 5.3.3 Relaxation of Intrinsic Disorder; 5.4 Defect Equilibration During Interdiffusion5.4.1 The Atomistics of Interdiffusion5.4.2 The Kirkendall Effect; 5.4.3 Local Defect Equilibration During Interdiffusion; 5.4.4 Interdiffusion of Heterovalent Compounds; References; 6 Heterogeneous Solid State Reactions; 6.1 Introduction; 6.2 Nucleation and Initial Growth; 6.2.1 Introductory Remarks; 6.2.2 Nucleation Kinetics; 6.2.3 Early Growth; 6.3 Compound Formation; 6.3.1 Formation Kinetics of Double Salts; 6.3.2 Formation of Multiphase Products; 6.4 Displacement Reactions; 6.5 Powder Reactions; 6.5.1 General; 6.5.2 Self-propagating Exothermic Powder Reactions; 6.6 Interface Rate Control6.7 Thermal Decomposition of SolidsMany different chemical processes take place inside solids or at solid surfaces and interfaces. However, their quantitative description sometimes seems difficult to understand. This book by Professor Schmalzried, author of the eminently successful Solid State Reactions; bridges the gap between the 'physical' and 'chemical' approaches to this subject because it is written in a language which both sides understand. For the first time, a comprehensive coverage of the rapidly developing field of Solid State Kinetics is available.The topics covered in this book go far beyond diffusional traSolid state chemistryChemical kineticsSolid state chemistry.Chemical kinetics.541.0421541.394Schmalzried Hermann18113MiAaPQMiAaPQMiAaPQBOOK996203158603316Chemical kinetics of solids2002551UNISA